Multibeam bathymetry and sidescan imaging of the Rivera Transform–Moctezuma Spreading Segment junction, northern East Pacific Rise: New constraints on Rivera–Pacific relative plate motion

To better understand the recent motion of the Pacific plate relative to the Rivera plate and to better define the limitations of the existing Rivera–Pacific plate motion models for accurately predicting this motion, total-field magnetic data, multibeam bathymetric data and sidescan sonar images were collected during the BART and FAMEX campaigns of the N/O L'Atalante conducted in April and May 2002 in the area surrounding the Moctezuma Spreading Segment of the East Pacific Rise, located offshore of Manzanillo, Mexico, at 106°16′W, between 17.8°N and 18.5°N. Among the main results are: (1) the principle transform displacement zone of the Rivera Transform is narrow and well defined east of 107o15′W and these azimuths should be used preferentially when deriving new plate motion models, and (2) spreading rates along the Moctezuma Spreading Segment should not be used in plate motion studies as either seafloor spreading has been accommodated at more than one location since the initiation of seafloor spreading in the area of the Moctezuma Spreading Segment, or this spreading center is not a Rivera–Pacific plate boundary as has been previously assumed. Comparison of observed transform azimuths with those predicted by the best-fit poles of six previous models of Rivera–Pacific relative motion indicate that, in the study area, a significant systematic bias is present in the predictions of Rivera–Pacific motion. Although the exact source of this bias remains unclear, this bias indicates the need to derive a new Rivera–Pacific relative plate motion model.     

A case study of land cover change (1950-2003) and runoff in a Mediterranean catchment

Mediterranean environments have been subject to major land cover change since the end of the second world war. Housing, agricultural activities, forests, green spaces and other land uses have shifted due to urbanisation and tourism. These changes influence runoff, and municipal authorities often cannot estimate the net impact of complex land cover transitions. During this period, elected representatives have become increasingly sensitive to the risks of flooding and have implemented a number of channel management strategies. The main objective of this case study was to analyse the impact of land cover change on total storm runoff between 1950 and 2003 in a Mediterranean catchment near St Tropez, France. A secondary objective was to compare these changes to the impacts of channel management on bankfull discharge. Aerial photographs were used to classify land cover in 3 urban categories, vineyards and bare soil, forests, and green spaces. Stream discharge was estimated using a distributed event based total runoff approach. After validating the model for a large winter event (114 mm) for 1982, runoff was calculated for the same event for 1950 and 2003. Land cover changes occurred mainly in the alluvial plain area. Total gauge catchment urban area increased from 30.1 ha to 393.8 between 1950 and 2003 at the expense mainly of agricultural land, but this was compensated in part by an increase in grassed area. Some of the loss in vineyards was replaced by clearing forested land on the first hills close to the plain. Bank stabilisation and channel maintenance since the 1980’s reduced surface roughness and increased channel area, thereby greatly increasing bankfull discharge. While the impact of urbanisation on runoff was small, channel management effects increased bankfull discharge substantially. Flood damage from extreme events was not studied here.     

Gabbroic intrusions and magmatic metasomatism in harzburgites from the Garrett transform fault: implications for the nature of the mantle–crust transition at fast-spreading ridges

 Mafic and ultramafic rocks sampled in the Garrett transform fault at 13°28′S on the East Pacific Rise (EPR) provide insight on magmatic processes occurring under a fast-spreading ridge system. Serpentinized harzburgite from Garrett have modal, mineral and bulk chemical compositions consistent with being mantle residue of a high degree of partial melting. Along with other EPR localities (Terevaka transform fault and Hess Deep), these harzburgites are among the most residual and depleted in magmatophile elements of the entire mid-ocean ridge system. Geothermometric calculations using olivine-spinel pairs indicate a mean temperature of 759 ± 25 °C for Garrett residual harzburgite similar to the average of 755 °C for tectonite peridotites from slow-spreading ridges. Results of this study show that mid-ocean ridge peridotites are subject to both fractional melting and metasomatic processes. Evidence for mantle metasomatism is ubiquitous in harzburgite and is likely widespread in the entire Garrett peridotite massif. Magma-harzburgite interactions are very well preserved as pyroxenite lenses, plagioclase dunite pockets or dunitic wall rock to intrusive gabbros. Abundant gabbroic rocks are found as intrusive pockets and dikes in harzburgite and have been injected in the following sequence: olivine-gabbro, gabbro, gabbronorite, and ferrogabbro. The wide variety of magmas that crystallized into gabbros contrast sharply with present-day intratransform basalts, which have a highly primitive composition. Ferrogabbro dikes have been intruded at the ridge-transform intersection and as they represent the last event of a succession of gabbros intrusive into the peridotite, they likely constrain the origin of the entire peridotite massif to the same location. In peridotite massifs from Pacific transform faults (Garrett and Terevaka), primitive to fractionated basaltic magmas have flowed and crystallized variable amounts of dunite (±plagioclase) and minor pyroxenite, followed by a succession of cumulate gabbroic dikes which have extensively intruded and modified the host harzburgitic rocks. The lithosphere and style of magmatic activity within a fast-slipping transform fault (outcrops of ultramafic massif, discontinuous gabbro pockets intrusive in peridotite, magnesian and phyric basalts) are more analogous to slow-spreading Mid-Atlantic Ridge type than the East Pacific Rise. Received: 13 October 1997 / Accepted: 5 February 1999     

