La turbulence isentropique latérale dans le tourbillon circulaire

Résumé La turbulence latérale étant considérée comme un mouvement d'agitation à deux dimensions dans les surfaces isentropiques, on établit successivement le tenseur deReynolds et le taux de production de l'énergie cinétique de turbulence.

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Summary Assuming lateral mixing as a two-dimensional eddy motion in isentropic surfaces, theReynolds' tensor and the rate of production of kinetic energy of turbulence are established.

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Zusammenfassung Auf Grund der Annahme, daß der Gleitaustausch als zweidimensionale Austauschbewegung in isentropen Flächen angesehen werden kann, werden der Tensor vonReynolds und der Betrag der kinetischen Turbulenzenergie abgeleitet, die in der Einheit von Volumen und Zeit erzeugt wird.

     

Hydrogeophysical approach for contamination assessment in NamSon landfill,Hanoi, Vietnam

Self potential (SP) and electrical resistivity tomography (ERT) methods are used together with the results of groundwater samples hydrogeochemical analysis to assess the impact of the water leak from the landfill garbage site at NamSon located in Northern Hanoi on causing pollution to the surrounding environment and affecting geological structure. Selected survey area covers an area of 180 × 300 m lying in the low land of the NamSon site with a slope ranging about 8 m in direction NW–SE. There are three geophysical measurements lines denoted as T1, T2 and T3. Processing 180 SP data points has allowed to draw maps of equipotential epoch in the two periods in 2015 and 2016. The maps show four zones of SP positive anomalies with maximum amplitudes of about +20 mV where the groundwater flow direction is downward and five zones of SP negative anomalies with minimum values in a range from ?180 to ?260 mV where the groundwater flow direction is upward. Resistivity values of the subsurface layers of soils and rocks have been aquired from 2D inverse model for measuring ERT in March 2015 and March 2016. The results of the ERT allowed to define the low resistivity in the range 15–20 Ωm related to leachate plume from NamSon landfill site. Results of the physico-chemical analysis of groundwater samples from the existing six boreholes show increases in concentration of the measured pollutant parameters indicating contamination of the groundwater as a result of solid waste leachate accumulation. This result is affirmative evidence for the survey results by geophysical technique. The rapid decrease in quality of groundwater over the last year is probably due to the influence of the leachate from the NamSon landfill site.     

Recent plumbing system of the Krakatau volcano revealed by teleseismic earthquake distribution

Spatial and temporal analysis of global seismological data 1964–2005 reveals a distinct teleseismic earthquake activity producing a columnar-like formation in the continental wedge between the Krakatau volcano at the surface and the subducting slab of the Indo-Australian plate. These earthquakes occur continuously in time, are in the body-wave (m _b) magnitude range 4.5–5.3 and in the depth range 1–100 km. The Krakatau earthquake cluster is vertical and elongated in the azimuth N30°E, suggesting existence of a deep-rooted fault zone cutting the Sunda Strait in the SSW-NNE direction. Possible continuation of the fault zone in the SW direction was activated by an intensive 2002/2003 aftershock sequence, elongated in the azimuth of N55°E. Beneath the Krakatau earthquake cluster, an aseismic gap exists in the Wadati-Benioff zone of the subducting plate at the depths 100–120 km. We interpret this aseismic gap as a consequence of partial melting inhibiting stress concentration necessary to generate stronger earthquakes, whereas the numerous earthquakes observed in the overlying lithospheric wedge beneath the volcano probably reflect magma ascent in the recent plumbing system of the Krakatau volcano. Focal depth of the deepest events (~100 km) of the Krakatau cluster constrains the location of the primary magma generation to greater depths. The ascending magmatic fluids stress fault segments within the Sunda Strait fault zone and change their friction parameters inducing the observed tectonic earthquakes beneath Krakatau.     

