Comparison between natural and artificial maturation series of humic coals from the Mahakam delta,Indonesia

Type III (humic) organic matter from the Mahakam delta (Indonesia) was chosen to compare artificial and natural coal series. Powdered and concentrated immature organic matter was heated in sealed gold tubes for 24 hr at temperatures ranging from 250 to 550°C and under pressures ranging from 0.5 to 4 kb, with and without water. Both elemental and Rock-Eval analyses were used to characterize the products. A comparison between our results, published data and the natural model shows that, quantitatively, natural maturation is simulated better when pyrolysis is performed under confined conditions (no free volume, no diluting inert gas). Thus, pyrolysis in a medium swept by an inert gas, vacuum pyrolysis and some pyrolysis in sealed glass tubes must be considered to be poor simulation tools. The presence of water does not seem to have an essential effect. Allowing the hydrocarbons formed to reach a certain value of partial pressure seems to be important. Results are unchanged when external pressure varies from 0.5 to 4 kb.     

Effect of treatment with reserpine on the change in filtration rate of Mytilus edulis subjected to dissolved copper

Exposure of specimens of Mytilus edulis to dissolved copper leads to a fall in the filtration rate measured in whole animals. The copper concentration leading to a 50% reduction in the filtration rate was found to be 0.094 mg I⁻¹. This effect was abolished on depletion of the monoamine content of the animal using reserpine. It is suggested that there may be a chemosensory mechanism present in the animals which responds to increased levels of metals in the seawater leading to a reduction in the rate of ciliary beating and mediated via the branchial nerve.     

Importance of the oxidation/maturation pair in the evolution of humic coals

The natural thermal evolution of type III coals (Humic origin) is expressed during diagenesis by a loss of oxygen as CO₂ and H₂O. Other phenomena such as oxidation can cause extensive geochemical modifications and may complicate the effects of simple maturation.Humic coals from the Jurassic in southeastern Utah were studied by elemental analysis, Rock-Eval pyrolysis and infrared spectroscopy. In a van Krevelen diagram (atomic H/C vs atomic O/C), the samples fall within the envelope defined by 860 reference humic coals covering the entire range of diagenesis. Nevertheless, various criteria (geochemical, petrographic, geological and microscopic) cast doubt upon the interpretation that such a distribution of coal composition results from thermal maturation.The same criteria indicate the intervention of redox phenomena. Comparison of our results with those from artificial and natural oxidation shows that these coals were subjected to an oxidation process different from ordinary late alteration. This process was probably due to circulation of highly oxidizing saline water causing oxygen fixation and the transformation of carboxyls into carboxylate anions. The cations that were fixed are oxygenated and certainly contain calcium, but also uranium and perhaps several other cations (V, Mo, Fe...). Emphasis is placed on possible mechanisms that cause such phenomena.     

RbSr and KAr ages of paleozoic glauconites from Ohio—Indiana and Missouri,U.S.A.

Glauconite pellets from the Lower Silurian Brassfield Formation on both limbs of the Cincinnati Arch in Ohio and Indiana give a RbSr age of 370 ± 11 Ma, which is substantially younger than the stratigraphic age of the formation. The age is concordantcwith conventional KAr ages of 355 ± 6 and 368 ± 5 Ma for two of the same glauconites. Concordant ages were also obtained from the Viburnum Trend in Missouri, where glauconite pellets from the Davis Formation in an ore-zone collapse structure into the underlying Bonneterre Formation give a RbSr age of 387 ± 21 Ma and conventional KAr ages of 368 ± 5 and 369 ± 5 and 369 ± 5 Ma. A third suite of glauconite from the Bonneterre Formation in the Old Lead Belt ～ 10 km from the nearest ore body has given a RbSr age of 423 ± 7 Ma and slightly older conventional KAr ages of 434 ± 6, 445 ± 6 and 441 ± 11 Ma.Because these glauconite-bearing rocks have been buried to depths of less than 1 km, thermal resetting of the RbSr and KAr systematics appears unlikely. The initial ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios of the RbSr isochrons are similar to the ratios for vein- and vug-filling dolomite and calcite. This is consistent with resetting of the RbSr and KAr systems during diagenetic changes which included the isotopic equilibration (perhaps by cation exchange) of the Sr in the glauconite with that in the diagenetic and Mississippi Valley-type ore fluids. This interpretation implies that the age of the Mississippi Valley-type mineralization in the Viburnum Trend is Devonian rather than Carboniferous—Permian as has been inferred from paleomagnetic measurements.Cation-exchange experiments with a dilute Sr-bearing solution and an artificial oilfield brine indicate that glauconite adsorbs large amounts of Sr, some of which is sufficiently strongly attached to the glauconite lattice as to resist leaching with ammonium acetate. The introduction of this strongly attached Sr may be the first step in the resetting of the RbSr systematics of glauconite by cation exchange.     

