Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.     

Zinc speciation in the Northeastern Atlantic Ocean

Measurements of zinc and zinc complexation by natural organic ligands in the northeastern part of the Atlantic Ocean were made using cathodic stripping voltammetry with ligand competition. Total zinc concentrations ranged from 0.3 nM in surface waters to 2 nM at 2000 m for open-ocean waters, whilst nearer the English coast, zinc concentrations reached 1.5 nM in the upper water column. In open-ocean waters zinc speciation was dominated by complexation to a natural organic ligand with conditional stability constant (log K_ZnL′) ranging between 10.0 and 10.5 and with ligand concentrations ranging between 0.4 and 2.5 nM. The ligand was found to be uniformly distributed throughout the water column even though zinc concentrations increased with depth. Organic ligand concentrations measured in this study are similar to those published for the North Pacific. However the log K_ZnL′ values for the North Atlantic are almost and order of magnitude lower than those reported by Bruland [Bruland, K.W., 1989. Complexation of zinc by natural organic-ligands in the central North Pacific. Limnol. Oceanogr., 34, 269–285.] using anodic stripping voltammetry for the North Pacific. Free zinc ion concentrations were low in open-ocean waters (6–20 pM) but are not low enough to limit growth of a typical oceanic species of phytoplankton.     

Upper temperature tolerances of exotic brackish-water mussel, Mytilopsis leucophaeata (Conrad): an experimental study

The dark false mussel, Mytilopsis leucophaeata is an important mussel colonising the brackish-water systems of temperate and subtropical regions. Of late it has earned notoriety as a biofouling species in industrial cooling water systems. However, there are no published data on the temperature tolerance of this species. This paper presents data on the upper temperature tolerance of this mussel from the view point of biofouling control using thermal methods. In addition to mortality, response of physiological activities such as oxygen consumption, filtration rate, foot activity and byssus thread production were also studied at temperatures varying from 5 to 35 degrees C. Experiments were also carried out to understand the effect of mussel size, breeding condition, nutritional status and acclimation conditions (temperature and salinity) on the mortality pattern. The physiological activities were significantly reduced at temperatures beyond 27.5 degrees C and ceased at 35 degrees C. In 20 mm size group mussels exposed to 37 degrees C, 50% mortality was observed after 85 min and 100% mortality after 113 min. The effect of mussel size on mortality at different temperatures was significant, with the larger size group mussels showing greater resistance. M. leucophaeata collected during the non-breeding season (December-April) were more tolerant to temperature than those collected during the breeding season (June-October). Nutritional status of the mussel had no significant influence on the thermal tolerance of the mussel: fed and starved (non-fed) mussels succumbed to temperature at comparable rates. The effect of acclimation temperature and acclimation salinity on M. leucophaeata mortality at different temperatures was significant. Survival time increased with increasing acclimation temperature and decreased with increasing salinity. In comparison with other co-occurring species such as Mytilus edulis and Dreissena polymorpha, M. leucophaeata appears to be more tolerant to high temperature stress.     

Morphology of the Wadati-Benioff zone,andesitic volcanism,and active fracture zones in Central America

Summary The morphology of the Wadati-Benioff zone in the region of Central America, based on the distribution of 1377 earthquake foci, verified the existence of an intermediate aseismic gap and its relation to active andesitic volcanism, and the non-uniformity of subduction due to the hampering effect of the main structural features of the subducting Cocos plate. Four deep seismically active fracture zones, genetically connected with the process of subduction, and three fracture zones manifesting the possible boundary between the Americas and Caribbean plates were identified in the continental wedge.     

Deep seismically active fracture zones in ecuador and northern peru

Summary A system of 8 seismically active fracture zones was delineated on the basis of the distribution of earthquake foci in the continental lithosphere of Ecuador. The position and width of the outcrop, thickness, dip and maximum depth of the individual fracture zones were estimated and correlated with surface geological and tectonic phenomena, volcanism and hydrothermal manifestations. The existence and strike of the fracture zones was independently confirmed by the occurrence of historical disastrous earthquakes.

