Variability of water mass properties in the last two decades in the South Adriatic Sea with emphasis on the period 2006-2009

Spatially averaged temperature and salinity profiles from individual cruises between 1990 and 2009 were analysed to outline the temporal evolution of water mass properties in the deep convection site in the South Adriatic Pit (SAP). The long-term variability in thermohaline conditions has been explained and related to a close feedback mechanism between the Ionian and the Adriatic Sea. Prominent influences of the Eastern Mediterranean Transient are manifested in changes in the vertical temperature and salinity patterns in the South Adriatic, and the whole studied period was divided into three stages according to the main thermohaline characteristics: 1990-1995, 1995-2004 and the last period from 2005 onwards.Particular attention was given to data collected during 2006-2009, which permitted us to situate the actual thermohaline properties in the context of the decadal variability. This last period was characterised by a very low production of dense water in the northern basin during 2007, while from winter 2008 high production of North Adriatic Deep Water (NAdDW) and Adriatic Deep Water (AdDW) in the northern and southern basins, respectively, was observed. Finally, we used the Optimum Multiparameter Analysis (OMP) to identify the percentages of the different water masses contained in the SAP, and this highlighted some differences between two recent periods studied (2007 and 2008) and the production of dense waters.     

Mössbauer and infrared spectrometry of lizardite-1T from Monte Fico, Elba

A well crystallized and homogeneous specimen of lizardite from Monte Fico, Elba, Italy, has been studied by Mössbauer and Fourier transform infrared (FTIR) spectrometries. One of the aims was the determination of the oxidation state and the distribution of iron in the structure of this reference sample. Mössbauer data indicate the presence of octahedral ferrous iron, octahedral ferric iron and tetrahedral ferric iron (59.9, 31.3 and 8.8% of total iron, respectively). The existence of only one octahedral site, previously suggested by X-ray structure refinement, is confirmed. The occurrence of tetrahedrally coordinated iron is indicated also by FTIR spectrometry, in particular by the presence of an absorption band at 790 cm^–1. Based also on new electron microprobe data, the improved crystal chemical formula for lizardite from Monte Fico is: (Mg_2.74Fe²⁺ _0.10Fe³⁺ _0.05Al_0.11)_Σ=3.00 ?· (Si_1.94Al_0.05Fe³⁺ _0.01)_Σ=2.00O_5.05(OH)_3.95.     

A simulation of the Chilean Coastal Current and associated topographic upwelling near Valparaíso, Chile

A 4-year simulation of the surface circulation driven by the local wind on a section of the central Chilean coast is presented. The model is shown to reproduce the major observed features of the circulation. Comparison to observations of sea-surface temperature (SST) taken within the study area suggests that the model captures well coastal upwelling processes in the region. The circulation is shown to have two distinct modes corresponding to spring/summer and autumn/winter. During spring/summer sustained strong south-westerly wind forcing drives an equatorward coastal jet consistent with the Chile Coastal Current (CCC) and coastal upwelling at previously identified locations of intense upwelling at Topocalma Point and Curaumilla Point. Weaker winds during autumn/winter produce a slower CCC and a more homogenous SST field. Upwelling/relaxation and topographic eddies provide the main sources of variability on sub-seasonal time-scales in the model. The mechanisms responsible for each of these are discussed. Upwelling at Topocalma and Curaumilla Points is shown to be produced through generation of an upwelling Ekman bottom boundary layer following acceleration of the CCC close to the coast, reinforced by secondary circulation due to flow curvature around the headlands. Additional upwelling occurs north of Curaumilla Point due to development of shallow wind-driven overturning flow. Wind-sheltering is shown to be an important factor for explaining the fact that Valparaíso Bay is typically an upwelling shadow. Flow separation and eddy formation within Valparaíso Bay is seen to occur on the order of 10 times per year during relaxation after strong wind events and may persist for a number of weeks. Shorter lived topographic eddies are also seen to occur commonly at Topocalma and Toro Points. These eddies are shown to form in response to the surface elevation minima produced at each of these locations during upwelling.     

Tellurium in rocks

Twenty different rocks have been analyzed for tellurium by atomic absorption. The average tellurium content of 12 igneous rocks is 82 p.p.b., with a range, 3.4 p.p.b. ≥ Te = 210 p.p.b. In ultrabasic rocks, the tellurium content is ? 10 p.p.b. Of the rocks analyzed, carbonates showed the highest Te content, 1–2 p.p.m., and the tellurium concentrations in 6 sedimentary rocks decrease in the following order: carbonates > shales > sandstones.     

