The acute aquatic toxicity of some substances carried by ships

At the request of the International Maritime Organization (IMO), our laboratory has performed acute toxicity testing with 43 substances, for which insufficient or no data had been available for hazard rating concerning damage to marine living resources.     

Observations of rapid mean flow produced in mercury by a moving heater

Abstract

Experimental and theoretical results are described for the moving flame experiment, where a heat source moves under a horizontal, annular channel filled with liquid mercury. The physical range under discussion consists of the creep flow limit, in which inertial forces are less than viscous forces. A mean surface flow was observed on the mercury. This flow was up to four times greater than the heater speed, and in an opposite direction. The ratio of mean flow to heater speed was theoretically and experimentally found to be proportional to the square of the thermal amplitude, in agreement with a special limit of Davey's earlier results. The basic flow here, as contrasted to those flows analyzed by earlier theories, appears to be generated by surface tension. However, the Reynolds stress mechanism which generates the mean flow is the same. Some experimental flows were so rapid that the range of validity of the present, as well as some earlier theories, was exceeded. The present theory suggests that the higher order nonlinearities may have cancellative effects, which implies that the present and some earlier theories are valid beyond their normal range of validity.     

Improving the efficiency of ant algorithms using adaptive refinement: Application to storm water network design

The ant algorithm is a new evolutionary optimization method proposed for the solution of discrete combinatorial optimization problems. Many engineering optimization problems involve decision variables of continuous nature. Application of the ant algorithm to the optimization of these continuous problems requires discretization of the continuous search space, thereby reducing the underlying continuous problem to a discrete optimization problem. The level of discretization of the continuous search space, however, could present some problems. Generally, coarse discretization of the continuous design variables could adversely affect the quality of the final solution while finer discretization would enlarge the scale of the problem leading to higher computation cost and, occasionally, to low quality solutions. An adaptive refinement procedure is introduced in this paper as a remedy for the problem just outlined. The method is based on the idea of limiting the originally wide search space to a smaller one once a locally converged solution is obtained. The smaller search space is designed to contain the locally optimum solution at its center. The resulting search space is discretized and a completely new search is conducted to find a better solution. The procedure is continued until no improvement can be made by further refinement. The method is applied to a benchmark problem in storm water network design discipline and the results are compared with those of existing methods. The method is shown to be very effective and efficient regarding the optimality of the solution, and the convergence characteristics of the resulting ant algorithm. Furthermore, the method proves itself capable of finding an optimal, or near-optimal solution, independent of the discretization level and the size of the colony used.     

Meteor44 Video Meteor Photometry

Meteor44 is a software system developed at MSFC for the calibration and analysis of video meteor data. The photometric range of the (8 bit) video data is extended from a visual magnitude range of from 8 to 3 to from 8 to −8 for both meteors and stellar images using saturation compensation. Camera and lens specific saturation compensation coefficients are derived from artificial variable star laboratory measurements. Saturation compensation significantly increases the number of meteors with measured intensity and improves the estimation of meteoroid mass distribution. Astrometry is automated to determine each image's plate coefficient using appropriate star catalogs. The images are simultaneously intensity calibrated from the contained stars to determine the photon sensitivity and the saturation level referenced above the atmosphere. The camera's spectral response is used to compensate for stellar color index and typical meteor spectra in order to report meteor light curves in traditional visual magnitude units. Recent efforts include improved camera calibration procedures and long focal length "streak" meteor photometry. Meteor44 has been used to analyze data from the 2001, 2002 and 2003 MSFC Leonid observational campaigns as well as several lesser showers.     

A comparative study of sequential minimal optimization-based support vector machines,vote feature intervals,and logistic regression in landslide susceptibility assessment using GIS

Landslide susceptibility assessment using GIS has been done for part of Uttarakhand region of Himalaya (India) with the objective of comparing the predictive capability of three different machine learning methods, namely sequential minimal optimization-based support vector machines (SMOSVM), vote feature intervals (VFI), and logistic regression (LR) for spatial prediction of landslide occurrence. Out of these three methods, the SMOSVM and VFI are state-of-the-art methods for binary classification problems but have not been applied for landslide prediction, whereas the LR is known as a popular method for landslide susceptibility assessment. In the study, a total of 430 historical landslide polygons and 11 landslide affecting factors such as slope angle, slope aspect, elevation, curvature, lithology, soil, land cover, distance to roads, distance to rivers, distance to lineaments, and rainfall were selected for landslide analysis. For validation and comparison, statistical index-based methods and the receiver operating characteristic curve have been used. Analysis results show that all these models have good performance for landslide spatial prediction but the SMOSVM model has the highest predictive capability, followed by the VFI model, and the LR model, respectively. Thus, SMOSVM is a better model for landslide prediction and can be used for landslide susceptibility mapping of landslide-prone areas.     

