The use of7LiOH-impregnated filters for the collection of acidic gases and analysis by instrumental neutron activation analysis

A simple system was designed using⁷LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M⁷LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO₂ and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO₂ may not be collected quantitatively since SO₂ is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected.     

Influence of m-cresol purple indicator additions on the pH of seawater samples: correction factors evaluated from a chemical speciation model

The perturbation of the indicator m-cresol purple on the pH in seawater is illustrated in diagrams, representing measurements in 1-cm and 5-cm cells. The diagrams apply to a measured pH interval of 7.4–8.4 using a 2-mM stock solution of m-cresol purple sodium salt dissolved in seawater. The magnitude of the perturbation is described as correction values, i.e., the change in seawater pH caused by the indicator. The diagrams are based on calculations made by using the equilibrium speciation programme, MARINHALT. From these calculations, and least squares fitting methods, pH correction values are described in terms of the pH difference between each seawater sample and the pH of an indicator stock solution. Calculations are performed for a typical high latitude water and a north Pacific deep water. Diagrams are presented for a salinity of 35 and a temperature of 15°C. Responses to salinities between 32 and 36 and temperatures 15–25°C are illustrated as well. A ±0.05 pH difference between a seawater sample and an indicator stock solution gives a correction of less than 0.001 pH unit for a 1-cm cell. For a 5-cm cell, pH differences between the indicator stock solution and a seawater sample as large as ±0.3 cause corrections smaller than ±0.001 pH unit. Calculations demonstrate that the five-fold lower indicator concentration used with 5-cm cells decreases the perturbation effect by approximately a factor of five relative to 1-cm cells.     

Strain properties of shelf grounds in the area of the Yurii Korchagin Field,North Caspian Sea

Marine disperse grounds from the shelf of the North Caspian Sea were studied using various test methods. The strain modulus and the coefficient of transverse strain were specified by triaxial compression and compression tests. Empirical correlations were found for the strain modulus as a result of both tests for different types of grounds.     

Accretion tectonics and crustal structure in Alaska

The entire width of the North American Cordillera in Alaska is made up of “suspect terranes”. Pre-Late Cretaceous paleogeography is poorly constrained and the ultimate origins of the many fragments which make up the state are unclear. The Prince William and Chugach terranes accreted since Late Cretaceous time and represent the collapse of much of the northeast Pacific Ocean swept into what today is southern Alaska. Greater Wrangellia, a composite terrane now dispersed into fragments scattered from Idaho to southern Alaska, apparently accreted into Alaska in Late Cretaceous time crushing an enormous deep-marine flysch basin on its inboard side. Most of interior eastern Alaska is the Yukon Tanana terrane, a very large entirely fault-bounded metamorphic-plutonic assemblage covering thousands of square kilometers in Canada as well as Alaska. The original stratigraphy and relationship to North America of the Yukon-Tanana terrane are both obscure. A collapsed Mesozoic flysch basin, similar to the one inboard of Wrangellia, lies along the northern margin. Much of Arctic Alaska was apparently a vast expanse of upper Paleozoic to Early Mesozoic deep marine sediments and mafic volcanic and plutonic rocks now scattered widely as large telescoped sheets and Klippen thrust over the Ruby geanticline and the Brooks Range, and probably underlying the Yukon-Koyukuk basin and the Yukon flats. The Brooks Range itself is a stack of north vergent nappes, the telescoping of which began in Early Cretaceous time. Despite compelling evidence for thousands of kilometers of relative displacement between the accreted terranes, and large amounts of telescoping, translation, and rotation since accretion, the resulting new continental crust added to North America in Alaska carries few obvious signatures that allow application of currently popular simple plate tectonic models. Intraplate telescoping and strike-slip translations, delamination at mid-crustal levels, and large-scale lithospheric wedging were important processes in northern Cordilleran tectonic evolution.     