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Visiting professors at Instituto Geofísico and Facultad de Geología, Minas y Petróleos, Escuela Politécnica Nacional, Quito (Ecuador).     

Age and significance of voluminous mafic–ultramafic magmatic events in the Murchison Domain,Yilgarn Craton

Mafic–ultramafic rocks in structurally dismembered layered intrusions comprise approximately 40% by volume of greenstones in the Murchison Domain of the Youanmi Terrane, Yilgarn Craton. Mafic–ultramafic rocks in the Murchison Domain may be divided into five components: (i) the ～2810 Ma Meeline Suite, which includes the large Windimurra Igneous Complex; (ii) the 2800 ± 6 Ma Boodanoo Suite, which includes the Narndee Igneous Complex; (iii) the 2792 ± 5 Ma Little Gap Suite; (iv) the ～2750 Ma Gnanagooragoo Igneous Complex; and (v) the 2735–2710 Ma Yalgowra Suite of layered gabbroic sills. The intrusions are typically layered, tabular bodies of gabbroic rock with ultramafic basal units which, in places, are more than 6 km thick and up to 2500 km² in areal extent. However, these are minimum dimensions as the intrusions have been dismembered by younger deformation. In the Windimurra and Narndee Igneous Complexes, discordant features and geochemical fractionation trends indicate multiple pulses of magma. These pulses produced several megacyclic units, each ～200 m thick. The suites are anhydrous except for the Boodanoo Suite, which contains a large volume of hornblende gabbro. They also host significant vanadium mineralisation, and at least minor Ni–Cu–PGE mineralisation. Collectively, the areal distribution, thickness and volume of mafic–ultramafic magma in these complexes is similar to that in the 2.06 Ga Bushveld Igneous Complex, and represents a major addition of mantle-derived magma to Murchison Domain crust over a 100 Ma period. All suites are demonstrably contemporaneous with packages of high-Mg tholeiitic lavas and/or felsic volcanic rocks in greenstone belts. The distribution, ages and compositions of the earlier mafic–ultramafic rocks are most consistent with genesis in a mantle plume setting.     

Search for H2 Emission from Disks around T Tauri and Herbig AE Stars

Preliminary results are presented of observations of the pure rotational lines of H2 toward T Tauri and Herbig Ae stars using the Short Wavelength Spectrometer (SWS) on the Infrared Space Observatory (ISO). The sources are selected to be isolated low- and intermediate-mass young stellar objects, for which the presence of a circumstellar disk has been established by millimeter interferometry. The lowest H2 S(0) and S(1) lines are detected in 3 out of 5 objects. The measured intensities indicate ∼ 0.01 M⊙ of warm (T ≈ 150 K) gas in the ISO beam. It is argued that for at least one case (HD 163296), the emission is probably dominated by the warm gas in the circumstellar disk rather than by shocked- or photon-heated gas in the surrounding envelope. Such observations can provide important constraints on the radial and vertical temperature profiles in circumstellar disks. This revised version was published online in August 2006 with corrections to the Cover Date.     

Radiative decay of the 4d5(6S)5p z5,7Po states in Tc ii: comparison along the homologous and isoelectronic sequences. Application to astrophysics

Using three independent theoretical approaches (CA, HFR + CP, AUTOSTRUCTURE), oscillator strengths have been calculated for a set of Tc  ii transitions of astrophysical interest and the reliability of their absolute scale has been assessed. The examination of the spectra emitted by some Ap stars has allowed the identification of Tc  ii transitions in HD 125248. This Tc  ii detection should however await confirmation from spectral synthesis relying on dedicated model atmospheres. New partition functions are also provided for Tc  i , Tc  ii and Tc  iii for temperatures ranging between 4000 and 13 000 K.