A numerical model of the partitioning of trace chemical solutes during drop freezing

Partitioning of volatile chemicals among the gas, liquid, and solid phases during freezing of liquid water in clouds can impact trace chemical distributions in the troposphere and in precipitation. We describe here a numerical model of this partitioning during the freezing of a supercooled liquid drop. Our model includes the time-dependent calculation of the coupled processes of crystallization kinetics, heat transport, and solute mass transport, for a freezing hydrometeor particle. We demonstrate the model for tracer partitioning during the freezing of a 1000 μm radius drop on a 100 μm ice substrate, under a few ambient condition scenarios. The model effectively simulates particle freezing and solute transport, yielding results that are qualitatively and quantitatively consistent with previous experimental and theoretical work. Results suggest that the ice shell formation time is governed by heat loss to air and not by dendrite propagation, and that the location of ice nucleation is not important to freezing times or the effective partitioning of chemical solutes. Even for the case of nucleation at the center of the drop, we found that dendrites propagated rapidly to form surface ice. Freezing then proceeded from the outside in. Results also indicate that the solid-liquid interfacial surface area is not important to freezing times or the effective partitioning of chemical solutes, and that the rate aspects of trapping are more important than equilibrium solid-liquid partitioning to the effective partitioning resulting from freezing.     

Assessment of Nitrate—Nitrogen Distribution in Kansas Groundwater, 1990–1998

Nitrate-nitrogen (nitrate-N) in groundwater is a potential problem in many parts of Kansas.From 1990 to 1998, 747 water samples were collected from domestic, irrigation, monitoring,and public water supply wells primarily from the western two-thirds of the state, and analyzedfor nitrate-N by the Kansas Geological Survey. Nitrate-N concentrations of the 747 samplesanalyzed range from 29% with less than or equal to 3 mg/L, 51% between 3 and 10 mg/L,and 20% greater than or equal to 10 mg/L. Factors that show a statistically significantrelationship with the occurrence of nitrate-N in Kansas groundwater in this assessment includegeographic area of the state, depth of well, and age of well. Nitrate-N levels of wells screenedin the High Plains aquifer in south-central Kansas showed a statistically higher concentrationthan samples collected from the High Plains aquifer in the western portion of the state.Comparison of nitrate-N with depth of well indicated that shallower wells throughout the stategenerally have higher nitrate-N values than deeper wells. Irrigation wells older than 1975showed statistically higher nitrate-N concentration than wells installed during and since 1975,possibly related to changes in well-construction practices and regulations that occurred in 1975.     

Discontinuity controlled probabilistic slope failure risk maps of the Altindag (settlement) region in Turkey

The evaluation of potential rock slope problems using stereographic projection techniques known as kinematic analysis is one of the most important parts of a slope stability investigation to be carried out in jointed rock media. In conventional stereoprojection techniques for the assessment of possible rock slope failures, the peak orientations of joints together with the slope geometry and the friction angle of the weakness planes are used. Other possible joint orientations which may be encountered in the rock media are ignored, although they belong to the group of joint peak orientations. In this study, nearly vertical jointed andesites cropped out at the Altindag settlement region in Ankara were studied in order to evaluate the relevance of this ignored discontinuity orientation data on slope stability. As a result, probabilistic risk maps for planar, toppling and wedge failures were produced using the kinematic rules and digital elevation model of the study area. The comparison of the distribution of the actual failures in the area and the probabilistic risk maps prepared for the study area revealed that all of the identified failures are found to be located in the higher risk zones on the probabilistic risk maps.     

