Identification of Anthropogenic Features Through Application of Principal Component Analysis to Hydrochemical Data from the Sines Coastal Aquifer, SW Portugal

The Sines coastal sedimentary basin, a tectonic trough with a NE-SW orientation filled with Mesozoic and Cenozoic deposits, has two hydrogeological systems: the Mio-Pliocene and the Jurassic. Both systems are supplying water to the entire region with highly populated and industrialized areas. The aquifers are recharged in the outcrop areas, although the Jurassic aquifer also receives some contribution from the overlying Miocene rocks. The main groundwater flow direction in the Jurassic aquifer is E to W towards the Atlantic Ocean. In order to understand the influence of anthropogenic activities on the water quality, a statistical principal components analysis (PCA) was performed on the physical–chemical data from groundwater samples in both aquifers. Four components were obtained in the Jurassic and three in the Miocene. The principal components analyses indicate water–rock interactions as the major mechanism responsible for the groundwater solutes (mainly calcium-bicarbonate type), from the calcareous and dolomitic units. Anthropogenic contamination was identified in the influence of the water compositions, corresponding to local polluting inputs. These were magnesium, sulfate, nitrate, iron and copper for PC 3 in the Jurassic and sodium, chloride, nitrate and manganese for PC 2 in the Miocene. These account for about 13% of the system total variance in the Jurassic aquifer and near 23% in the Miocene one.     

Origin of the Rubian carbonate-hosted magnesite deposit, Galicia, NW Spain: mineralogical, REE, fluid inclusion and isotope evidence

The Rubian magnesite deposit (West Asturian—Leonese Zone, Iberian Variscan belt) is hosted by a 100-m-thick folded and metamorphosed Lower Cambrian carbonate/siliciclastic metasedimentary sequence—the Cándana Limestone Formation. It comprises upper (20-m thickness) and lower (17-m thickness) lens-shaped ore bodies separated by 55 m of slates and micaceous schists. The main (lower) magnesite ore body comprises a package of magnesite beds with dolomite-rich intercalations, sandwiched between slates and micaceous schists. In the upper ore body, the magnesite beds are thinner (centimetre scale mainly) and occur between slate beds. Mafic dolerite dykes intrude the mineralisation. The mineralisation passes eastwards into sequence of bedded dolostone (Buxan) and laminated to banded calcitic marble (Mao). These show significant Variscan extensional shearing or fold-related deformation, whereas neither Rubian dolomite nor magnesite show evidence of tectonic disturbance. This suggests that the dolomitisation and magnesite formation postdate the main Variscan deformation. In addition, the morphology of magnesite crystals and primary fluid inclusions indicate that magnesite is a neoformed hydrothermal mineral. Magnesite contains irregularly distributed dolomite inclusions (<50 μm) and these are interpreted as relics of a metasomatically replaced dolostone precursor. The total rare earth element (REE) contents of magnesite are very similar to those of Buxan dolostone but are depleted in light rare earth elements (LREE); heavy rare earth element concentrations are comparable. However, magnesite REE chondrite normalised profiles lack any characteristic anomaly indicative of marine environment. Compared with Mao calcite, magnesite is distinct in terms of both REE concentrations and patterns. Fluid inclusion studies show that the mineralising fluids were MgCl₂–NaCl–CaCl₂–H₂O aqueous brines exhibiting highly variable salinities (3.3 to 29.5 wt.% salts). This may be the result of a combination of fluid mixing, migration of pulses of variable-salinity brines and/or local dissolution and replacement processes of the host dolostone. Fluid inclusion data and comparison with other N Iberian dolostone-hosted metasomatic deposits suggest that Rubian magnesite probably formed at temperatures between 160 and 200°C. This corresponds, at hydrostatic pressure (500 bar), to a depth of formation of ~~5 km. Mineralisation-related Rubian dolomite yields δ ¹⁸O values (δ ¹⁸O: 12.0–15.4‰, mean: 14.4±1.1‰) depleted by around 5‰ compared with barren Buxan dolomite (δ ¹⁸O: 17.1–20.2‰, mean: 19.4±1.0‰). This was interpreted to reflect an influx of ¹⁸O-depleted waters accompanied by a temperature increase in a fluid-dominated system. Overlapping calculated δ ¹⁸O_fluid values (~+5‰ at 200°C) for fluids in equilibrium with Rubian dolomite and magnesite show that they were formed by the same hydrothermal system at different temperatures. In terms of δ ¹³C values, Rubian dolomite (δ ¹³C: −1.4 to 1.9‰, mean: 0.4±1.3‰) and magnesite (δ ¹³C: −2.3 to 2.4‰, mean: 0.60±1.0‰) generally exhibit more negative δ ¹³C values compared with Buxan dolomite (δ ¹³C: −0.2 to 1.9‰, mean: 0.8±0.6‰) and Mao calcite (δ ¹³C: −0.3 to 1.5‰, mean: 0.6±0.6‰), indicating progressive modification to lower δ ¹³C values through interaction with hydrothermal fluids. ⁸⁷Sr/⁸⁶Sr ratios, calculated at 290 Ma, vary from 0.70849 to 0.70976 for the Mao calcite and from 0.70538 to 0.70880 for the Buxan dolostone. The ⁸⁷Sr/⁸⁶Sr ratios in Rubian magnesite are more radiogenic and range from 0.71123 to 0.71494. The combined δ ¹⁸O–δ ¹³C and ⁸⁷Sr/⁸⁶Sr data indicate that the magnesite-related fluids were modified basinal brines that have reacted and equilibrated with intercalated siliciclastic rocks. Magnesite formation is genetically linked to regional hydrothermal dolomitisation associated with lithospheric delamination, late-Variscan high heat flow and extensional tectonics in the NW Iberian Belt. A comparison with genetic models for the Puebla de Lillo talc deposits suggests that the formation of hydrothermal replacive magnesite at Rubian resulted from a metasomatic column with magnesite forming at higher fluid/rock ratios than dolomite. In this study, magnesite generation took place via the local reaction of hydrothermal dolostone with the same hydrothermal fluids in very high permeability zones at high fluid/rock ratios (e.g. faults). It was also possibly aided by additional heat from intrusive dykes or sub-cropping igneous bodies. This would locally raise isotherms enabling a transition from the dolomite stability field to that of magnesite.Editorial handling: F. Tornos     