A New Approach for Scientific Data Dissemination in Developing Countries: A Case of Indonesia

This short paper is a progress report on our experiences in Indonesia of collecting, integrating and disseminating both global and local scientific data across the country through the web. Our recent efforts are concentrated on improving local public access to global scientific data, and encouraging local scientific data to be more accessible for global communities. We have maintained a well-connected infrastructure and web-based information management systems to realize these objectives. This paper is especially focused on introducing the ARSIP system for mirroring global data and sharing local scientific data, and the newly developed Indonesian Scientific Index for integrating local scientific data through an automated intelligent indexing system.     

The Mechanical Coupling of Fluid-Filled Granular Material Under Shear

The coupled mechanics of fluid-filled granular media controls the physics of many Earth systems, for example saturated soils, fault gouge, and landslide shear zones. It is well established that when the pore fluid pressure rises, the shear resistance of fluid-filled granular systems decreases, and, as a result, catastrophic events such as soil liquefaction, earthquakes, and accelerating landslides may be triggered. Alternatively, when the pore pressure drops, the shear resistance of these geosystems increases. Despite the great importance of the coupled mechanics of grain–fluid systems, the basic physics that controls this coupling is far from understood. Fundamental questions that must be addressed include: what are the processes that control pore fluid pressurization and depressurization in response to deformation of the granular skeleton? and how do variations of pore pressure affect the mechanical strength of the grains skeleton? To answer these questions, a formulation for the pore fluid pressure and flow has been developed from mass and momentum conservation, and is coupled with a granular dynamics algorithm that solves the grain dynamics, to form a fully coupled model. The pore fluid formulation reveals that the evolution of pore pressure obeys viscoelastic rheology in response to pore space variations. Under undrained conditions elastic-like behavior dominates and leads to a linear relationship between pore pressure and overall volumetric strain. Viscous-like behavior dominates under well-drained conditions and leads to a linear relationship between pore pressure and volumetric strain rate. Numerical simulations reveal the possibility of liquefaction under drained and initially over-compacted conditions, which were often believed to be resistant to liquefaction. Under such conditions liquefaction occurs during short compactive phases that punctuate the overall dilative trend. In addition, the previously recognized generation of elevated pore pressure under undrained compactive conditions is observed. Simulations also show that during liquefaction events stress chains are detached, the external load becomes completely supported by the pressurized pore fluid, and shear resistance vanishes.     

Dunes on Titan observed by Cassini Radar

Thousands of longitudinal dunes have recently been discovered by the Titan Radar Mapper on the surface of Titan. These are found mainly within ±30° of the equator in optically-, near-infrared-, and radar-dark regions, indicating a strong proportion of organics, and cover well over 5% of Titan's surface. Their longitudinal duneform, interactions with topography, and correlation with other aeolian forms indicate a single, dominant wind direction aligned with the dune axis plus lesser, off-axis or seasonally alternating winds. Global compilations of dune orientations reveal the mean wind direction is dominantly eastwards, with regional and local variations where winds are diverted around topographically high features, such as mountain blocks or broad landforms. Global winds may carry sediments from high latitude regions to equatorial regions, where relatively drier conditions prevail, and the particles are reworked into dunes, perhaps on timescales of thousands to tens of thousands of years. On Titan, adequate sediment supply, sufficient wind, and the absence of sediment carriage and trapping by fluids are the dominant factors in the presence of dunes.     

Solar rotation, 1966–1978

Photospheric and chromospheric spectroscopic Doppler rotation rates for the full solar disk are analyzed for the period July, 1966 to July, 1978. An approximately linear secular increase of the equatorial rate of 3.7% for these 12 years is found (in confirmation of Howard, 1976). The high latitude rates above 65 ° appear to vary with a peak-to-peak amplitude of 8%, or more, phased to the sunspot cycle such that the most rapid rotation occurs at, or following, solar maximum. The chromosphere, as indicated by H, has continued to rotate on the average 3% faster than the photosphere agreeing with past observations. Sources of error are discussed and evaluated.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.