Mineralogy and major-element geochemistry of the lower Permian Greta Seam,Sydney Basin,Australia

The mineralogy of the high-volatile bituminous coals and associated strata from the Greta seam, Sydney Basin, Australia, has been evaluated in this study. Although the seam is not immediately overlain by marine strata, percolation of marine water into the original peat bed is indicated by the petrological, mineralogical and geochemical characteristics, which resemble those of coals with marine roof strata. The upper and lower sections of the seam have contrasting mineralogy. Pyrite typically comprises 40 to 56 wt% of the mineral assemblage in the marine-influenced upper part of the seam section. The lower part contains much less pyrite (typically <5 wt%, organic-free basis), and also relatively abundant dawsonite (up to 14 wt%, organic-free basis). The minerals within most coal plies are largely of authigenic origin. These include pyrite, siderite, clay minerals (mainly kaolinite and Na-rich mixed-layer illite/smectite), and quartz, most of which have a relatively early, syngenetic origin. Minor Ti-bearing minerals, anatase or rutile, and phosphate minerals, fluorapatite and goyazite, were probably also formed during early diagenesis. Other minerals have features that indicate late-stage precipitation. These include abundant cleat- and fracture-filling dawsonite, which may be the result of reactions between earlier-precipitated kaolinite and Na₂CO₃- or NaHCO₃-bearing fluids. Minor albite may also be epigenetic, possibly precipitated from the same Ca–Al bearing fluids that formed the dawsonite. The most abundant detrital minerals in the Greta coals are quartz, poorly ordered kaolinite, illite and mixed-layer illite/smectite (I/S). These occur mainly in the floor, roof and other epiclastic horizons of the seam, reflecting periods of greater clastic influx into those parts of the original peat-forming environment. Detrital minerals are rare in the coals away from the epiclastic horizons, probably owing to almost complete sediment bypassing in the depositional system. Alternatively, any detrital minerals that were originally present may have been leached from the peat bed by diagenetic or post-diagenetic processes.     

Assessment of the effects of climate and land cover changes on river discharge and sediment yield,and an adaptive spatial planning in the Jakarta region

In Jakarta, climate change has been detected through rising air temperatures, increased intensity of rainfall in the wet season, and sea level rise. The coupling of such changes with local anthropogenic driven modifications in the environmental setting could contribute to an increased probability of flooding, due to increase in both extreme river discharge and sedimentation (as a result of erosion in the watersheds above Jakarta and as indicated by sediment yield in the downstream area). In order to respond to the observed and projected changes in river discharge and sediment yield, and their secondary impacts, adaptation strategies are required. A possible adaptation strategy is through policy making in the field of spatial planning. For example, in Indonesia, presidential regulation number 54 year 2008 (Peraturan Presiden Nomor 54 Tahun 2008—Perpres 54/2008) was issued as a reference for the implementation of water and soil conservation. This paper assesses the impact of climate and land cover change on river discharge and sediment yield, as well as the effects of Perpres 54/2008 on that river discharge and sediment yield. The spatial water balance model Spatial Tools for River Basins and Environmental and Analysis of Management Option was used for the runoff computations, whilst the Spatial Decision Assistance of Watershed Sedimentation model was used to simulate erosion, Sediment Delivery Ratio, and sediment yield. The computation period is from January 1901 to December 2005, at the scale of the following watersheds: Ciujung, Cisadane, Ciliwung, and Citarum. During the twentieth century, computed average discharge in the downstream area (near Jakarta) increased between 2.5 and 35 m³/s/month, and sediment yield increased between 1 × 10³ and 42 × 10³ tons/year. These changes were caused by changes in both land cover and climate, with the former playing a stronger role. Based on a computation under a theoretical full implementation of the spatial plan proposed by Perpres 54/2008, river discharge would decrease by up to 5 % in the Ciliwung watershed and 26 % in the Cisadane watershed. The implementation of Perpres 54/2008 could also decrease the sediment yield, by up to 61 and 22 % in the Ciliwung and Cisadane watersheds, respectively. These findings show that the implementation of the spatial plan of Perpres 54/2008 could significantly improve watershed response to runoff and erosion. This study may serve as a tool for assessing the reduction in climate change impacts and evaluating the role of spatial planning for adaptation strategies.     

Sediment and particulate phosphorus characteristics in grassed waterways from row crop corn and alfalfa fields collected by manual University of Exeter samplers and automatic sampling

Phosphorus (P) export from agricultural lands above known threshold levels can result in adverse impacts to receiving water quality. Phosphorus loss occurs in dissolved and sediment‐bound, or particulate phosphorous (PP), forms, with the latter often dominating losses from row‐cropped systems. To target practices, land managers need good computer models and model developers need good monitoring data. Sediment monitoring data (e.g. radiometric finger printing and sediment P sorption capacity) can help identify sediment source areas and improve models, but require more sediment mass than is typically obtained by automatic sampling. This study compares a simple suspended sediment sampler developed at the University of Exeter (UE) with automatic sampling in intermittent channels draining corn and alfalfa fields. The corn field had a greater runoff coefficient (27%) than alfalfa (11%). No differences were found in enrichment ratios (sediment constituent/soil constituent) in PP (PP_ER) or percent loss on ignition (LOI_ER) between paired UE samplers on corn. The median LOI_ER for the UE samplers (1·9%) did not differ significantly (p > 0·13) from the automatic sampler (2·0%). The PP_ER from the UE samplers was on average 20% lower than the automatic samplers. A correlation (r² = 0·75) was found between sediment PP and % LOI from automatic samplers and UE samplers for particles < 50 µm, while for > 50 µm PP concentration did not change with changes in % LOI. Sediment ammonium‐oxalate extractable metals were similarly related to LOI, with the strongest correlation for iron (r² = 0·71) and magnesium (r² = 0·70). Copyright © 2011 John Wiley & Sons, Ltd.     

