Michigan basin regional ground water flow discharge to three Great Lakes

Ground water discharge to the Great Lakes around the Lower Peninsula of Michigan is primarily from recharge in riparian basins and proximal upland areas that are especially important to the northern half of the Lake Michigan shoreline. A steady-state finite-difference model was developed to simulate ground water flow in four regional aquifers in Michigan's Lower Peninsula: the Glaciofluvial, Saginaw, Parma-Bayport, and Marshall aquifers interlayered with the Till/"red beds," Saginaw, and Michigan confining units, respectively. The model domain was laterally bound by a continuous specified-head boundary, formed from lakes Michigan, Huron, St. Clair, and Erie, with the St. Clair and Detroit River connecting channels. The model was developed to quantify regional ground water flow in the aquifer systems using independently determined recharge estimates. According to the flow model, local stream stages and discharges account for 95% of the overall model water budget; only 50% enters the lakes directly from the ground water system. Direct ground water discharge to the Great Lakes' shorelines was calculated at 36 m3/sec, accounting for 5% of the overall model water budget. Lowland areas contribute far less ground water discharge to the Great Lakes than upland areas. The model indicates that Saginaw Bay receives only approximately 1.13 m3/sec ground water; the southern half of the Lake Michigan shoreline receives only approximately 2.83 m3/sec. In contrast, the northern half of the Lake Michigan shoreline receives more than 17 m3/sec from upland areas.     

Improvement of snowpack simulations in a regional climate model

To improve simulations of regional‐scale snow processes and related cold‐season hydroclimate, the Community Land Model version 3 (CLM3), developed by the National Center for Atmospheric Research (NCAR), was coupled with the Pennsylvania State University/NCAR fifth‐generation Mesoscale Model (MM5). CLM3 physically describes the mass and heat transfer within the snowpack using five snow layers that include liquid water and solid ice. The coupled MM5–CLM3 model performance was evaluated for the snowmelt season in the Columbia River Basin in the Pacific Northwestern United States using gridded temperature and precipitation observations, along with station observations. The results from MM5–CLM3 show a significant improvement in the SWE simulation, which has been underestimated in the original version of MM5 coupled with the Noah land‐surface model. One important cause for the underestimated SWE in Noah is its unrealistic land‐surface structure configuration where vegetation, snow and the topsoil layer are blended when snow is present. This study demonstrates the importance of the sheltering effects of the forest canopy on snow surface energy budgets, which is included in CLM3. Such effects are further seen in the simulations of surface air temperature and precipitation in regional weather and climate models such as MM5. In addition, the snow‐season surface albedo overestimated by MM5–Noah is now more accurately predicted by MM5–CLM3 using a more realistic albedo algorithm that intensifies the solar radiation absorption on the land surface, reducing the strong near‐surface cold bias in MM5–Noah. The cold bias is further alleviated due to a slower snowmelt rate in MM5–CLM3 during the early snowmelt stage, which is closer to observations than the comparable components of MM5–Noah. In addition, the over‐predicted precipitation in the Pacific Northwest as shown in MM5–Noah is significantly decreased in MM5–CLM3 due to the lower evaporation resulting from the longer snow duration. Copyright © 2011 John Wiley & Sons, Ltd.     

The use of fluorine as a pathfinder for volcanic-hosted massive sulfide ore deposits