The increasing CO2 concentration in the atmosphere and its implication on agricultural productivity II. Effects through CO2-induced climatic change

In a prior paper (Part I), the point was made that, assuming an unchanged climate, water use efficiency in agricultural crop production will likely be favored by the increase in CO₂ concentration projected to occur within the next half century. Since climatic changeis likely to result from the CO₂ concentration increase, its possible impacts on agricultural productivity must also be considered. An attempt to do so, using the Great Plains region of North America as a case study, is reported in this paper (Part II). A number of climatic models predict significant increases in surface temperature. Manabe and Wetherald's (1980) model provides the most specific projections for a hypothetical Northern hemisphere continent. That model also predicts an intensification of the hydrologic cycle with rainfall distribution altered so that some zones will receive more and some less as a result of a doubling in the atmospheric CO₂ concentration. The zone between 37 and 47° N latitude will suffer a reduction in availability of soil moisture. A number of regression models of grain yield as a function of temperature and precipitation have been used to anticipate the impacts of the projected climatic changes. The value of this approach is questioned. An alternative approach - the study of the migration of major agricultural crops across strong climatic gradients - is proposed. Changes in the geographical distribution of the hard red winter wheat zone in North America provide an example. The point is also made that factorscurrently limiting food production must be considered in order to predict the possible impacts of any given climatic change. In the central Great Plains today, the energy consumed by evapotranspiration often exceeds that supplied by net radiation since sensible heat advection from dryer regions to the south and west provides a major additional input of energy. If, as models project, the excess of precipitation over evaporation increases south of 37° N, the advection of sensible heat and, hence, the rates of evapotranspiration and degree of water stress on growing plants could be reduced in the adjacent regions to the north. Published as Paper No. 6123, Journal Series, Nebraska Agricultural Experiment Station. The work reported was conducted under Regional Research Project 11-033 and Nebraska Agricultural Station Project 11-049. George Holmes Professor of Agricultural Meteorology, Center for Agricultural Meteorology and Climatology, Institute of Agriculture and Natural Resources, University of Nebraska, Lincoln, Nebraska, 68583-0728.     

Characteristics of air flow above and within soybean canopies

Air flow was observed above and within canopies of a number of kinds of soybeans. The Clark cultivar and two isolines of the Harosoy cultivar were studied in 1979 and 1980, respectively. Wind speed above the canopy was measured with cup anemometers. Heated thermistor anemometers were used to measure air flow within the canopy. Above-canopy air flow was characterized in terms of the zero-plane displacement (d), roughness parameter (z _o) and drag coefficient (C _d). d and z _o were dependent on canopy height but were independent of friction velocity in the range 0.55 to 0.75 m s^?1 · C _d for the various canopies ranged from 0.027 to 0.035. Greater C _d values were measured over an erectophile canopy than over a planophile canopy. C _d was not measurably affected by differences in leaf pubescence. Within-canopy wind profiles were measured at two locations: within and between rows. The wind profile was characterized by a region of great wind shear in the upper canopy and by a region of relatively weak wind shear in the middle canopy. Considerable spatial variability in wind speed was evident, however. This result has significant implications for canopy flow modeling efforts aimed at evaluating transport in the canopy. In the lower canopy, wind speed within a row increased with depth whereas wind speed between two rows decreased with depth. The wind speeds at the two locations tended to converge to a common value at a height near 0.10 m. The attenuation of within-canopy air flow was stronger in canopies with greater foliage density. Canopy flow attenuation seemed to decrease with increasing wind speed, suggesting that high winds distorted the shape of the canopy in such a manner that the penetration of wind into the canopy increased.     

Radiocarbon dating of Danube Delta deposits

The Holocene history of the Danube Delta has been studied using ¹⁴C analyses of faunal material. The principal phases of development include: (1) initial Letea Caroarman spit, 11,700–9800 yr B.P. in its central part, 8800-5500 yr B.P. in its southern part; (2) Sf. Gheorghe I Delta, 8900-7200 yr B.P.; (3) Sulina Delta, 7200-2000 yr B.P., and (4) Sf. Gheorghe II Delta-Chilia Delta 2000 yr B.P.-present. Other smaller-scale features have also been dated, including secondary deltas (Co?na and Sinoe Deltas) and littoral bars. Age determinations carried out on whole samples were erratic and it was found that individual species had to be separated and dated. In all cases, the older dates were of transported material whereas the younger dates gave the true age of the formation.     

Verifying warnings for point precipitation

Short-term risk forecasts of point precipitation are obtained with COTREC/RainCast, a technique for extrapolation of radar images. The risk forecasts are updated every 5 min for the next 0–2 h. Risk levels are defined for moderate, heavy and extreme precipitation. Warning messages are generated if, at the locations of 23 rain gauges, these risk levels are reached or exceeded. The time-resolved gauge data are used to judge if the warning messages are in time, early or late.Data over a period of 4 months (summer 2002) are used for verification. The largest number of warnings (1790) was obtained for moderate precipitation. About 55% of these warnings were in time, 23% were early and 22% were late. This finding is in a good agreement with the defined risk level for warnings (50%), indicating that the model for calculating the risk factors is reliable. Less warnings in time, and more late warnings were found for heavy and extreme precipitation. Hence, the risk levels need to be lowered for heavy and extreme precipitation, in order to reduce the number of late warnings.     

Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).