Effects of metals and sediment particle size on the species composition of the epifauna of Pinna bicolor near a lead smelter,Spencer Gulf,South Australia

Pinna bicolor (Mollusca: Pelecypoda) were transplanted between four sites near a lead smelter. The species composition of their epifauna (sessile and mobile) was examined in relation to characteristics of both sediments and seston at the sites. Seventy-two taxa were distinguished in the epifaunal community. Substantial differences were found in the short-term sensitivity of some of the species to concentrations of Cd, Pb and Zn in sediments and to sediment particle size. The short-term sensitivity of many species to metals or sediment particle size explained their long-term distribution pattern. Twenty-three taxa were identified as significantly characterizing the faunal differences. Of these, eleven (four molluscs, four bryozoans, two barnacles and one ascidian) were affected by both sediment metal concentration and particle size, and eight (four molluscs, one bryozoan, one polychaete, one hydroid and one barnacle) were affected by metal contamination but not particle size. Of all fauna examined, the Bryozoa were the most metal-sensitive. Four species, Smittina raigii (Bryozoa), Galeolaria sp. 1 (Polychaeta), Epopella simplex (Cirripedia) and Monia ione (Pelecypoda) were identified by their short- and long-term sensitivity to metal contamination, and absence of sensitivity to sediment particle size, as suitable species for monitoring the effects of metal contamination on the epifauna. The implications of the results for toxicity-testing are discussed.     

Investigating the central engine of ultraluminous infrared galaxies: near-infrared imaging

We present 0.5-arcsec-resolution near-infrared images of six ultraluminous infrared galaxies with known redshifts. Six of the eight bright nuclei are resolved on kiloparsec scales, suggesting that there is significant circumnuclear star formation or close progenitor nuclei. At this spatial resolution, the nuclei have very red colours that cannot in general be reproduced by reddening stellar light, but require an additional component of hot dust emission. In five of the six primary nuclei more than 20 per cent of the K -band continuum originates in hot dust, but the temperature cannot be determined by JHK broad-band colours alone. Comparison with the spectral shapes, however, does allow the temperature to be constrained, and we find in every case that it is at the upper end of the permissible range, ≳1000 K. This does not necessarily imply that there is an active galactic nucleus present, since there is evidence that stellar processes can also generate dust this hot via stochastic heating of small grains. The quantities of hot dust we have found here can make up to 0.5-mag difference to the K -band magnitude even at     , with implications for observations and population synthesis models of higher-redshift objects. Observations in the L or M bands, where hot dust is most important at     , could help to discriminate between models of dusty starbursts and ellipticals.     

Solar nebula dispersal and the stability of the planetary system: I. Scanning secular resonance theory

Secular resonances in the early solar system are studied in an effort to establish constraints on the time scale and/or method of solar nebula dispersal. Simplified nebula models and dispersal routines are employed to approximate changes in an assumed axisymmetric nebula potential. These changes, in turn, drive an evolutionary sequence of Laplace-Lagrange solutions for the secular variations of the solar system. A general feature of these sequences is a sweep of one or more giant planet resonances through the inner solar system. Their effect is rate dependent; in the linearized models considered, characteristic dispersal times ≤O(10^4?5 years) are required to avoid the generation of terrestrial eccentricities and inclinations in excess of observed values. These times are short compared to typical estimates of the accretion time scales [i.e., ～O(10^7?9 years)] and may provide an important boundary condition for developing models of nebula dispersal and solar system formation in general.     

Speculation on martian north polar wind circulation and the resultant orientations of polar sand dunes

Dunes in the Martian north polar erg show two dominant orientations. When seen at frost cap minimum, dunes north of 80°N record east winds, dunes south of 80°N record west winds. Many of the transverse dunes are considered to be reversing dunes. Dunes in two fields may have reversed at least once during the lifetime of the Viking Orbiters. Poor agreement exists among published predictive models of north polar winds and the interpretations derived from the major published map of the north polar dunes. We propose that the average polar winds are: (1) strong, off-pole northwest winds in fall; (2) moderate west winds in winter; (3) latitude-dependent weak to strong off-pole northeast winds in spring; and (4) weak west winds in summer. Viking images of near-polar clouds confirm much of the hypothesis. Images discussed in other studies can be given alternative interpretations that support this hypothesis also. Over millenia, the combination of reversing west and east winds could produce the binodal distributions of dune orientations observed at the north pole.