Absolute spectrophotometry of Neptune: 3390 to 7800 Å

Absolute spectrophotometry of Neptune from 3390 to 7800 Å, with spectral resolution of 10 Å in the interval 3390–6055 and 20 Å in the interval 6055–7800 Å, is reported. The results are compared with filter photometry (Appleby, 1973; Wamsteker, 1973; Savage et al., 1980) and with synthetic spectra computed on the basis of a parameterization proposed by Podolak and Danielson (1977) for aerosol scattering and absorption. A CH₄/H₂ ratio of is derived for the convectively mixed part of Neptune's atmosphere, and constrains optical properties of hypothetical aerosol layers.     

Phytoplankton production and nutrient distributions in a subtropical estuary: Importance of freshwater flow

The relationships between phytoplankton productivity, nutrient distributions, and freshwater flow were examined in a seasonal study conducted in Escambia Bay, Florida, USA, located in the northeastern Gulf of Mexico. Five sites oriented along the salinity gradient were sampled 24 times over the 28-mo period from 1999 to 2001. Water column profiles of temperature and salinity were measured along with surface chlorophyll and surface inorganic nutrient concentrations. Primary productivity was measured at 2 sites on 11 dates, and estimated for the remaining dates and sites using an empirical regression model relating phytoplankton net production to the product of chlorophyll, euphotic zone depth, and daily solar insolation. Freshwater flow into the system varied markedly over the study period with record low flow during 2000, a flood event in March 2001, and subsequent resumption of normal flow. Flushing times ranged from 1 d during the flood to 20 d during the drought. Freshwater input strongly affected surface salinity distributions, nutrient flux, chlorophyll, and primary productivity. The flood caused high turbidity and rapid flushing, severely reducing phytoplankton production and biomass accumulation. Following the flood, phytoplankton biomass and productivity sharply increased. Analysis of nutrient distributions suggested Escambia Bay phytoplankton alternated between phosphorus limitation during normal flow and nitrogen limitation during low flow periods. This study found that Escambia Bay is a moderately productive estuary, with an average annual integrated phytoplankton production rate of 290 g C m⁻² yr⁻¹.     

Validation of methods to estimate design discharge flow rates for dam spillways with large regulating capacity

Abstract

The estimation and review of discharge flow rates in hydraulic works is a fundamental problem in water management. In the case of dams with large regulating capacity, in order to estimate return periods of discharge flow rates from the spillways, it becomes necessary to consider both peak flow and volume of the incoming floods. In this paper, the results of the validation for several methods of assessing design floods for spillways of dams with a large flood control capacity are presented; the validation is performed by comparing the maximum outflows (or the maximum levels reached in the reservoir) obtained from the routing of the design floods with those obtained from the routing of the historical annual maximum floods. The basin of Malpaso Dam, Mexico, is used as the case study.

Editor D. Koutsoyiannis

Citation Domínguez, M.R. and Arganis, J.M.L., 2012. Validation of methods to estimate design discharge flow rates for dam spillways with large regulating capacity. Hydrological Sciences Journal, 57 (3), 460–478.     

Uncertainty and learning: implications for the trade-off between short-lived and long-lived greenhouse gases

The economic benefits of a multi-gas approach to climate change mitigation are clear. However, there is still a debate on how to make the trade-off between different greenhouse gases (GHGs). The trade-off debate has mainly centered on the use of Global Warming Potentials (GWPs), governing the trade-off under the Kyoto Protocol, with results showing that the cost-effective valuation of short-lived GHGs, like methane (CH₄), should be lower than its current GWP value if the ultimate aim is to stabilize the anthropogenic temperature change. However, contrary to this, there have also been proposals that early mitigation mainly should be targeted on short-lived GHGs. In this paper we analyze the cost-effective trade-off between a short-lived GHG, CH₄, and a long-lived GHG, carbon dioxide (CO₂), when a temperature target is to be met, taking into consideration the current uncertainty of the climate sensitivity as well as the likelihood that this will be reduced in the future. The analysis is carried out using an integrated climate and economic model (MiMiC) and the results from this model are explored and explained using a simplified analytical economic model. The main finding is that the introduction of uncertainty and learning about the climate sensitivity increases the near-term cost-effective valuation of CH₄ relative to CO₂. The larger the uncertainty span, the higher the valuation of the short-lived gas. For an uncertainty span of ±1°C around an expected climate sensitivity of 3°C, CH₄ is cost-effectively valued 6.8 times as high as CO₂ in year 2005. This is almost twice as high as the valuation in a deterministic case, but still significantly lower than its GWP₁₀₀ value.     

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.     

High‐resolution seismic monitoring of instrumented buildings using a model‐based state observer

This paper proposes a model‐based state observer to perform high‐definition response estimation in partially instrumented building structures. The proposed estimator is verified in a simulated five‐story shear‐building structure and validated using measurements from a seven‐story reinforced concrete building slice tested at the NEES‐University of California at San Diego shake table. In both cases the proposed estimator yielded satisfactory results by estimating the time history of shear forces, bending moments, displacements, and strains at various points/sections of interest. The proposed algorithm can be used in instrumented buildings for various practical applications such as post‐earthquake damage assessment, structural control, and building code calibration. Copyright © 2016 John Wiley & Sons, Ltd.     

1) I. A. H. S. / A. I. H. S.

Abstract

A simple method is used to study the response of runoff in the Sahel to climate change. The statistical characteristics of rainfall are calculated over the western part of the Sahel for the period 1961–1990, using the BADOPLU network. Daily rainfall is simulated using a Markov process with Weibull distribution for rainfall depths. Runoff is modelled using a conceptual SCS model and the curve numbers are calculated for West Africa. Climate change is provided by simulations using the Arpège GCM (Scenario A1B), and a perturbation method is used on the parameters which describe the rainfall. Changes in rainfall are assumed to occur through increases in frequency, not intensity. Using Arpège, runoff is mainly found to increase, in depth and in number of events, by the end of the 21st century. Changes in evaporation and land use are not included in the analysis. The impact of this 21st century potential climate change (rainfall) on the runoff is found to be of the same magnitude as the impact of changes in land use.     

A detailed study of the duality relation for the least squares adjustment in euclidean spaces

The Euclidean spaces with their inner products are used to describe methods of least squares adjustment as orthogonal projections on finite-dimensional subspaces. A unified Euclidean space approach to the least squares adjustment methods “observation equations” and “condition equations” is suggested. Hence not only the two adjustment solutions are treated from the view-point of Euclidean space theory in a unified frame but also the existing duality relation between the methods of “observation equations” and “condition equations” is discussed in full detail. Another purpose of this paper is to contribute to the development of some familiarity with Euclidean and Hilbert space concepts. We are convinced that Euclidean and Hilbert space techniques in least squares adjustment are elegant and powerful geodetic methods.