Petrology and Rare Earth Elements Mineral Chemistry of Chadegan Metabasites (Sanandaj-Sirjan Zone,Iran): Evidence for Eclogite-Facies Metamorphism during Neotethyan Subduction

The metabasites of Chadegan, including eclogite, garnet amphibolite and amphibolite, are forming a part of Sanandaj–Sirjan Zone. These rocks have formed during the subduction of the Neo–Tethys ocean crust under Iranian plate. This subduction resulted in a subduction metamorphism under high pressuremedium temperature of eclogite and amphibolites facies condition. Then the metamorphic rocks were exhumed during the continental collision between the Afro–Arabian continent and the Iranian microcontinent. In the metabasite rocks, with typical MORB composition, garnet preserved a compositional zoning occurred during metamorphism. The magnesium (X_Mg) gradually increases from core to rim of garnets, while the manganese (X_Mn) decreases towards the rim. Chondrite–normalized Rare Earth Element patterns for these garnets exhibit core–to–rim increases in Light Rare Earth Elements. The chondrite–normalized REE patterns of garnets, amphiboles and pyroxenes display positive trend from LREEs to Heavy Rare Earth Elements (especially in garnet), which suggests the role of these minerals as the major controller of HREE distribution. The geochemical features show that the studied eclogite and associated rocks have a MORB origin, and probably formed in a deep–seated subduction channel environment. The geothermometry estimation yields average pressure of ~22 kbar and temperature of 470–520°C for eclogite fomation. The thermobarometry results gave T = 650–700°C and P ≈ 10–11 kbar for amphibolite facies.     

Influence of Mussel Culture on the Vertical Export of Phytoplankton Carbon in a Coastal Upwelling Embayment (Ría de Vigo,NW Iberia)

The goal of this paper is to find out whether suspended mussel culture affects the vertical fluxes of biogenic particles in the Ría de Vigo on a seasonal scale. With this aim, vertical fluxes of particulate organic carbon (POC) and the magnitude and composition of vertical export of phytoplankton carbon (Cphyto) collected in sediment traps were examined by comparing data obtained inside a mussel farming area (RaS) with those found at a reference station (ReS) not affected by mussels. Our results indicate that mussel farming has a strong impact on sedimentation fluxes under the rafts, not only increasing POC flux but also altering the magnitude and composition of Cphyto fluxes. Average POC flux at RaS (2564?±?1936 mg m^?2 day^?1) was four times higher than at ReS (731?±?276 mg m^?2 day^?1), and much of this increase was due to biodeposit fluxes (Cbiodep) which accounted for large proportion of POC flux (35–60 %). Indeed, because of this high Cbiodep flux, only a small proportion of the POC flux was due to Cphyto flux (3–12 %). At the same time, we observed an increased sedimentation of phytoplankton cells at RaS that could be explained by a combination of mechanisms: less energetic hydrodynamic conditions under mussel rafts, ballast effect by sinking mussel feces, and diatom aggregates. Moreover, mussel farming also altered the quality of the Cphyto flux by removing part of the predatory pressure of zooplankton and thus matching diatom composition in water column and sediment traps.     

A GEOGRAPHIC INFORMATION SYSTEM FOR PHYSICAL-GEOGRAPHIC REGIONALIZATION

The design and functioning of a geographic information system established for the purpose of objectively delineating the boundaries of major physical geographic regions in the USSR is described. The basic components include an information input block for data collection and preliminary image processing; a recognition block for feature classification and analysis; a data base management system providing for repeated revision, addition, and use of spectral information; and a block for displaying results of processing in various forms. Applications of the system are demonstrated in the mapping of physical regions in a steppe and semi-desert area of the southern USSR. Translated from: Izvestiya Akademii Nauk SSSR, seriya geograficheskaya, 1988, No. 2, pp. 89-94.     

Analyses of pre-injection reservoir data for stable carbon isotope trend predictions in CO2 monitoring: preparing for CO2 injection

Baseline monitoring at the proposed enhanced gas recovery site in Altmark (Germany) was carried out in combination with theoretical and laboratory investigations to describe and predict the principles of expected stable carbon isotope and dissolved inorganic carbon (DIC) trends during CO₂ injection in reservoirs. This provides fundamental data for site-specific characterisation for monitoring purposes. Baseline ??¹³C values at the Altmark site ranged between ?1.8 and ?11.5??? and DIC values were about 2?mmol?L^?1. These baseline values form the basis for a theoretical study on the influences of the ambient reservoir conditions on the state of geochemical and isotope equilibrium of the reservoir fluids. Transferring this theoretical study to the Altmark site enables predictions on geochemical trends during potential injection. Assuming that CO₂ would be injected at the Altmark site to pCO₂?=?100?bar and with a ??¹³C of ?30???, at isotopic and geochemical equilibrium, ??¹³C_DIC values would approach this end-member, and DIC concentrations of 1,000?mmol L^?1 would be expected. Laboratory experiments were conducted at low pCO₂ levels (4?C35?bars) to mimic the approach of a CO₂ plume at a monitoring well. These results support field investigations from other sites: that ??¹³C_DIC is a sensitive tool for monitoring CO₂ migration in the subsurface and simultaneously allows quantification of geochemical trapping of CO₂.     

