Inorganic and organic nitrogen cycling in the Southern California Bight

On the basis of mass balance calculations performed for nitrogen (N) uptake experiments in the Southern California Bight (SCB), it has been suggested that a significant portion of dissolved inorganic N (DIN) uptake results in the production of dissolved organic N (DON). To investigate this process, the fate of ammonium (NH₄⁺) and nitrate (NO₃⁻) uptake was quantified within the euphotic zone at three coastal stations in the SCB using ¹⁵N tracer techniques. Several trends in the fate of DIN and the production of DON were observed. First, production of particulate N (PN), from both NH₄⁺ and NO₃⁻, was quantitatively more important in near surface waters, while DON release dominated within the nitracline. Second, the percentage of gross N uptake released as DON was generally higher when NO₃⁻, rather than NH₄⁺, was the substrate. Third, the percentage of N released as DON was higher at night, relative to the day. Fourth, rates of DON release were significantly correlated to NH₄⁺ regeneration, suggesting that similar mechanisms are responsible for both processes—presumably grazing. The results of this study indicate that the DON pool is a sink for DIN uptake on the time scale of hours. One implication of this finding is that new production estimates based on ¹⁵NO₃⁻ uptake rates will likely underestimate particle flux out of the surface layer because the rate of NO₃⁻ uptake is underestimated due to loss of DO¹⁵N during the incubation. On time scales of months to years, however, the N that is taken up as NO₃⁻ and released as DON will likely contribute to export flux via incorporation of the dissolved phase during seasonal mixing into sinking particles or transport. The export of DON on these time scales argues for the use of gross uptake rates to calculate f-ratios.     

Anak Krakatau — a colonization model within a colonization model?

The ppaer re-examines three suggestions previously made concerning the colonization of the Krakatau islands since the extirpating 1883 eruption that involve the more recently emergent volcanic island Anak Krakatau, which itself suffered a devastating eruption in 1952. The suggestions re-addressed in the light of recent comments by other workers are:

Verification of a coupled climate-hydrological model against Holocene palaeohydrological records

We have coupled a climate model (ECBilt-CLIO-VECODE) and a hydrological model (STREAM) offline to simulate palaeodischarge of nineteen rivers (Amazon, Congo, Danube, Ganges, Krishna, Lena, Mackenzie, Mekong, Meuse, Mississippi, Murray–Darling, Nile, Oder, Rhine, Sacramento–San Joaquin, Syr Darya, Volga, Volta, Zambezi) for three time-slices: Early Holocene (9000–8650 BP), Mid-Holocene (6200–5850 BP) and Recent (1750–2000 AD). To evaluate the model's skill in retrodicting broad changes in mean palaeodischarge we have compared the model results with palaeodischarge estimates from multi-proxy records. We have compared the general trends inferred from the proxy data with statistical differences in modelled discharge between the three periods, thereby developing a technique to assess the level of agreement between the model and proxy data. The quality of the proxy data for each basin has been classed as good, reasonable or low. Of the model runs for which the proxy data were good or reasonable, 72% were in good agreement with the proxy data, and 92% were in at least reasonable agreement. We conclude that the coupled climate-hydrological model performs well in simulating mean discharge in the time-slices studied. The discharge trends inferred from the proxy and model data closely follow latitudinal and seasonal variations in insolation over the Holocene. For a number of basins for which agreement was not good we have identified specific mechanisms which could be responsible for the discrepancy, primarily the absence of the Laurentide ice sheet in our model. In order to use the model in an operational sense within water management studies it would be useful to use a higher spatial resolution and a daily time-step.     

Implementing Digital Imaging for Improved Understanding of Microfine Cement Grout Permeation and Filtration

Geotechnical and Geological Engineering - Permeation grouting is a ground improvement method commonly used for strengthening and/or reducing permeability of soils with minimal disturbance to the...     

Characterizing and predicting essential habitat features for juvenile coastal sharks