3D hydrodynamic characterisation of a meso-tidal harbour: The case of Bilbao (northern Spain)

A background knowledge of marine dynamics helps harbour managers to control pollution and to manage dredging and traffic operations. This contribution studies the hydrodynamic conditions within Bilbao Harbour, which is enclosed by the Nervión Estuary (in the Basque Country, Spain). The results obtained from hydrographical surveys are compared with numerical simulations obtained using the Regional Ocean Modelling System (ROMS). Hydrodynamic modelling was carried out to determine the inner harbour currents for a specific period in which data were available. Then, numerical experiments were designed in order to quantify the importance of different driving mechanisms in the harbour hydrodynamics. The results show that, in addition to the strong tidal influence on water circulation, the wind forcing and freshwater discharge also have a non-negligible influence on the currents. The computational domain is complex due to the presence of harbour infrastructures (i.e. breakwaters and piers). As a result, topographic eddies are therefore observed in the results. The freshwater influence of the Nervión river can also be observed in residual currents. This paper presents an improvement to the application of numerical modelling to a complex geometry domain, contributing to our understanding of the behaviour of the marine systems in meso-tidal harbours. This can be used to deal with harbour engineering and management problems.     

Rainfall regionalization on the basis of the precipitation convective features using a raingauge network and weather radar observations

The main objective of the present paper is to show a methodology for undertaking rainfall regionalization of a region taking into account the convective features of the precipitation, and useful for establishing homogeneous zones for improving the alert system. This methodology has been applied to a hydrographic region located in northeast Spain, with an area of 16000 km² and characterized by a highly contrasted topography. Information provided by meteorological radar and 5-min precipitation data for 126 automatic raingauges has been used for the period 1996–2002. The previous analysis done on the basis of the 1927–1981 rainfall rate series for the Jardí raingauge, located in Barcelona, has also been considered. To that end, the first step was to draw up a proposal for classification of the pluviometric episodes. Recourse was had for this purpose to definition of the β parameter, related with the greater or lesser convective character of the event and calculated on the basis of the rainfall intensity at the surface (Llasat, 2001) and, when data are available, on the basis of radar reflectivity. Results show that the threshold of 35 mm/h to characterize convective episodes from raingauge data can be corroborated from the radar point of view when convective precipitation is identified using 2-D algorithms with a reflectivity threshold of 43 dBZ. Once the soundness of the β parameter had been corroborated, it was applied to more than 2900 precipitation episodes recorded in the region, in order to discriminate the features of the different subregions and their time and space distribution throughout the entire series of the samples. Using this definition, 92% of the precipitation events recorded in this region, with accumulated rainfall above 35 mm, are classified as convective ones, representing 95% of the precipitation amount. Application of the β parameter combined with monthly rainfall data allows differentiation of 8 regions with different convective precipitation features.     

Improving the Abel transform inversion using bending angles from FORMOSAT-3/COSMIC

The FORMOSAT-3/COSMIC satellite constellation has become an important tool toward providing global remote sensing data for sounding of the atmosphere of the earth and the ionosphere in particular. In this study, the electron density profiles are derived using the Abel transform inversion. Some drawbacks of this transform in LEO GPS sounding can be overcome by considering the separability concept: horizontal gradients of vertical total electron content (VTEC) information are incorporated by the inversion method, providing more accurate electron density determinations. The novelty presented in this paper with respect to previous works is the use of the phase change between the GPS transmitter and the LEO receiver as the main observable instead of the ionospheric combination of carrier phase observables for the implementation of separability in the inversion process. Some of the characteristics of the method when applied to the excess phase are discussed. The results obtained show the equivalence of both approaches but the method exposed in this work has the potentiality to be applied to the neutral atmosphere. Recent FORMOSAT-3/COSMIC data have been processed with both the classical Abel inversion and the separability approach and evaluated versus colocated ionosonde data.     

Normal modes of black hole accretion disks

This article studies the hydrodynamical problem of normal modes of small adiabatic oscillations of relativistic barotropic thin accretion disks around black holes (and compact weakly magnetic neutron stars). Employing Wentzel-Kramers-Brillouin (WKB) techniques, we obtain the eigenfrequencies and eigenfunctions of the modes for different values of the mass and angular momentum of the central black hole. We discuss the properties of the various types of modes and show for the first time that modes covering the whole extension of the disk (full-disk p-modes) can exist within the studied thin disk model. However, these modes have relatively short wavelengths.