A multi-element geochemical study of the wall rocks of intermediate to felsic volcanic-hosted massive sulfide deposits was carried out to identify pathfinder elements which significantly enlarge the size of exploration targets. Drill core samples from the Crandon massive sulfide deposit in Wisconsin, and outcrop samples from the United Verde and Iron King deposits in Arizona, and from the Captains Flat, Mt. Costigan, and Wiseman Creek deposits in New South Wales, Australia were analyzed. Because anomalously high fluorine values have been described in several volcanic-hosted ore systems, fluorine was included in the study.All of the above deposits have patterns of fluorine enrichment around ore. Drill core samples from two noneconomic prospects within ten miles of the Crandon deposit contain background to only weakly anomalous fluorine values.At the large Crandon deposit (> 50 million tons of zinc, copper ore), fluorine enrichment extends approximately 320 m into the footwall rocks and at least 220 m into the hanging wall rocks. At the large United Verde deposit (> 50 million tons of copper, zinc ore), fluorine enrichment is recognizable in the footwall rocks at least 650 m from the ore. At the smaller Iron King deposit (five million tons production of zinc, lead, copper ore), fluorine enrichment extends for a distance of approximately 60 m into the footwall rocks. At the small deposits in New South Wales (< five million tons production of zinc, lead, copper ore), fluorine enrichment is easily recognizable, but with the samples collected, the limits of the anomalous patterns cannot be defined.Fluorine occurs in some hydrothermal systems unassociated with mineralization and is therefore not a specific signature of ore-forming processes. From the work completed, many massive sulfide deposits in volcanic rocks occur in hydrothermal systems which contain fluorine. On the basis of the data presented, if anomalously high fluorine values do exist in an exploration search area, the chances of finding a massive sulfide ore deposit are improved.Genetic models for volcanic-hosted massive sulfide ore deposits have concentrated on rock textures, alteration mineralogy, and geochemistry of the ore metals. From the data presented, fluorine should be considered as a component of massive sulfide systems in intermediate to felsic volcanic rocks, and should be considered as a possible complexing agent for the ore metals.     

Structural features and metallogenesis of the Carlin-type Jinfeng (Lannigou) gold deposit, Guizhou Province, China

Jinfeng, previously known as Lannigou, is the largest Carlin-type gold deposit in the Yunnan–Guizhou–Guangxi region in southwestern China. Gold mineralization in the Jinfeng deposit is almost entirely fault-hosted and structurally controlled, with very little disseminated ore occurring in the adjacent host rocks. The structural elements in the Jinfeng deposit can be subdivided into 3 groups comprising NS-, NW-, and NE-striking faults and folds, with NW-striking structures controlling the overall framework of the deposit. Four tectonic stages have been recorded in the Jinfeng area, i.e., rifting, orogenic compression, lateral transpression, and lithospheric extension. A series of contemporaneous normal faults, such as the N-striking and east-dipping F1 and F7 faults developed along the edges of a carbonate platform during basin rifting (D₂–T₂). These structures provided an initial framework for subsequent basin evolution, and also represent the principal hydrothermal conduits. A gradual change of the compression direction during the orogenic stage (T₃) from E→W to NE→SW, gave rise to the NW-striking structures, including large, tight to overturned folds such as the Huangchanggou synclinorium and associated thrusts such as the F3 fault. The development of these orogenic, predominantly NE-dipping structures, as well as accompanying NE-striking dextral shear and transform faults (such as the F2 fault) along the margin of the Laizishan Dome established the structural pattern of the deposit area. The NW-striking folds were refolded by NE-striking superimposed folds during post-collisional lateral transpression (J₁) and NW–SE directed compression. Oblique stress distribution gave rise to NS-trending compression and EW-trending extension, with dilational zones developing at the intersection of the F2 and the F3 faults east of the Laizishan dome. It is these dextral- and sinistral-normal dilational zones in which gold was precipitated during the main ore-forming event at Jinfeng. Following the main ore stage lithospheric extension occurred during the Yanshan stage (J₂–K) resulting in minor reverse faults that in places cut pre-existing structures. The above four main structural deformation stages mirror the evolution of the Youjiang Basin from inception to basin inversion and post-orogenic collapse and renewed extension. Significant gold metallogenesis at Jinfeng occurred during the transition from collisional compression to extensional tectonics in the early Jurassic, and is focussed into intersections of F2 and F3 and fault splays adjacent to F3. This structurally controlled gold metallogenic model is likely to be applicable to analogous settings elsewhere in the Yunnan–Guizhou–Guangxi triangle area, and has implications for the targeting of Carlin-type gold mineralization in this region.     

