Atmospheric absorption in the O2 Schumann-Runge band spectral range and photodissociation rates in the stratosphere and mesophere

A general analysis of the absorption of the Schumann-Runge bands of molecular oxygen has been made in order to compare the various experimental and theoretical results which have been obtained for an application to the O₂ atmospheric absorption and its photodissociation in the mesosphere and stratosphere. The different values of the oscillator strengths deduced from the laboratory absorption spectra and of the predissociation linewidths used for the calculation of the absorption have been compared.Calculations based on a Voight profile of the O₂ rotational lines have led to simple formulas for atmospheric applications taking into account that the total photodissociation rate in the stratosphere depends strongly on the absorption of solar radiation in the spectral range of the O₂ Herzberg continuum. Specific examples are given.     

The solar spectral irradiance and its action in the atmospheric photodissociation processes

A critical analysis has been made of solar irradiance in the spectral region covering wavelengths from 100 nm upwards; the absorption characteristics of molecules of oxygen and ozone have been taken into account with a view to the direct application of the results to atmospheric photochemistry. The absorption of radiation by these molecules results in the photodissociation of both of them in the homosphere, and it also makes possible the penetration of solar radiation from the thermosphere, through the mesosphere and the stratosphere, down to the troposphere.Special attention has been given to each of the following spectral regions: Lyman-alpha radiation at 121.6 nm, the O₂ Schumann-Runge continuum at wavelengths less than 175 nm, the O₂ Schumann-Runge band system from 200 to 175 nm, and the O₂ Herzberg continuum at 242.4 nm. For absorption by ozone, the solar spectrum has been analysed in the following regions: the Hartley band at wavelengths less than 310 nm, the Huggins bands at wavelengths above 310 nm and the visible Chappuis bands. Finally, for the photodissociation of O₃, particular attention has been given to the transition region (300–320 nm) in which there is a change-over from the production of the excited atom O(¹D) to that of the atom in its ground state O(³p).     

Improved Representation of Land-surface Heterogeneity in a Non-hydrostatic Numerical Weather Prediction Model

This study focuses on the relevance of accurate surface parameters, in particular soil moisture, and of parameterizations for heterogeneous land surfaces, for the prediction of sensible and latent heat fluxes by a mesoscale weather forecast model with horizontal grid resolution of 7 km. The analysis is based on model integrations for a 30-day period, which are compared both to flux measurements obtained from the LITFASS-2003 field experiment and to high-resolution-model (1-km grid spacing) results. At first, the relevance of improved parameter sets and input data compared to usual operational practice for an accurate prediction of near-surface fluxes is shown and discussed. It is demonstrated that an observation-based land-surface assimilation scheme leads to an improved soil moisture analysis, which is shown to be essential for the realistic simulation of surface fluxes. Secondly, the implementation of two efficient parameterization strategies for subgrid-scale variability of the surface, the mosaic and the tile approach, is presented. Using these methods, the simulations are in better agreement with measurements than simulations with simple aggregation methods that use effective surface parameters. Integrations with the mosaic approach reproduce high resolution simulations very well and more accurately than simulations with the tile method. Finally, the high resolution simulations are analyzed to justify and discuss the approximations underlying both methods.     

Tracing of variabilities within a geological barrier by molecular organic geochemistry.: Case of the Callovo-Oxfordian sedimentary series in the East of the Paris Basin (France)

The Callovo-Oxfordian claystones located at 500 m depth at Bure (Meuse, France) are currently being investigated by Andra (the French National Radioactive Waste Management Agency) for testing the feasibility of long-term and deep geological nuclear waste disposal. In order to evaluate its potential as a geological barrier, it is very important to study, assess and describe its physico-chemical variability. The molecular biomarker composition of 150 samples of these claystones and their surrounding limestones carry diverse information on the sources of the sedimentary organic matter, the chemistry of the depositional environment, the preservation and diagenesis conditions. It also allows assessing the degree of lateral and vertical variability of the organic matter within these sedimentary series. The abundance of unsaturated biomarkers, the distribution of steroids and hopanoids and CPI values >2 prove the thermal immaturity of the organic matter. The co-occurrence of plankton, bacteria and land plant biomarkers indicate that the organic matter is a mixture of marine and continental contributions. The data also reveal that the organic matter was deposited under oxic and open-sea conditions except for a brief event of photic zone anoxia at the beginning of the Middle Callovian. In the claystones, the geosynthesis of diasterenes is favored to the detriment of the formation of steranes, especially in smectite-rich levels, and the organic matter is rapidly isolated from oxidizing then reducing conditions after the deposition due to the protective effect of clays. On the scale investigated, the claystones are characterized by a unique molecular facies and are thus homogenous from their organic content point of view. Yet, detailed investigation of specific molecular families indicates changes related to major claystone–limestone transitions. The homogeneity of these claystones can be explained by the paleogeographic position of their depositional setting and the plane and sub-horizontal paleotopography on which they were deposited. This study demonstrates the efficiency of organic geochemistry in the assessment of the variability of geological barriers.     

Is pure groundwater safe to drink?: natural "contamination' of groundwater in Norway

The title of this article is designed to provoke. Naturally occurring parameters are, by definition, not contamination. Nevertheless, nature is not necessarily nice, and naturally occurring trace toxins can be every bit as undesirable as their counterparts derived from human pollution.     

