Characterization of fresh and weathered petroleum for potential impacts to soil fertility

In many petroleum-producing regions, there are not adequate controls to prevent pipeline breaks and spills, and thus soil is frequently contaminated with petroleum hydrocarbons. Different petroleum oil compounds may produce negative impacts on soil fertility. In this study, four fresh crudes, a weathered petroleum, and oils from bioremediated and burned sites were investigated (specific gravities 0.83–1.27). Fourier transform infrared spectroscopy revealed three predominant polar functional groups to be more plentiful in the heavier crudes. The relative abundance of these groups was used to calculate an index that was directly correlated with specific gravity (R ² = 0.9960) and the percent of asphaltene plus (polars + resins) fractions in the oil (R ² = 0.9643). This index correlated exponentially to the water repellency caused by petroleum in an alluvial soil (R ² = 0.9928). Furthermore, extra-heavy oil at a concentration of 10,000 ppm, the maximum allowable oil concentration in the soil that is within regulatory norms in many US states and other countries, and with a specific gravity >1.002, showed severe water repellency. This study presents an alternative for determining soil remediation criteria based on the API gravity of the oil rather than the C-range of the hydrocarbon mixtures, simplifying analytical methods and systematically studying the interaction between the kinds of petroleum mixtures and potential impacts to soil fertility.     

Enhancement of a hypoplastic model for granular soil–structure interface behaviour

Modelling of interfaces in geotechnical engineering is an important issue. Interfaces between structural elements (e.g., anchors, piles, tunnel linings) and soils are widely used in geotechnical engineering. The objective of this article is to propose an enhanced hypoplastic interface model that incorporates the in-plane stresses at the interface. To this aim, we develop a general approach to convert the existing hypoplastic model with a predefined limit state surface for sands into an interface model. This is achieved by adopting reduced stress and stretching vectors and redefining tensorial operations which can be used in the existing continuum model with few modifications. The enhanced interface model and the previous model are compared under constant-load, stiffness and volume conditions. The comparison is followed by a verification of two the approaches for modelling the different surface roughness. Subsequently, a validation between available experimental data from the literature versus simulations is presented. The new enhanced model gives improved predictions by the incorporation of in-plane stresses into the model formulation.