Isotopic and noble gas study of Chalk groundwater in the London Basin, England

The chemical and isotopic composition of groundwater from 52 sites in the London (U.K.) area was determined as part of a project aimed at assessing the spatial variation in the age of Chalk groundwater, and in determining the relationship between fracture and matrix groundwater in this dual porosity system.Systematic changes in groundwater chemistry take place in the downgradient direction in response to several chemical processes. These processes include early concentration by evaporation and congruent dissolution of calcite followed by widespread incongruent dissolution and ion exchange in addition to local oxidation-reduction reactions, gypsum dissolution and saline intrusion. As a result of the above processes, Chalk groundwater follows an evolutionary path from Ca bicarbonate type to Na bicarbonate type.The age of Chalk groundwater was modelled using¹⁴C, δ¹³C,³H, δ²H and δ¹⁸0. There is a general increase in the groundwater age in a downgradient direction with the oldest water found in N central areas of the basin. Groundwater in the unconfined zones and in areas S of the Greenwich fault is almost entirely of unevolved, modem composition. Carbon-14 modelling suggests that Chalk groundwater in the S basin is generally less than 10000 a old while that in the north is generally between 10000 and 25000 a old. The presence of³H in concentrations of up to 7 TU in groundwater which yields ages of several 1000 a, however, indicates that mechanisms exist for the rapid introduction of recent groundwater to the confined aquifer. Results of palaeorecharge temperature determinations using δ²H, δ¹⁸0 and noble gas analytical results suggest that significant Devensian recharge did indeed occur in the aquifer.A model of the development of the Chalk recognizes that it is a classic dual porosity aquifer in which groundwater flow occurs predominantly in the fracture system. The upper 50 m of the aquifer was flushed with fresh water during the 2–3 × 10⁶ a of the Quaternary and therefore meteoric water largely replaced the Tertiary and Cretaceous marine water that previously saturated the system. Most processes which control the chemistry of the groundwater occur in the matrix where the surface area is exceptionally high. Although fracture flow dominates the flow regime, diffusion from the matrix into the fracture porosity controls the chemistry of Chalk groundwater.     

内蒙古温带半干旱羊草草原N2O通量及其影响因素

利用静态箱 -气相色谱法于 2 0 0 1～ 2 0 0 3年对内蒙古锡林河流域羊草草原进行了连续 2年的野外定位试验 ,获得羊草草原原状群落与土壤N2 O年排放通量分别在 3 91～ 4 71μgm- 2h- 1以及 5 5 0～ 10 0 3μgm- 2 h- 1范围内变动 ,证明内蒙古温带半干旱羊草草原生态系统是大气中N2 O的源 ;系统分析了羊草草原N2 O通量的季节变化、源汇特征以及关键的环境因子对草地N2 O通量的影响等 ,建立了N2 O通量与环境因子间的回归方程 ;并利用两年连续完整的观测数据对羊草草原N2 O年排放量进行了估算     

Hydrological trends and the evolution of catchment research in the Alptal valley,central Switzerland

When the observation of small headwater catchments in the pre-Alpine Alptal valley (central Switzerland) started in the late 1960s, the researchers were mainly interested in questions related to floods and forest management. Investigations of geomorphological processes in the steep torrent channels followed in the 1980s, along with detailed observations of biogeochemical and ecohydrological processes in individual forest stands. More recently, research in the Alptal has addressed the impacts of climate change on water supply and runoff generation. In this article, we describe, for the first time, the evolution of catchment research at Alptal, and present new analyses of long-term trends and short-term hydrologic behaviour. Hydrometeorological time series from the past 50 years show substantial interannual variability, but only minimal long-term trends, except for the ~2°C increase in mean annual air temperature over the 50-year period, and a corresponding shift towards earlier snowmelt. Similar to previous studies in larger Alpine catchments, the decadal variations in mean annual runoff in Alptal's small research catchments reflect the long-term variability in annual precipitation. In the Alptal valley, the most evident hydrological trends were observed in late spring and are related to the substantial change in the duration of the snow cover. Streamflow and water quality are highly variable within and between hydrological events, suggesting rapid shifts in flow pathways and mixing, as well as changing connectivity of runoff-generating areas. This overview illustrates how catchment research in the Alptal has evolved in response to changing societal concerns and emerging scientific questions.     

