(Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes at high pressure: influence of cation substitution on elastic behavior and phase transition

A compressional study of (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxenes was carried out at high pressures between 10⁻⁴ and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti³⁺–Ti³⁺ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi³⁺Si₂O₆. Equation-of-state parameters are K ₀ = 115.9(7) GPa with K′ = −0.9(3) and K ₀ = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P [`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character. The influence of the coupled substitution Na⁺Ti³⁺↔Ca²⁺Mg²⁺ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate composition (Na_0.54Ca_0.46)(Mg_0.46Ti_0.54)Si₂O₆. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K ₀ = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi₂O₆ and reveal major similarities. The main driving force for the phase transition in NaTi³⁺Si₂O₆ is the localization of the Ti³⁺ d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxene.     

KINEMATICS OF QUATERNARY EXTENSION IN THE PAMIR

KINEMATICS OF QUATERNARY EXTENSION IN THE PAMIR1　BurtmanVS ,MolnarP .GeologicalandgeophysicalevidencefordeepsubductionofcontinentalcrustbeneaththePamir[J].SpecPapGeolSocAm ,1993,2 81:76 . 2　StreckerMR ,FrischW ,HamburgerMW ,etal.QuaternarydeformationintheEasternPamirs ,TadzhikistanandKyrgyzs tan[J].Tectonics,1995 ,14(5 ) :10 6 1～ 10 79.…     

Assimilation of Earth rotation parameters into a global ocean model: length of day excitation

Changes in the oceanic current system and in the oceanic mass distribution alter, together with other processes, the state of the Earth’s rotation. This state is characterized by the length of day (LOD) and the tilt of the pole-to-pole axis. The aim of our study was to derive the respective governing physical mechanisms in the ocean. Therefore, Earth rotation observations were assimilated into a global circulation model of the ocean. Although assimilation is a well-established tool in climate science, the assimilation of Earth rotation observations into a global ocean model was done here for the first time. Prior to the assimilation, the Earth rotation observations were projected onto the angular momentum of the ocean. Non-oceanic contributions were removed. The result of the subsequent assimilation procedure is a time varying ocean model state that reproduces the projected Earth rotation observations well. This solution was studied to understand the oceanic generation of Earth rotation deviations and to identify governing physical mechanisms. This paper focuses on LOD anomalies although polar motion was assimilated simultaneously. Our results indicate that changes in the oceanic LOD excitation are mostly attributed to changes in total ocean mass. Changes in the spatial distribution of ocean mass turned out to have a minor contribution to the LOD deviations. The same applies to changes in the current system.     

Managing Groundwater to Ensure Ecosystem Function

Groundwater is a critical resource not only for human communities but also for many terrestrial, riparian, and aquatic ecosystems and species. Yet groundwater planning and management decisions frequently ignore or inadequately address the needs of these natural systems. As a consequence, ecosystems dependent on groundwater have been threatened, degraded, or eliminated, especially in arid regions. There is growing acknowledgment that governmental protections for these ecological resources are necessary, but current legal, regulatory and voluntary provisions are often inadequate. Groundwater management premised on “safe yield,” which aims to balance human withdrawals with natural recharge rates, typically provides little to no consideration for water needed by ecosystems. Alternatively, the “sustainable yield” concept aims to integrate social, economic and environmental needs for groundwater, but the complexity of groundwater systems creates substantial uncertainty about the impact that current or future groundwater withdrawals will have on ecosystems. Regardless of the legal or regulatory framework, guidance is needed to help ensure environmental water needs will be met, especially in the face of pressure to increase human uses of groundwater resources. In this paper, we describe minimum provisions for planning, managing, and monitoring groundwater that collectively can lower the risk of harm to groundwater-dependent ecosystems and species, with a special emphasis on arid systems, where ecosystems and species may be especially reliant upon and sensitive to groundwater dynamics.     

Evolution of photoautotrophy and early atmospheric oxygen levels

Current photochemical models suggest that oxygen levels in the prebiological atmosphere were extremely low, most probably remaining in the range 10⁻⁸–10⁻¹⁴ PAL (present atmospheric level). It is, therefore, reasonable to assume that only life processes were able to overwhelm these minor O₂-pressures, with free oxygen resulting from the reduction of carbon dioxide to the carbohydrate level during photoautotrophic carbon fixation using water as an electron donor (

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). It is by now well established that reduced (organic) carbon is a common constituent of sedimentary rocks from the very start of the geological record 3.8 Ga ago. Both direct assays and inferences derived from a carbon isotope mass balance suggest that the C_org-content of Archaean sediments was not basically different from that of geologically younger rocks. This poses the problem of the existence 3.5 Ga ago of an oxidation equivalent of such a formidable ancient C_org-reservoir which, depending on the model adopted for the growth of the sedimentary mass through time, might have amounted to between 20 and 100% of the present one. Low atmospheric oxygen pressures in the Early Precambrian that are inferred from retarded oxidation reactions, notably in the ancient continental weathering cycle, are likely, therefore, to indicate extremely rapid processes of oxygen consumption in other parts of the system (e.g., hydrosphere) rather than the general absence of photosynthetic oxidation equivalents during this time.