Étude de la Représentativité des Teneurs en Platine et En Iridium d'un Echantillon de Sédiment de Ruisseau Prélevé a Proximité d'un Gîte de Cr-EGP-Ni

Une étude de représentativité a été effectuée sur un échantillon de sédiment de ruisseau (SRH-1) prélevéà proximité d'un gîte de Cr-EGP-Ni contenu dans la ceinture ophiolitique des Appalaches du Québec (Canada). Notre étude avait pour but de démontrer que l'analyse de quelques grammes de SRH-1 assurait une représentativité adéquate à l'utilisation des teneurs en EGP d'échantillons de sédiment de ruisseau comme outil d'exploration pour les gîtes de Cr-EGP-Ni associés aux séquences ophiolitiques. Pour ce faire, les teneurs en EGP de SRH-1 ont d'abord été caractérisées par pyroanalyse au sulfure de nickel (29 parties aliquotes de 50 g) et par pyroanalyse plombeuse (50 parties aliquotes de 25 g). Dans ce dernier cas, seulement Pt, Pd et Rh ont été mesurés. Ensuite, les EGP ont été mesurés dans des quantités de plus en plus petites de SRH-1 par pyroanalyse au sulfure de nickel (8 parties aliquotes de 15 g, 8 de 8 g et 8 de 5 g). Les résultats démontrent que des prises de 5 g de SRH-1 assurent une représentativité adéquate à l'analyse de Pt et de Ir soit des résultats analytiques similaires (moyennes et écarts types) à ceux découlant de l'analyse d'une prise de 50 g. Il nous a été impossible de juger de la représentativité d'une prise de 5 g en ce qui concerne les déterminations de Pd, Rh, Os, Ru, ces éléments se trouvant sous ou près des seuils de détection dans les prises de 15, 8, et de 5 g.     

From strike-slip faulting to oblique subduction: A survey of the Alpine Fault-Puysegur Trench transition,New Zealand,results of cruise Geodynz-sud leg 2

The Geodynz-sud cruise on board the R/V l'Atalante collected bathymetric, side-scan sonar and seismic reflection data along the obliquely convergent boundary between the Australian and Pacific plates southwest of the South Island, New Zealand. The survey area extended from 44°05 S to 49°40 S, covering the transition zone between the offshore extension of the Alpine Fault and the Puysegur Trench and Puysegur Ridge. Based on variations in the nature and structure of the crust on either side of the margin, the plate boundary zone can be divided into three domains with distinctive structural and sedimentary characteristics. The northern domain involves subduction of probably thinned continental crust of the southern Challenger Plateau beneath the continental crust of Fiordland. It is characterized by thick sediments on the downgoing slab and a steep continental slope disrupted by fault scarps and canyons. The middle domain marks the transition between subduction of likely continental and oceanic crust defined by a series of en echelon ridges on the downgoing slab. This domain is characterized by a large collapse terrace on the continental slope which appears to be due to the collision of the en echelon ridges with the plate margin. The southern domain involves subduction of oceanic crust beneath continental and oceanic crust. This domain is characterized by exposed fabric of seafloor spreading on the downgoing slab, a steep inner trench wall and linear ridges and valleys on the Puysegur ridge crest. The data collected on this cruise provide insights into the nature and history of both plates, and factors influencing the distribution of strike-slip and compressive strain and the evolution of subduction processes along a highly oblique convergent margin.     

Macroalgal assemblages of disturbed coastal detritic bottoms subject to invasive species

Characteristic flora and fauna that are highly sensitive to disturbances colonize coastal detritic bottoms in the Mediterranean Sea. In the present study, a comparison of the assemblage composition and colonization by invasive macroalgae was made between two coastal detritic macrophyte assemblages, one dominated by rhodoliths (free-living non-geniculate Corallinales) and the other dominated by fleshy algae, in an area that has been exposed to important levels of anthropogenic disturbance, mainly pollution (including changed sedimentation regimes) in the recent past (bay of Marseilles, France). In comparison with less strongly impacted Mediterranean regions, the macrophyte assemblages in the bay of Marseilles were characteristic in terms of species identity and richness of coastal detritic macrophyte assemblages. However, extremely low species abundance (cover) was observed. As far as invasive species were concerned, Caulerpa racemosa var. cylindracea was only abundant in the rhodolith assemblage whereas the two invasive Rhodophyta Asparagopsis armata and Womersleyella setacea were mainly found in the fleshy algae assemblage. The seasonality observed in the Rhodolith assemblage seemed to be related to the development of C. racemosa var. cylindracea and did not follow the typical pattern of other Mediterranean assemblages. This study represents the first study of coastal detritic assemblages invaded by C. racemosa var. cylindracea.     