MODELLING LONG‐TERM SUMMER AND WINTER BALANCES AND THE CLIMATE SENSITIVITY OF STORBREEN,NORWAY

Measurements of winter balance (b_w) and summer balance (b_s) have been carried out at Storbreen since 1949. Here we apply a simple mass balance model to study the climate sensitivity and to reconstruct the mass balance series priorto 1949. The model is calibrated and validated with data from an automatic weather station (AWS) operating in the ablation zone of Storbreen since 2001. Regression analysis revealed that b_w was best modelled using precipitation data southwest of the glacier. Results from the model compared well with reported mass balance values for the period 1949–2006, obtained correlations (r) for b_w and b_s varied between 0.83 and 0.87 depending on model set up. Reconstruction of the mass balance series for the period 1924/1925–1948/1949 suggested a cumulative mass deficit of c. 30 m w.e. mainly due to highly negative summer balances, but also lower b_wthan the average for 1949–2006. Calculated change in specific mass balance for a ±1°C change in air temperature was ±0.55 m w.e., whereas a ±10 % increase in precipitation represented a change of ±0.20 m w.e. Model results further indicated that for a 2°C warming, the ablation season will be extended by c. 30 days and that the period of ice melt at the AWS location will increase from c. 40 to c. 80 days.     

The sedimentary and tectonic evolution of the Amur River and North Sakhalin Basin: new evidence from seismic stratigraphy and Neogene–Recent sediment budgets

The North Sakhalin Basin in the western Sea of Okhotsk has been the main site of sedimentation from the Amur River since the Early Miocene. In this article, we present regional seismic reflection data and a Neogene–Recent sediment budget to constrain the evolution of the basin and its sedimentary fill, and consider the implications for sediment flux from the Amur River, in particular testing models of continental‐scale Neogene drainage capture. The Amur‐derived basin‐fill history can be divided into five distinct stages: the first Amur‐derived sediments (>21–16.5 Ma) were deposited during a period of transtension along the Sakhalin‐Hokkaido Shear Zone, with moderately high sediment flux to the basin (71 Mt year^?1). The second stage sequence (16.5–10.4 Ma) was deposited following the cessation of transtension, and was characterised by a significant reduction in sediment flux (24 Mt year^?1) and widespread retrogradation of deltaic sediments. The third (10.4–5.3 Ma) and fourth (5.3–2.5 Ma) stages were characterised by progradation of deltaic sediments and an associated increase in sediment flux (48–60 Mt year^?1) to the basin. Significant uplift associated with regional transpression started during this time in southeastern Sakhalin, but the north‐eastward propagating strain did not reach the NE shelf of Sakhalin until the Pleistocene (<2.5 Ma). This uplift event, still ongoing today, resulted in recycling of older deltaic sediments from the island of Sakhalin, and contributed to a substantially increased total sediment flux to the adjacent basinal areas (165 Mt year^?1). Adjusted rates to discount these local erosional products (117 Mt year^?1) imply an Amur catchment‐wide increase in denudation rates during the Late Pliocene–Pleistocene; however, this was likely a result of global climatic and eustatic effects, combined with tectonic processes within the Amur catchment and possibly a smaller drainage capture event by the Sungari tributary, rather than continental‐scale drainage capture involving the entire upper Amur catchment.     

Bildung bromhaltiger Desinfektionsnebenprodukte nach Chlorung von Bodenseewasser in Abhängigkeit von Aufbereitungsschritten und der Bromidkonzentration

Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.     

Landslide susceptibility analysis with a heuristic approach in the Eastern Alps (Vorarlberg, Austria)

The aim of the study is landslide hazard assessment carried out on a working scale of 1:25 000. The study area within the Northern Calcareous Alps was geologically and geotechnically mapped in order to identify causes and mechanisms of active mass movements. The field surveys were digitised by a Geographical Information System and divided into data layers. The geological units were classified according to their geotechnical properties. All layers were converted into grids and spatially analysed together with a Digital Elevation Model. Comparing the layers with the inventory of active landslides, the prevailing factors leading to sliding movements were identified. Because of the complex tectonic setting and the small number of active landslides, a statistical method of hazard assessment was not applicable. Using the heuristic approach of an index method, the data layers of geotechnical class, bedding conditions, tectonic layouts, slope angles, slope orientations, vegetation and erosion were analysed. The susceptibility of each layer has been evaluated with help of bivariate statistics. The layers have been weighted with indices due to their importance iteratively and were combined into a landslide susceptibility map.