Possible formation scenarios for the giant H i envelope around the NGC 4490/4485 system

We present observations of H i in the nearby interacting galaxies NGC 4490 and 4485 made with the VLA in both C and D arrays. The galaxies are embedded in an extensive envelope of neutral hydrogen which is elongated in a direction approximately perpendicular to the plane of NGC 4490, with an extent of about 56 kpc. We argue that this distribution of neutral hydrogen can best be explained by a galactic-scale bipolar outflow of H  i driven by supernovae in NGC 4490. The flow from the disc appears to be reasonably well collimated and has probably persisted for approximately 6 × 10⁸ yr. The implications for galaxy evolution when such mass loss occurs are briefly discussed.     

Die fazielle und paläogeographische Entwicklung der infrakambrischen bis ordovizischen Sedimente im Mittleren Antiatlas um Agdz (S-Marokko)

Zusammenfassung Die Entwicklung des Adoudounien (Infrakambrium) und Géorgien (Unterkambrium) ist im Mittleren Antiatlas durch einen Wechsel von marinen und kontinentalen Sedimenten gekennzeichnet. Wildbachablagerungen an der Basis und an den Beckenrändern werden von marin-marginalen stromatolithischen Karbonaten abgelöst. Ignimbrite belegen wiederholte terrestrische Sedimentation.Mit fluviatilen Sanden und wiederum Stromatolithen und lagunären Karbonaten (mit ersten Trilobiten!) setzt ein zweiter transgressiver Großzyklus ein, der an der Wende Infra-/Unter-Kambrium einen ersten Höhepunkt erreicht. Durch regressive Kleinzyklen charakterisierte Abfolgen leiten zu Sandsteinen über, die als Ablagerungen eines Deltas gedeutet werden.Vom Mittelkambrium bis Ordovizium dominiert marine Schelfsedimentation.

---

The formations of Adoudounien (Infra Cambrian) and Géorgien (Lower Cambrian) of the middle Anti-Atlas are characterized by an alternation of marine and continental sediments. Torrent conglomerates at the base and the margins of the basin took turns to marine-marginal stromatolitic carbonates. Ignimbrites prove repeated terrestrial sedimentation.A second transgressiv megasequence begins with fluviatil sands and goes on with stromatolites and lagoon carbonates (first Trilobites). This transgression reachs his first culmination at the Infra-/Lower-Cambrian boundary. Typical regressiv cycles form a transition to sandstones, which are interpreted as sediments of a delta.Marine shelf environment dominates from Middle Cambrian to Ordovician beds.

---

Résumé Dans le moyen Anti-Atlas, l'évolution de l'Adoudounien et du Géorgien est caractérisée par un changement des sédiments marins et continentaux. Les dépôts des torrents à la base et dans la bordure du bassin font place à des carbonates marins marginaux stromatolithiques. Les ignimbrites marquent le retour fréquent à la sédimentation terrestre.Une deuxième mégaséquence transgressive débute avec des sables fluviatiles, des stromatolithes et des carbonates lagunaires (premiers trilobites). La transgression atteint une première phase culminante à la transition de l'Adoudounien au Géorgien. Des séquences caractérisées par de petits cycles régressifs conduisent à des grès qui pourraient être interpré tés comme des sédiments deltaïques.A partir du Cambrien moyen jusqu'à l'Ordovicien prédomine un milieu de plate-forme externe.

---

Adoudounien — — Géorgien — — . — — . , - , , . , , . .

     

Buchbesprechungen

Ohne Zusammenfassung     

Changes in stream water quality due to logging of the boreal forest in the Montmorency Forest,Québec

Summer stream water quality was monitored before and following the logging of 50% of the boreal forest within three small watersheds (<50 ha) nested in the ‘Ruisseau des Eaux‐Volées’ Experimental Watershed, Montmorency Forest (Québec, Canada). Logging was conducted in winter, on snow cover according to recommended best management practices (BMPs) to minimize soil disturbance and protect advance growth. A 20‐m forest buffer was maintained along perennial streams. In watershed 7·2, cut‐blocks were located near the stream network and logging was partially allowed within the riparian buffer zone. In watersheds 7·5 and 7·7, logging occurred farther away from the stream network. Observations were also made for watershed 7·3 that collected the runoff from watersheds 7·2 and 7·5, and watershed 7·6, the uproad portion of watershed 7·7. The control watershed 0·2 was contiguous to the impacted watersheds and remained undisturbed. Following clearcutting, changes in summer daily maximum and minimum stream temperatures remained within ± 1 °C while changes in diurnal variation did not decrease by more than 0·5 °C. Concentrations of NO₃^? greatly increased by up to 6000% and concentrations of K⁺ increased by up to 300% during the second summer after logging. Smaller increases were observed for Fe_total (up to 71%), specific conductance (up to 26%), and Mg²⁺ (up to 19%). Post‐logging pH decreased slightly by no more than 7% while PO₄^3? concentration remained relatively constant. Suspended sediment concentrations appeared to increase during post‐logging, but there was not enough pre‐logging data to statistically confirm this result. Logging of moderate intensity and respecting established BMPs may account for the limited changes of water quality parameters and the low exceedances of the criteria for the protection of aquatic life. The proximity of the cutover to the stream network and logging within the riparian zone did not appear to affect water quality. Copyright © 2008 John Wiley & Sons, Ltd.