Length scales of mantle heterogeneities and their relationship to ocean island basalt geochemistry

The upper mantle is widely considered to be heterogeneous, possibly comprising a “marble-cake” mixture of heterogeneous domains in a relatively well-mixed matrix. The extent to which such domains are capable of producing and expelling melts with characteristic geochemical signatures upon partial melting, rather than equilibrating diffusively with surrounding peridotite, is a critical question for the origin of ocean island basalts (OIB) and mantle heterogeneity, but is poorly constrained. Central to this problem is the characteristic length scale of heterogeneous domains. If radiogenic osmium signatures in OIB are derived from discrete domains, then sub-linear correlations between Os isotopes and other geochemical indices, suggesting melt-melt mixing, may be used to constrain the length scales of these domains. These constraints arise because partial melts of geochemically distinct domains must segregate from their sources without significant equilibration with surrounding peridotite. Segregation of partial melts from such domains in upwelling mantle is promoted by compaction of the domain mineral matrix, and must occur faster than diffusive equilibration between the domain and its surroundings. Our calculations show that the diffusive equilibration time depends on the ratios of partition and diffusion coefficients of the partial melt and surrounding peridotite. Comparison of time scales between diffusion and melt segregation shows that segregation is more rapid than diffusive equilibration for Os, Sr, Pb, and Nd isotopes if the body widths are greater than tens of centimeter to several meters, depending on the aspect ratio of the bodies, on the melt fraction at which melt becomes interconnected in the bodies, and on the diffusivity in the solid. However, because Fe-Mg exchange occurs significantly more rapidly than equilibration of these isotopes under solid-state and partially molten conditions, it is possible that some domains can produce melts with Fe/Mg ratios reflecting that of the surrounding mantle but retaining isotopic signatures of heterogeneous domains. Although more refined estimates on the rates of, and controls on, Os mobility are needed, our preliminary analysis shows that heterogeneous domains large enough to remain compositionally distinct in the mantle (as solids) for ∼10⁹ yr in a marble-cake mantle, can produce and expel partial melts faster than they equilibrate with surrounding peridotite.     

Identification of stoichiometric iron-phosphorus colloids produced in a eutrophic lake

: Iron-rich colloids formed at the oxic-anoxic interface of a eutrophic lake (Lake Lugano; CH) were characterized by bulk chemical methods and analytical electron microscopy. Fractionation of raw waters showed that non-dissolved iron is particulate above the oxicline and mainly colloidal in the anoxic part of the hypolimnion, while non-dissolved ortho-phosphate is mostly colloidal through the water column. Because of these differences, filtration did not prove helpful for the determination of the role of iron-rich species in the scavenging of ortho-phosphate. On the other hand, analytical electron microscopy revealed that iron-rich nano-granules (ca. 50nm) are associated to the surface of bacterially produced fibrillar polysaccharides. Iron colloids in these complex entities contain important and constant amounts of phosphorus ([PO4]part:[Fe]part = 0.48 - 0.11, n = 1096 Fe-rich entities analyzed by electron microscopy), which suggests that phosphates are stoichiometrically incorporated into the hydrous iron oxide phase, with a tentative composition Fe2[OOH]1-x[(OH)3]x[PO4], during its genesis.     

Geophysical evidence for gas geohazards off Iskenderun Bay, SE Turkey

High-resolution seafloor and sub-surface data were acquired as part of a site survey in Iskenderun Bay, SE Turkey to characterize the geohazards at the location of the proposed drilling site. A 3 km×3 km geophysical study reveals a pockmark field which trends NE and NNE, similar to the trend of major fault systems in the area. The pockmarks, with an average diameter of 35 m, reach their highest density in the northern part of the detailed survey area, with 13 features/km². Acoustic anomalies in the seismic records (acoustic turbidity, blanking, enhanced reflectors) below the proposed drilling site indicated potential shallow gas beneath it. The local seismic anomalies (amplitude and frequency) parallel to stratigraphy were assigned a low gas risk. As a result of the active neotectonics in the area, the pockmark field presented a potential hazard for drilling at the original location. The geohazard study resulted in moving the proposed drilling site eastward to an area of fewer pockmarks, less sub-surface seismic anomalies, and thus a location interpreted as a lower geohazard environment.