激光剥蚀-等离子体质谱技术及其在地球化学宇宙化学和环境研究中的应用

激光剥蚀-等离子体质谱(LA-ICPMS)已成为地球化学、宇宙化学和环境研究领域元素和同位素原位分析最重要的技术之一。文章介绍了多种类型的质谱仪及其使用的激光器。用途最广的LA-ICPMS仪器之一是单接收器扇形磁场质谱仪,配有Nd:YAG激光剥蚀系统(激光波长分为193 nm和213 nm两种),MPI Mainz实验室使用的就是这套系统,文章对此作一详细介绍。文中阐述了数据优化技术及其多种校正过程;介绍LA-ICPMS在痕量元素和同位素分析领域的一些应用,包括参考物质的研制,Hawaiian玄武岩、Martian陨石、生物骨针和珊瑚虫中痕量元素分析及熔融包裹体和富钙-铝碳质球粒陨石中的铅和锶同位素测量。     

Influence of food supply on the δ13C signature of mollusc shells: implications for palaeoenvironmental reconstitutions

Compared to oxygen isotopes, the carbon isotope composition of biogenic carbonates is less commonly used as proxy for palaeoenvironmental reconstructions because shell δ¹³C is derived from both dissolved inorganic (seawater) and organic carbon sources (food), and interactions between these two pools make it difficult to unambiguously identify any independent effect of either. The main purpose of this study was to demonstrate any direct impact of variable food supply on bivalve shell δ¹³C signatures, using low/high rations of a ¹³C-light mixed algal diet fed to 14-month-old (adult) cultured Japanese Crassostrea gigas under otherwise essentially identical in vitro conditions during 3 summer months (May, June and July 2003, seawater temperature means at 16, 18 and 20 °C respectively) in experimental tanks at the Argenton laboratory along the Brittany Atlantic coast of France. At a daily ration of 12% (versus 4%) oyster dry weight, the newly grown part of the shells (hinge region) showed significantly lower δ¹³C values, by 3.5‰ (high ration: mean of −5.8  ± 1.1‰, n = 10; low ration: mean of −2.3  ± 0.7‰, n = 6; ANOVA Scheffe’s test, p < 0.0001). This can be explained by an enhanced metabolic activity at higher food supply, raising ¹³C-depleted respiratory CO₂ in the extrapallial cavity. Based on these δ¹³C values and data extracted from the literature, and assuming no carbon isotope fractionation between food and shell, the proportion of shell metabolic carbon would be 26  ± 7 and 5  ± 5% for the high- and low-ration C. gigas shells respectively; with carbon isotope fractionation (arguably more realistic), the corresponding values would be 69  ± 14 and 24  ± 9%. Both groups of cultured shells exhibited lower δ¹³C values than did wild oysters from Marennes-Ol éron Bay in the study region, which is not inconsistent with an independent influence of diet type. Although there was no significant difference between the two food regimes in terms of δ¹⁸O shell values (means of 0.1  ± 0.3 and 0.4  ± 0.2‰ at high and low rations respectively, non-significant Scheffe’s test), a positive δ¹³C vs. δ¹⁸O relationship recorded at high rations supports the interpretation of a progressive temperature-mediated rise in metabolic activity fuelled by higher food supply (in this case reflecting increased energy investment in reproduction), in terms not only of δ¹³C (metabolic signal) but also of δ¹⁸O (seawater temperature signal). Overall, whole-shell δ¹⁸O trends faithfully recorded summer/winter variations in seawater temperature experienced by the 17-month-old cultured oysters.     

Array performances for ambient vibrations on a shallow structure and consequences over <Emphasis Type="Italic">V</Emphasis><Subscript><Emphasis Type="Italic">s</Emphasis></Subscript> inversion