The successful management of shark populations requires juvenile recruitment success. Thus, conservation initiatives now strive to include the protection of areas used by pre‐adult sharks in order to promote juvenile survivorship. Many shark species use inshore areas for early life stages; however, species often segregate within sites to reduce competition. Using a fisheries‐independent gillnet survey from the Northern Gulf of Mexico (2000–2010) we describe distribution patterns and preferred habitat features of the juveniles of six shark species. Our results suggest that multiple shark species concurrently use the area for early life stages and although they overlap, they exhibit distinct habitat preferences characterized by physical variables. Habitat suitability models suggest that temperature, depth, and salinity are the important factors driving juvenile shark occurrence. Within each site, across the sampled range of physical characteristics, blacktip shark (Carcharhinus limbatus) preferred higher temperature (>30 °C) and mid‐depth (~5.5 m); bonnethead shark (Sphyrna tiburo) preferred higher temperature (>30 °C) and mid‐salinity (30–35 PSU), finetooth shark (Carcharhinus isodon) preferred low salinity (<20 PSU) with mid‐depth (~4 m), scalloped hammerhead shark (Sphyrna lewini) preferred high temperature (>30 °C) and salinity (>35 PSU), Atlantic sharpnose shark (Rhizoprionodon terraenovae) preferred high temperature (>30 °C) and deep water (>6 m), and spinner shark (Carcharhinus brevipinna) preferred deep water (>8 m) and high temperature (>30 °C). The other investigated factors, including year, month, latitude, longitude, bottom type, inlet distance, coastline and human coast were not influential for any species. Combining habitat preferences with the sampled environmental characteristics, we predicted habitat suitability throughout the four sites for which physical characteristics were sampled. Habitat suitability surfaces highlight the differences in habitat use between and within sites. This work provides important insight into the habitat ecology of juvenile shark populations, which can be used to better manage these species and protect critical habitat.     

GAUGE: the GrAnd Unification and Gravity Explorer

The GAUGE (GrAnd Unification and Gravity Explorer) mission proposes to use a drag-free spacecraft platform onto which a number of experiments are attached. They are designed to address a number of key issues at the interface between gravity and unification with the other forces of nature. The equivalence principle is to be probed with both a high-precision test using classical macroscopic test bodies, and, to lower precision, using microscopic test bodies via cold-atom interferometry. These two equivalence principle tests will explore string-dilaton theories and the effect of space–time fluctuations respectively. The macroscopic test bodies will also be used for intermediate-range inverse-square law and an axion-like spin-coupling search. The microscopic test bodies offer the prospect of extending the range of tests to also include short-range inverse-square law and spin-coupling measurements as well as looking for evidence of quantum decoherence due to space–time fluctuations at the Planck scale.     

Advance,deglacial and sea‐level chronology for Foxe Peninsula,Baffin Island,Nunavut

The impact of the Laurentide Ice Sheet (LIS) deglaciation on Northern Hemisphere early Holocene climate can be evaluated only once a detailed chronology of ice history and sea‐level change is established. Foxe Peninsula is ideally situated on the northern boundary of Hudson Strait, and preserves a chronostratigraphy that provides important glaciological insights regarding changes in ice‐sheet position and relative sea level before and after the 8.2 ka cooling event. We utilized a combination of radiocarbon ages, adjusted with a new locally derived ΔR, and terrestrial in‐situ cosmogenic nuclide (TCN) exposure ages to develop a chronology for early‐Holocene events in the northern Hudson Strait. A marine limit at 192 m a.s.l., dated at 8.1–7.9 cal. ka BP, provides the timing of deglaciation following the 8.2 ka event, confirming that ice persisted at least north of Hudson Bay until then. A moraine complex and esker morphosequence, the Foxe Moraine, relates to glaciomarine outwash deltas and beaches at 160 m a.s.l., and is tightly dated at 7.6 cal. ka BP with a combination of shell dates and exposure ages on boulders. The final rapid collapse of Foxe Peninsula ice occurred by 7.1–6.9 cal. ka BP (radiocarbon dates and TCN depth profile age on an outwash delta), which supports the hypothesis that LIS melting contributed to the contemporaneous global sea‐level rise known as the Catastrophic Rise Event 3 (CRE‐3).     

Groundwater transport of crater-lake brine at Poa´s Volcano, Costa Rica

Poa´s Volcano is an active stratovolcano in Costa Rica that has a lake in its active crater. The crater lake has high temperatures (50–90 °C), high acidity (pH ≈ 0.0), and a high dissolved-solids content (100 g/kg). The volcano has numerous freshwater springs on its flanks, but a few on the northwestern flank are highly acidic (pH = 1.6–2.5) and have high dissolved-solids concentrations (2–22 g/kg). This study analyzes the regional groundwater system at Poa´s and demonstrates the likelihood that the water discharging from the acidic springs in the Rio Agrio watershed originates at the acidic crater lake. Both heat and solute transport are analyzed on a regional scale through numerical simulations using the HST3D finite-difference model, which solves the coupled equations for fluid flow, heat transport, and solute transport. The code allows fluid viscosity and density to be functions of both temperature and solute concentration. The simulations use estimates for recharge to the mountain and a range of values and various distributions of permeability and porosity. Several sensitivity analyses are performed to test how the uncertainty in many of the model parameters affects the simulation results. These uncertainties yield an estimated range of travel times from the crater lake to the Rio Agrio springs of 1–30 years, which is in close agreement with the results of tritium analyses of the springs. Calculated groundwater fluxes into and out of the crater lake are both about several hundred kg/s. These fluxes must be accounted for in water budgets of the crater lake.