Tropospheric Ozone in a Global-Scale Three-Dimensional Lagrangian Model and Its Response to NOX Emission Controls

A three-dimensional Lagrangian tropospheric chemistry modelis used toinvestigate the impact of human activities on the tropospheric distributionofozone and hydroxyl radicals. The model describes the behaviour of 50 speciesincluding methane, carbon monoxide, oxides of nitrogen, sulphur dioxide andnineorganic compounds emitted from human activities and a range of other sources.Thechemical mechanism involves about 100 chemical reactions of which 16 arephotochemical reactions whose diurnal dependence is treated in full. The modelutilises a five minute chemistry time step and a three hour advection timestepfor the 50,000 air parcels. Meteorological data for the winds, temperatures,clouds and so on are taken from the UK Meteorological Office global model for1994 onwards. The impacts of a 50% reduction in European NO_Xemissions onglobal ozone concentrations are assessed. Surface ozoneconcentrations decrease in summertime and rise in wintertime, but to differentextents.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

Multi-decadal synthesis of benthic–pelagic coupling in the western arctic: Role of cross-shelf advective processes

Using geographic information systems (GIS) software and geostatistical techniques, we utilized three decades of water-column chlorophyll a data to examine the relative importance of autochthonous versus allochthonous sources of reduced carbon to benthic communities that occur from the northern Bering to the eastern Beaufort Sea shelf. Spatial trend analyses revealed areas of high benthic biomass (>300 g m⁻²) and chlorophyll (>150 mg m⁻²) on both the southern and northern Chukchi shelf; both areas are known as depositional centers for reduced organic matter that originates on the Bering Sea shelf and is advected northward in Anadyr and Bering shelf water masses. We found a significant correlation between biomass and chlorophyll a in the Chukchi Sea, reflective of the strong benthic–pelagic coupling in a system that is utilized heavily by benthic-feeding marine mammals. In contrast, there was no significant correlation between biomass and chlorophyll in the Beaufort Sea, which by comparison, is considerably less productive (biomass and chlorophyll, <75 g m⁻² and <50 mg m⁻², respectively). One notable exception is an area of relatively high biomass (50–100 g m⁻²) and chlorophyll (80 mg m⁻²) near Barter Island in the eastern Beaufort Sea. Compared to other adjacent areas in the Beaufort Sea, the chlorophyll values in the vicinity of Barter Island were considerably higher and likely reflect a long-hypothesized upwelling in that area and close coupling between the benthos and autochthonous production. In the Bering Sea, a drop in benthic biomass in 1994 compared with previous measurements (1974–1993) may support earlier observations that document a decline in biomass that began between the 1980s and 1990s in the Chirikov Basin and south of St. Lawrence Island. The results of this study indicate that the benthos is an excellent long-term indicator of both local and physical advective processes. In addition, this work provides further evidence that secondary production on arctic shelves can be significantly augmented by reduced carbon advected from highly productive adjacent shelves.     

Closed-form solution of P4P or the three-dimensional resection problem in terms of Möbius barycentric coordinates

 The perspective 4 point (P4P) problem - also called the three-dimensional resection problem - is solved by means of a new algorithm: At first the unknown Cartesian coordinates of the perspective center are computed by means of M?bius barycentric coordinates. Secondly these coordinates are represented in terms of observables, namely space angles in the five-dimensional simplex generated by the unknown point and the four known points. Substitution of M?bius barycentric coordinates leads to the unknown Cartesian coordinates (2.8)–(2.10) of Box 2.2. The unknown distances within the five-dimensional simplex are determined by solving the Grunert equations, namely by forward reduction to one algebraic equation (3.8) of order four and backward linear substitution. Tables 1.–4. contain a numerical example. Finally we give a reference to the solution of the 3 point (P3P) problem, the two-dimensional resection problem, namely to the Ansermet barycentric coordinates initiated by C.F. Gau? (1842), A. Schreiber (1908) and A.␣Ansermet (1910). Received: 05 March 1996; Accepted: 15 October 1996