OSL and 14C chronologies of a Holocene sedimentary record (Garding‐2 core) from the German North Sea coast

The history of sea‐level change and sediment accumulation since the last deglaciation along the German North Sea coast is still controversial because of a limitation in the quantity and quality of chronological data. In the current study, the chronology of a 16‐ka coastal sedimentary record from the Garding‐2 core, retrieved from the Eiderstedt Peninsula in Schleswig‐Holstein, northern Germany, was established using OSL and AMS ¹⁴C dating techniques. The robust chronology using 14 radiocarbon and 25 OSL dates from the Garding‐2 core is the first long‐term record that covers the Holocene as well as the last deglaciation period in one succession in the German North Sea area. It provides a new insight into understanding the Holocene transgression and coastal accumulation histories. The combined evidence from the sedimentology and chronology investigations indicates that an estuarine environment dominated in Eiderstedt Peninsula from 16 to 13 ka, followed by a depositional hiatus between 13 and 8.3 ka, attributed to erosion caused by the Holocene transgression; the onset of the Holocene transgression at the core site occurred at around 8.3 ka. The sea level continued to rise with a decelerated rate until around 3 ka. Since 3 ka, the shoreline has begun to prograde. Foreshore (tidal flat) sediments have been deposited at the drilling site with a very high sedimentation rate of about 10 m ka^?1. At around 2 ka, a sandy beach deposit accumulated in the sedimentary succession, indicating that the coastline shifted landward, which may represent a small‐scale transgression in the late Holocene. At around 1.5 ka, terrestrial clastic sediment started to accumulate, indicating a retreat of the relative sea level in this area, which may be related to local diking activities undertaken since the 11th century.     

Dating fluvial erosion: fluvial response to climate change in the Moselle catchment (France,Germany) since the Late Saalian

This paper focuses upon the youngest terraces of the Moselle and its tributary the Meurthe (NE France and SW Germany). It includes research on several sections, in particular the key sections of Golbey‐Pré Droué and Thörnich‐Hochrech (located in the vicinity of the Vosges Massif and in the Rhenish Massif, respectively), and the use of the Optically Stimulated Luminescence (OSL) dating method. Our investigations made it possible to obtain a more robust chronostratigraphical framework and to update the previous model of fluvial response to climate change. The results demonstrate that the Moselle terrace M3 (first terrace formed after the capture of the Upper Moselle by the Palaeo‐Meurthe) has the same age from the Vosges to the Rhenish Massif. The formation of this terrace included two main periods of sedimentation attributed to the Late Saalian (MIS 6) and the Early Weichselian (MIS 5), respectively. They were separated by a major episode of fluvial erosion that may be allocated to the MIS 6–5 transition on the basis of chronological and sedimentological evidence. This erosion led to the removal of most of the MIS 6 deposits, whereas the MIS 5 deposits have been widely preserved following the subsequent (MIS 5–4) terrace incision. This evolution somewhat contrasts with that observed in the Sarre valley, the main tributary of the Moselle, and with many fluvial systems in western Europe, which show better preservation of deposits from cold periods. This atypical behaviour is explained by the relationship between the fluvial evolution and the glaciers covering the upper Moselle catchment (Vosges Massif) during the Pleistocene cold periods.     