Comparative study of tracer diffusion of HTO, Na and Cl in compacted kaolinite, illite and montmorillonite

The through-diffusion of HTO, ²²Na⁺ and ³⁶Cl⁻ in kaolinite, homo-ionic Na-illite and homo-ionic Na-montmorillonite was measured at a high degree of compaction as a function of the salt concentration in the ‘external solution’, i.e. in the solution in contact with the clay sample. The clays were chosen for this study because of their differences in the number and nature of ion exchange sites leading to different proportions of interlayer-, inter-particle and free pore water. It was found that the diffusive mass transfer of Na⁺ in Na-montmorillonite and Na-illite increased with decreasing external salt concentration, while the opposite trend was observed for the diffusion of Cl⁻. These trends are more pronounced in the case of Na-montmorillonite than in Na-illite, while almost no salt effect was observed for kaolinite. Similarly no salt effect was observed for the diffusion of HTO through all of the clays tested. These observations are in agreement with a conceptual model where it is assumed that cations diffuse preferentially in the interlayer or diffuse double-layer porosity, while anions are almost completely excluded from these regions. In the case of Na⁺ diffusion, the salt effects can be explained by an influence on the concentration gradient of diffusing cations, while in the case of Cl⁻ the external salt concentration has an effect on the accessible porosity. Effective diffusion coefficients of Cl⁻ fulfil the same relationship to porosity as those of the uncharged HTO, when using accessible porosities for such a comparison. Furthermore it is shown that pore diffusion coefficients for the three tracers are fairly well correlated with the respective diffusion coefficients in bulk water, if the effective diffusion coefficients for Na⁺ are derived from calculated tracer concentration gradients in the interlayer or diffuse double-layer porosities.     

A numerical diffusion model for continuous releases

The purpose of this study was to develop a diffusion model for a continuous point source which takes into account the increase of wind speed with height, and to compare this model with short-range diffusion experiments. The main problem was to find a good expression for the vertical diffusion coefficient. It turned out that good agreement between theory and experiment could only be obtained by introducing a settling speed W for the tracer combined with a conventional expression for the vertical diffusion (K(Z) = K ₀Z^1−p). An empirical relation was found between K ₀ and τ _vU and between W and bar σ _vU².     

Carbon sources in arc volcanism, with implications for the carbon cycle

New CO₂/³ He data from the East Sunda Arc (Indonesia) confirm earlier observations that arc volcanic gases have higher CO₂/³ He ratios than MOR environments.On average, > 80% of arc volcanic CO₂ is recycled, exogene carbon. Addition of a few percent of carbonate-bearing sediments to the mantle wedge explains much of the carbon abundance andcarbon isotopic data of arc gases, but can not explain the He isotope observations. The CO₂/³He in arc volcanoes is not strongly dependent on the composition of modem trough sediments (e.g. deep sea clays vs carbonate-rich sequences), and calcite veins in the hydrothermally altered subducted slab may provide a contribution to the recycled carbon flux of, arcs. The sum of globally deep-subducted sediment and slab carbon exceeds the estimated arc CO₂ flux, and approximately 3.5 teramole of carbon may return annually to the mantle in convergent zones. The modem combined processes of MOR volcanism, slab alteration, and subduction volcanism do not produce a substantial carbon flux into the exosphere, and rate-changes in ocean floor spreading are unlikely to cause major changes in atmospheric CO₂ as a result of changes in the volcanic CO₂ fluxes. Intense pulses of flood basalt volcanism, however, may alter the CO₂ contents of the atmosphere over the course of a millenium or so, and influence global climate.     

Solubility of manganotantalite, zircon and hafnon in highly fluxed peralkaline to peraluminous pegmatitic melts