Valuable information about one-dimensional soil structures can be obtained by recording ambient vibrations at the surface, in which the energy contribution of surface waves predominates over the one of other types of waves. The dispersion characteristics of surface waves allow the retrieval of the shear-wave velocity as a function of depth. Microtremor studies are usually divided in two stages: deriving the dispersion (or auto-correlation) curve from the recorded signals and inverting it to obtain the site velocity profile. The possibility to determine the dispersion curve over the adequate frequency range at one site depends on the array aperture and on the wavefield spectra amplitude that can be altered by filtering effects due to the ground structure. Microtremors are usually recorded with several arrays of various apertures to get the spectral curves over a wide frequency band, and different methods also exist for processing the raw signals. With the objective of defining a strategy to achieve reliable results for microtremor on a shallow structure, we analyse synthetic ambient vibrations (vertical component) simulated with 333 broadband sources for a 25-m deep soil layer overlying a bedrock. The first part of our study is focused on the determination of the reliable frequency range of the spectral curves (dispersion or auto-correlation) for a given array geometry. We find that the wavenumber limits deduced from the theoretical array re sponse are good estimates of the valid spectral curve range. In the second part, the spectral curves are calculated with the three most popular noise-processing techniques (frequency–wavenumber, high-resolution frequency–wavenumber and spa tial auto-correlation methods) and inverted indi vidually in each case. The inversions are performed with a tool based on the neighbour hood algorithm that offers a better estimation of the global uncertainties than classical linearised methods, especially if the solution is not unique. Several array apertures are necessary to construct the dispersion (auto-correlation) curves in the appropriate frequency range. Considering the final velocity profiles, the three tested methods are almost equivalent, and no significant advantage was found for one particular method. With the chosen model, all methods exhibit a penetration limited to the bedrock depth, as a consequence of the filtering effect of the ground structure on the vertical component, which was observed in numerous shallow sites.     

Adsorption mechanisms of trivalent gold on iron- and aluminum-(oxy)hydroxides. Part 1: X-ray absorption and Raman scattering spectroscopic studies of Au(III) adsorbed on ferrihydrite, goethite, and boehmite

Gold adsorption products on powdered ferrihydrite, goethite, and boehmite samples, prepared by reacting Au(III)-Cl solutions ([Au] = 4.2 × 10⁻⁵-9.0 × 10⁻³ M; [Cl] = 0.017-0.6 M) with these adsorbents at pH values of 4 to 9 and Au adsorption densities ranging from 0.046 to 1.53 μmol/m² were characterized using Au-L_III XAFS spectroscopy. The solutions (before and after uptake) were investigated by Raman scattering to determine speciation and by Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES) to determine solution composition. We present an analysis of several effects that are observed in the Au L_III-edge XAFS spectra, including X-ray beam-induced photo-reduction, multi-electronic excitations, disorder effects, and multiple scattering, that would complicate interpretation of the spectra if not accounted for. A combination of methods (spectral deconvolution, principal component analysis, spectral inversion, and wavelet analysis) was used to identify and quantify these effects, to characterize the nature of mixed ligands around gold, and to distinguish between multiple-scattering features and features due to next-nearest neighbors in the XAFS spectra.Analysis of the Au-L_III XAFS spectra showed that Au(III) is present as square-planar Au(III)(O,Cl)₄ complexes in the aqueous solutions and on the surfaces of the Al/Fe-(oxy)hydroxide adsorption samples with dominantly O ligands at pH > 6 and mixed O/Cl ligands at lower pH values. The EXAFS-derived Au-O and Au-Cl distances are 2.00(2) and 2.28(2) Å, respectively, and the magnitudes of the Debye-Waller factors and third cumulants from anharmonic analyses indicate very little thermal or positional disorder around Au(III) in the adsorption samples. Iron second neighbors are present around Au in the Au(III)/ferrihydrite and Au(III)/goethite adsorption samples, with Au-Fe distances of 3.1(1) and 3.3(1) Å. In boehmite, two sets of Au-Al distances were detected at 3.0(1) and 3.2(1) Å. A reverse Monte Carlo study of the XAFS spectroscopic data suggests the presence of a continuum of edge-shared AuO₄-FeO₆ distances, which cannot be described correctly by a classical model of these data in which only a mean distance (although severely under-estimated) is derived.     

Quantitative assessment of intertidal blue mussel (Mytilus edulis L.) stocks: combined methods of remote sensing, field investigation and sampling

The aim of this investigation was to develop appropriate methods for quantitative assessment of blue mussel beds. Combined methods of remote sensing, ground truth investigation and sampling in the field were applied to mature and young intertidal mussel beds. Three variables were measured to obtain reliable quantitative estimates of biomass and abundance: the total area covered by a bed; the cover, i.e. the area of mussel-covered patches in relation to the total mussel bed area; and the proportion, i.e. the area covered by mussels within the patches in relation to the total area of mussel patches. Cover and proportion of intertidal blue mussel beds were measured in the field by the transection method. Aerial photographs enabled the total area of the beds to be determined and large-scale surveys of mussel beds to be carried out synchronously. By examining large-scale aerial photographs it was possible also to determine the cover by remote sensing. The proportion could not be derived from aerial photographs, even from pictures at the largest scale tested during this investigation (scale 1:2500). By statistical methods it was estimated that 12 sub-samples (each covering 177 cm²) from mature beds, and 12 sub-samples (each covering 38 cm²) from young beds are needed to obtain reliable data on biomass and abundance.