Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

Stratigraphic and geochemical study of the organic-rich black shales in the Tarcău Nappe of the Moldavidian Domain (Carpathian Chain,Romania)

An integrated stratigraphic analysis has been made of the Tarcău Nappe (Moldavidian Domain, Eastern Romanian Carpathians), coupled with a geochemical study of organic-rich beds. Two Main Sequence Boundaries (Early Oligocene and near to the Oligocene–Aquitanian boundary, respectively) divide the sedimentary record into three depositional sequences. The sedimentation occurred in the central area of a basin supplied by different and opposite sources. The high amount of siliciclastics at the beginning of the Miocene marks the activation of the “foredeep stage”. The successions studied are younger than previously thought and they more accurately date the deformation of the different Miocene phases affecting the Moldavidian Basin. The intervals with black shales identified are related to two main separate anoxic episodes with an age not older than Late Rupelian and not before Late Chattian. The most important organic-rich beds correspond to the Lower Menilites, Bituminous Marls and Lower Dysodilic Shales Members (Interval 2). These constitute a good potential source rock for petroleum, with homogeneous Type II oil-prone organic matter, highly lipidic and thermally immature. The deposition of black shales has been interpreted as occurring within a deep, periodically isolated and tectonically controlled basin.     

Simulated decadal oscillations of the Atlantic meridional overturning circulation in a cold climate state

The significance of the Atlantic meridional overturning circulation (MOC) for regional and hemispheric climate change requires a complete understanding using fully coupled climate models. Here we present a persistent, decadal oscillation in a coupled atmosphere–ocean general circulation model. While the present study is limited by the lack of comparisons with paleo-proxy records, the purpose is to reveal a new theoretically interesting solution found in the fully-coupled climate model. The model exhibits two multi-century-long stable states with one dominated by decadal MOC oscillations. The oscillations involve an interaction between anomalous advective transport of salt and surface density in the North Atlantic subpolar gyre. Their time scale is fundamentally determined by the advection. In addition, there is a link between the MOC oscillations and North Atlantic Oscillation (NAO)-like sea level pressure anomalies. The analysis suggests an interaction between the NAO and an anomalous subpolar gyre circulation in which sea ice near and south of the Labrador Sea plays an important role in generating a large local thermal anomaly and a meridional temperature gradient. The latter induces a positive feedback via synoptic eddy activity in the atmosphere. In addition, the oscillation only appears when the Nordic Sea is completely covered by sea ice in winter, and deep convection is active only near the Irminger Sea. Such conditions are provided by a substantially colder North Atlantic climate than today.     

Reducing greenhouse gas emissions from deforestation and forest degradation in developing countries: revisiting the assumptions

The United Nations Framework on Climate Change (UNFCCC), at its thirteenth meeting in 2005 (COP-11), agreed to start a work program to explore a range of policy approaches and positive incentives for Reducing Emissions from Deforestation and Degradation (REDD). This process was further encouraged in the 2007 COP-13 with the explicit consideration of REDD activities as a means to enhance mitigation action by developing countries in the future. This paper outlines the context of this ongoing political process by reviewing the science indicating that land-use change is a key contributor of greenhouse emissions globally and the assumptions that REDD activities may be competitive—in terms of cost effectiveness—in comparison to other mitigation options. The paper then examines REDD proposals submitted by Parties before COP-13 and identifies key economic, technological, methodological and institutional challenges associated with their implementation. These proposals are discussed in the light of major drivers of deforestation and ongoing efforts to address deforestation. This reveals another set of challenges which, if not taken into account, may undermine REDD effectiveness. The paper aims to aid the policy process and contribute to the best possible design of a REDD framework under the future climate regime.     

Taphonomic analysis of small mammal bone remains preyed upon by wildcats (Carnivora: Felidae) from the central Monte Desert (Mendoza,Argentina)

The present study analysed the taphonomic characteristics of small mammal bone accumulations produced by small felids in an area from the central Monte Desert (Mendoza, Argentina). In order to provide criteria to identify the role that these predators had in the formation of zooarchaeological assemblages, the anatomical representation, bone breakage patterns and degrees of digestive corrosion were evaluated. The main taphonomic results are: low average values for the relative abundance of skeletal elements; greater representation of mandibles, maxillae, isolated incisors, humeri and femora than the remaining elements; preponderance of cranial elements with high proportion of isolated teeth; elevated frequencies of proximal limb bones compared with distal parts; high degree of breakage in all skeletal elements and digestive corrosion on almost all diagnostic bones (mainly moderate and heavy). The values of the studied taphonomic variables indicate that small felids in this area made severe alterations to the bones of their prey (mainly rodents), attributable to the category of extreme modifier, while preserving enough skeletal elements to allow their taphonomic characterization. Tooth marks or grooves on bone surfaces produced by scratching and chewing were not detected. The low relative abundance of skeletal elements, the high degree of breakage and the elevated frequency of elements with digestion traces represent general taphonomic patterns that fall within those reported for other South American small carnivores.     