The behavior of tantalum and zirconium in pegmatitic systems has been investigated through the determination of Ta and Zr solubilities at manganotantalite and zircon saturation from dissolution and crystallization experiments in hydrous, Li-, F-, P- and B-bearing pegmatitic melts. The pegmatitic melts are synthetic and enriched in flux elements: 0.7–1.3 wt% Li₂O, 2–5.5 wt% F, 2.8–4 wt% P₂O₅ and 0–2.8 wt% B₂O₃, and their aluminum saturation index ranges from peralkaline to peraluminous (ASI_Li = Al/[Na + K + Li] = 0.8 to 1.3) with various K/Na ratios. Dissolution and crystallization experiments were conducted at temperatures varying between 700 and 1,150°C, at 200 MPa and nearly water-saturated conditions. For dissolution experiments, pure synthetic, end member manganotantalite and zircon were used in order to avoid problems with slow solid-state kinetics, but additional experiments using natural manganotantalite and zircon of relatively pure composition (i.e., close to end member composition) displayed similar solubility results. Zircon and manganotantalite solubilities considerably increase from peraluminous to peralkaline compositions, and are more sensitive to changes in temperature or ASI of the melt than to flux content. A model relating the enthalpy of dissolution of manganotantalite to the ASI_Li of the melt is proposed: ∆H _diss (kJ/mol) = 304 × ASI_Li − 176 in the peralkaline field, and ∆H _diss (kJ/mol) = −111 × ASI_Li + 245 in the peraluminous field. The solubility data reveal a small but detectable competitivity between Zr and Ta in the melt, i.e., lower amounts of Zr are incorporated in a Ta-bearing melt compared to a Ta-free melt under the same conditions. A similar behavior is observed for Hf and Ta. The competitivity between Zr (or Hf) and Ta increases from peraluminous to peralkaline compositions, and suggests that Ta is preferentially bonded to non-bridging oxygens (NBOs) with Al as first-neighbors, whereas Zr is preferentially bonded to NBOs formed by excess alkalies. As a consequence Zr/Ta ratios, when buffered by zircon and manganotantalite simultaneously, are higher in peralkaline melts than in peraluminous melts.     

Determination of lower and upper bounds of predicted production from history-matched models

We present a method to determine lower and upper bounds to the predicted production or any other economic objective from history-matched reservoir models. The method consists of two steps: 1) performing a traditional computer-assisted history match of a reservoir model with the objective to minimize the mismatch between predicted and observed production data through adjusting the grid block permeability values of the model. 2) performing two optimization exercises to minimize and maximize an economic objective over the remaining field life, for a fixed production strategy, by manipulating the same grid block permeabilities, however without significantly changing the mismatch obtained under step 1. This is accomplished through a hierarchical optimization procedure that limits the solution space of a secondary optimization problem to the (approximate) null space of the primary optimization problem. We applied this procedure to two different reservoir models. We performed a history match based on synthetic data, starting from a uniform prior and using a gradient-based minimization procedure. After history matching, minimization and maximization of the net present value (NPV), using a fixed control strategy, were executed as secondary optimization problems by changing the model parameters while staying close to the null space of the primary optimization problem. In other words, we optimized the secondary objective functions, while requiring that optimality of the primary objective (a good history match) was preserved. This method therefore provides a way to quantify the economic consequences of the well-known problem that history matching is a strongly ill-posed problem. We also investigated how this method can be used as a means to assess the cost-effectiveness of acquiring different data types to reduce the uncertainty in the expected NPV.     

Fluidization of buried mass-wasting deposits in lake sediments and its relevance for paleoseismology: Results from a reflection seismic study of lakes Villarrica and Calafquén (South-Central Chile)

A dense grid of very-high resolution seismic profiles on Lake Villarrica provides a quasi-3D view on intercalated lenses of low-amplitude reflections, which are connected by acoustic wipe-out patches and fractures to an underlying voluminous mass-wasting deposit. The lenses are interpreted as being created by earthquake-triggered liquefaction in this buried mass-wasting deposit and subsequent sediment fluidization and extrusion at the paleo-lake bottom. These sediment volcanoes are mapped in detail. They have a rather uniform circular geometry and show a linear relationship between apparent width and maximum thickness on a seismic section. The largest sediment volcanoes are up to 80 m wide and 1.9 m thick. Their slope angles designate a syn- to post-depositional sagging of most sediment volcanoes. Sediment volcano detection and mapping from nearby Lake Calafquén further strengthen the revealed geometrical relationships. Locally, some of the sediment/fluid escape structures extend to a higher position in the stratigraphy, which points to a polyphase escape process associated with multiple multi-century spaced strong earthquakes. Thickness and morphology of the source layer seem to exert a dominant control in the production of sediment/fluid extrusions. This study shows that reflection seismic profiling allowed recognizing 4 different seismic events in the studied stratigraphic interval, which are evidenced by mass-wasting deposits and/or fluidization features.