Climate control on the evolution of Late Pleistocene alluvial‐fan and aeolian sand‐sheet systems in NW Germany

The Late Pleistocene was characterized by rapid climate oscillations with alternation of warm and cold periods that lasted up to several thousand years. Although much work has been carried out on the palaeoclimate reconstruction, a direct correlation of ice‐core, marine and terrestrial records is still difficult. Here we present new data from late Middle Pleniglacial to Lateglacial alluvial‐fan and aeolian sand‐sheet deposits in northwestern Germany. Records of Late Pleniglacial alluvial fans in central Europe are very rare, and OSL dating is used to determine the timing of fan aggradation. In contrast to fluvial systems that commonly show a delay between climate change and incision/aggradation, the small alluvial‐fan systems of the Senne area responded rapidly to climatic changes and therefore act as important terrestrial climate archives for this time span. The onset of alluvial‐fan deposition correlates with the climate change from warm to cold at the end of MIS 3 (29.3±3.2 ka). Strong fan progradation started at 24.4±2.8 ka and may be related to a period of higher humidity. The vertical stacking pattern of sedimentary facies and channel styles indicate a subsequrent overall decrease in water and sediment supply, with less sustained discharges and more sporadic runoffs from the catchment area, corresponding to an increasing aridity in central Europe during the Late Pleniglacial. Major phases of channel incision and fan aggradation may have been controlled by millennial‐scale Dansgaard–Oeschger cycles. The incision of channel systems is attributed to unstable climate phases at cold–warm (dry–wet) or warm–cold (wet–dry) transitions. The alluvial‐fan deposits are bounded by an erosion surface and are overlain by aeolian sand‐sheets that were periodically affected by flash‐floods. This unconformity might be correlated with the Beuningen Gravel Bed, which is an important marker horizon in deposits of the Late Pleniglacial resulting from deflation under polar desert conditions. The deposition of aeolian sand‐sheet systems (19.6±2.1 to 13.1±1.5 ka) indicates a rapid increase in aridity at the end of the Late Pleniglacial. Intercalated flash‐floods deposits and palaeosols (Finow type) point to temporarily wet conditions during the Lateglacial. The formation of an ephemeral channel network probably marks the warm‐cold transition from the Allerød to the Younger Dryas.     

Horizontal and vertical winds and temperatures in the equatorial thermosphere: Measurements from Natal,Brazil during August–September 1982

Fabry-Perot interferometer measurements of Doppler shifts and widths of the 630.0 nm nightglow line have been used to determine the neutral winds and temperatures in the equatorial thermosphere over Natal, Brazil during August–September 1982. During this period, in the early night (2130 U.T.) the average value of the horizontal wind vector was 95 m s^?1 at 100° azimuth, and the temperature varied from a low of 950 K during geomagnetically quiet conditions to a high of ~ 1400 K during a storm (6 September). The meridional winds were small, ?, 50 m s^?1, and the eastward zonal winds reached a maximum value 1–3 h after sunset, in qualitative agreement with TGCM predictions. On 26 August, an observed persistent convergence in the horizontal meridional flow was accompanied by a downward vertical velocity and an increase in the thermospheric temperature measured overhead. Oscillations with periods of 40–45 min in both the zonal and vertical wind velocities were observed during the geomagnetic storm of 6 September, suggesting gravity wave modulation of the equatorial thermospheric flow.     

Interaction of interstellar pick-up ions with the solar wind

The interaction of interstellar pick-up ions with the solar wind is studied by comparing a model for the velocity distribution function of pick-up ions with actual measurements of He⁺ ions in the solar wind. The model includes the effects of pitch-ang'e diffusion due to interplanetary Alfvén waves, adiabatic deceleration in the expanding solar wind and the radial variation of the source function. It is demonstrated that the scattering mean free path is in the range 0.1 AU and that energy diffusion can be neglected as compared with adiabatic deceleration. The effects of adiabatic focusing, of the radial variation of the neutral density and of a variation of the solar wind velocity with distance from the Sun are investigated. With the correct choice of these parameters we can model the measured energy spectra of the pick-up ions reasonably well. It is shown that the measured differential energy density of the pick-up ions does not vary with the solar wind velocity and the direction of the interplanetary magnetic field for a given local neutral gas density and ionization rate. Therefore, the comparison of the model distributions with the measurements leads to a quantitative determination of the local interstellar gas density.Paper dedicated to Professor Hannes Alfvén on the occasion of his 80th birthday, 30 May 1988.