The identification of an active fault by a multidisciplinary study at the archaeological site of Sagalassos (SW Turkey)

The archaeological site of Sagalassos (SW Turkey) is located in a region characterized by the absence of any significant recent seismic activity, contrary to adjacent regions. However, the assessment of earthquake-related damage at the site suggests that the earthquakes that have been demonstrated to have struck this Pisidian city in ca. AD 500 and in the middle or second half of the 7th century AD are characterized by an MSK intensity of at least VIII and occurred on a fault very close to the city. Different investigation techniques (archaeoseismology, remote sensing and geomorphology, surface geology and structural data, 2D resistivity imaging and palaeoseismological trenching) have been applied at the archaeological site and its direct surroundings in search for the causative fault of these earthquakes. This multidisciplinary approach shows that each of the different approaches independently provides only partial, non-conclusive information with respect to the fault identification. Integration is imperative to give a conclusive answer in the search for the causative fault. This study has, indeed, revealed the existence of a to date unknown active normal fault system passing underneath ancient Sagalassos, i.e. the Sagalassos fault. A historical coseismic surface rupture event on this fault could be identified. This event possibly corresponds to the devastating Sagalassos earthquakes of ca. AD 500 and the middle or second half of the 7th century AD. Finally, this study demonstrates that in the particular geodynamic setting of SW Turkey archaeological sites with extensive earthquake-related damage form an important tool in any attempt to asses the seismic hazard.     