Variscan ore formation and metamorphism at the Felbertal scheelite deposit (Austria): constraining tungsten mineralisation from Re–Os dating of molybdenite

The Felbertal scheelite deposit in the Eastern Alps has been regarded as the type locality for stratabound scheelite deposits. It is hosted by a Cambro-Ordovician metavolcanic arc sequence with minor Variscan granitoids (∼ 340 Ma) in the central Tauern Window. Re–Os model ages for molybdenite from the Felbertal tungsten deposit range between ∼ 358 and ∼ 336 Ma and record several pulses of magmatic-hydrothermal-metamorphic molybdenite formation. Molybdenite ages from the K2 orebody, a scheelite-rich quartz mylonite in the Western ore field, indicate that both mineralisation and mylonite are Variscan in age and suggest that the shear zone was active for ∼ 20 million years. Early stage tungsten mineralisation (Scheelite 1) in quartzitic ores in the Eastern ore field, which is free of molybdenite, yielded very low to near blank levels of Re and Os and thus could not be dated. However, molybdenite from scheelite–quartz stringers, previously interpreted as a feeder stockwork to quartzitic scheelite ore of presumed Cambrian age, yielded Variscan Re–Os ages of ∼ 342 and ∼ 337 Ma. Dating of molybdenite contained in scheelite ores thus far provides no indication of a Cambrian component to the tungsten mineralisation. Our data are consistent with a model of either granite intrusion-related ore formation and coeval metamorphic overprint during the Early Carboniferous or, alternatively, molybdenite formation may be exclusively attributed to Variscan metamorphism (see Stein 2006).     

Analysis of the weightiness of site effects on reinforced concrete (RC) building seismic behaviour: The Adra town example (SE Spain)

The damage distribution in Adra town (south‐eastern Spain) during the 1993 and 1994 Adra earthquakes (5.0 magnitude), that reached a maximum intensity degree of VII (European Macroseismic Scale (EMS scale)), was concentrated mainly in the south‐east zone of the town and the most relevant damage occurred in reinforced concrete (RC) buildings with four or five storeys. In order to evaluate the influence of ground condition on RC building behaviour, geological, geomorphological and geophysical surveys were carried out, and a detailed map of ground surface structure was obtained. Short‐period microtremor observations were performed in 160 sites on a 100m × 100m dimension grid and Nakamura's method was applied in order to determine a distribution map of soil predominant periods. Shorter predominant periods (0.1–0.3 s) were found in mountainous and neighbouring zones and larger periods (greater than 0.5 s) in thicker Holocene alluvial fans. A relationship T = (0.049 ± 0.001)N, where T is the natural period of swaying motion and N is the number of storeys, has been empirically obtained by using microtremor measurements at the top of 38 RC buildings (ranging from 2 to 9 storeys). 1‐D simulation of strong motion on different soil conditions and for several typical RC buildings were computed, using the acceleration record in Adra town of the 1993 earthquake. It is noteworthy that all the aforementioned results show the influence of site effects in the degree and distribution of observed building damage. Copyright © 2007 John Wiley & Sons, Ltd.     

Quantifying the rate and depth dependence of bioturbation based on optically‐stimulated luminescence (OSL) dates and meteoric 10Be

Both the rate and the vertical distribution of soil disturbance modify soil properties such as porosity, particle size, chemical composition and age structure; all of which play an important role in a soil's biogeochemical functioning. Whereas rates of mixing have been previously quantified, the nature of bioturbation's depth dependence remains poorly constrained. Here we constrain, for the first time, the relationship between mixing rate and depth in a bioturbated soil in northeast Queensland, Australia using a novel method combining OSL (optically‐stimulated luminescence) ages and meteoric beryllium‐10 (¹⁰Be) inventories. We find that the best fit mixing rate decreases non‐linearly with increasing soil depth in this soil and the characteristic length scale of 0.28 m over which the mixing coefficient decays is comparable to reported rooting depth coefficients. In addition we show that estimates of surface mixing rates from OSL data are highly dependent on erosion rate and that erosion rate must be constrained if accurate mixing rates are to be quantified. We calculate surface diffusion‐like mixing coefficients of 1.8 × 10^?4 and 2.1 × 10^?4 m² yr^?1 for the studied soil for two different estimates of soil erosion. © 2014 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.