Application of the Mussel Watch concept in studies of the distribution of hydrocarbons in the coastal zone of the Ebro Delta

The Mussel Watch concept was applied in a study of man-induced chemical changes in the Ebro Delta on the Catalonian coast to obtain a preliminary assessment of the distribution of synthetic organic compounds, petroleum and biogenic hydrocarbons in the local coastal zone. Mussels, oysters and clams were selected as the indicator organisms. Levels of petroleum accumulated by mussels were generally high, in the order of 100–800 μg^?1 dry weight, equivalent to those in mussels in the most polluted harbours and bays of California. The relative distributions of the steranes and pentacyclic triterpanes in the mussels were significantly different from those found in petroleum from a local field, indicating that local petroleum was not contributing to the present contamination. The composition of biogenic compounds was variable, probably reflecting differences in the composition of local plankton communities, PCB levels were high in relation to current levels in mussels from US sites, reflecting continuing PCB use in Spain. The Delta appears to be a point source of a number of organochlorine compounds, including HCB, the DDT compounds, endrin and γ-chlordane. Levels of the DDT compound o,p′-DDD, a pharmacologically active substance, were unexpectedly high; identification was confirmed by GS/MS. Many unidentified peaks were present on EC chromatograms, indicating a more complex pattern of contamination than might be suggested by printed summaries of data.     

Majorite formation from enstatite by experimental shock-loading

Majorite has been observed for the first time after experimental shock-loading of enstatite (Bamle, Norway). The identification of this high pressure garnet has been carried out by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction experiments, majorite formation was indicated by these techniques for the pressure range between ca. 35 and 50 GPa. This also proves formation of majorite by impact metamorphosis in the Coorara meteorite as well as terrestrial formation of that phase by the same process.     

Time‐geographic Derivation of Feasible Co‐presence Opportunities from Network‐constrained Episodic Movement Data

Certain datasets on moving objects are episodic in nature – that is, the data is characterized by time gaps during which the position of the object is unknown. In this article, a model is developed to study the sparsely sampled network‐constrained movement of several objects by calculating both potential and feasible (i.e. more likely) co‐presence opportunities over time. The approach is applied to the context of a static sensor network, where the location of an object is only registered when passing a sensor location along a road network. Feasibility is incorporated based on the deviation from the shortest path. As an illustration, the model is applied to a large Bluetooth tracking dataset gathered at a mass event. The model output consists of maps showing the temporal evolution of the distribution of feasible co‐presence opportunities of tracked visitors over the network (i.e. the number of visitors that could have been present together). We demonstrate the model's usefulness in studying the movement and distribution of a crowd over a study area with relatively few sampling locations. Finally, we discuss the results with a special emphasis on the distinction between feasible and actual presence, the need for further validation and calibration, and the performance of the implementation.     

Large biases and inconsistent climate change signals in ENSEMBLES regional projections

In this paper we analyze some caveats found in the state-of-the-art ENSEMBLES regional projections dataset focusing on precipitation over Spain, and highlight the need of a task-oriented validation of the GCM-driven control runs. In particular, we compare the performance of the GCM-driven control runs (20C3M scenario) with the ERA40-driven ones (“perfect” boundary conditions) in a common period (1961–2000). Large deviations between the results indicate a large uncertainty/bias for the particular RCM-GCM combinations and, hence, a small confidence for the corresponding transient simulations due to the potential nonlinear amplification of biases. Specifically, we found large biases for some RCM-GCM combinations attributable to RCM in-house problems with the particular GCM coupling. These biases are shown to distort the corresponding climate change signal, or “delta”, in the last decades of the 21st century, considering the A1B scenario. Moreover, we analyze how to best combine the available RCMs to obtain more reliable projections.     

The ecological fallacy in a time series context: evidence from Spanish regional unemployment rates

The ecological fallacy (EF) is a common problem regional scientists have to deal with when using aggregated data in their analyses. Although there is a wide number of studies considering different aspects of this problem, little attention has been paid to the potential negative effects of the EF in a time series context. Using Spanish regional unemployment data, this paper shows that EF effects are not only observed at the cross-section level, but also in a time series framework. The empirical evidence obtained shows that analytical regional configurations are the least susceptible to time effects relative to both normative and random regional configurations, while normative configurations are an improvement over random ones.