Diffusion of tetravalent cations in zircon

Diffusion rates for the three tetravalent cations U, Th and Hf have been measured in synthetic zircon. Diffusant sources included oxide powders and ground pre-synthesized silicates. Rutherford backscattering spectrometry (RBS) was used to measure depth profiles. Over the temperature range 1400–1650 °C, the following Arrhenius relations were obtained (diffusion coefficients in m²sec⁻¹): log D _Th = (1.936 ± 0.9820) + (− 792 ± 34 kJ mol⁻¹ /2.303 RT) log D _U = (0.212 ± 2.440) + (− 726 ± 83 kJ mol⁻¹ /2.303 RT) log D _Hf = (3.206 ± 1.592) + (− 812 ± 54 kJ mol⁻¹ /2.303 RT) The data show a systematic increase in diffusivity with decreasing ionic radius (i.e., faster diffusion rates for Hf than for U or Th), a trend also observed in our earlier study of rare earth diffusion in zircon. Diffusive fractionation may be a factor in the Lu-Hf system given the much slower diffusion rates of tetravalent cations when compared with the trivalent rare earths. The very slow diffusion rates measured for these tetravalent cations suggest that they are essentially immobile under most geologic conditions, permitting the preservation of fine-scale chemical zoning and isotopic signatures of inherited cores. Received: 12 July 1996 / Accepted: 2 December 1996     

A predictability study of simulated North Atlantic multidecadal variability

 The North Atlantic is one of the few places on the globe where the atmosphere is linked to the deep ocean through air–sea interaction. While the internal variability of the atmosphere by itself is only predictable over a period of one to two weeks, climate variations are potentially predictable for much longer periods of months or even years because of coupling with the ocean. This work presents details from the first study to quantify the predictability for simulated multidecadal climate variability over the North Atlantic. The model used for this purpose is the GFDL coupled ocean-atmosphere climate model used extensively for studies of global warming and natural climate variability. This model contains fluctuations of the North Atlantic and high-latitude oceanic circulation with variability concentrated in the 40–60 year range. Oceanic predictability is quantified through analysis of the time-dependent behavior of large-scale empirical orthogonal function (EOF) patterns for the meridional stream function, dynamic topography, 170 m temperature, surface temperature and surface salinity. The results indicate that predictability in the North Atlantic depends on three main physical mechanisms. The first involves the oceanic deep convection in the subpolar region which acts to integrate atmospheric fluctuations, thus providing for a red noise oceanic response as elaborated by Hasselmann. The second involves the large-scale dynamics of the thermohaline circulation, which can cause the oceanic variations to have an oscillatory character on the multidecadal time scale. The third involves nonlocal effects on the North Atlantic arising from periodic anomalous fresh water transport advecting southward from the polar regions in the East Greenland Current. When the multidecadal oscillatory variations of the thermohaline circulation are active, the first and second EOF patterns for the North Atlantic dynamic topography have predictability time scales on the order of 10–20 y, whereas EOF-1 of SST has predictability time scales of 5–7 y. When the thermohaline variability has weak multidecadal power, the Hasselmann mechanism is dominant and the predictability is reduced by at least a factor of two. When the third mechanism is in an extreme phase, the North Atlantic dynamic topography patterns realize a 10–20 year predictability time scale. Additional analysis of SST in the Greenland Sea, in a region associated with the southward propagating fresh water anomalies, indicates the potential for decadal scale predictability for this high latitude region as well. The model calculations also allow insight into regional variations of predictability, which might be useful information for the design of a monitoring system for the North Atlantic. Predictability appears to break down most rapidly in regions of active convection in the high-latitude regions of the North Atlantic. Received: 28 October 1996 / Accepted: 21 March 1997     

Two-frequency timing of the pulsar B1937+21 in Kalyazin and Kashima in 1997–2002

We present the results from our timing of the millisecond pulsar B1937+21, performed jointly since 1997 on two radio telescopes: the RT-64 in Kalyazin (Russia) at a frequency of 0.6GHz and RT-34 in Kashima (Japan) at a frequency of 2.15 GHz. The rms value of the pulse time of arrival (TOA) residuals for the pulsar at the barycenter of the Solar system is 1.8 μs (the relative variation is ≈10^?14 over the observing period). The TOA residuals are shown to be dominated by white phase noise, which allows this pulsar to be used as an independent time scale keeper. The upper limit for the gravitational background energy density Ω_gh² at frequencies ≈6.5 × 10^?9 Hz is estimated to be no higher than 10^?6. Based on the long-term timing of the pulsar, we have improved its parameters and accurately determined the dispersion measure and its time variation over the period 1984–2002, which was, on average, ?0.00114(3) pc cm^?3 yr^?1.     

Zeeman-doppler imaging: A new option for magnetic field study of Ap and solar-type stars

In the task of studying stellar magnetic fields, polarimetric methods have been intensively used in Ap stars. But the observational material classically used to reconstruct stellar magnetic structures (average longitudinal magnetic field as a function of rotational phase) is not rich enough in spatial information to derive geometries more complex than centered or decentered dipoles.In solar-type stars, all evidences of activity recently detected on their surfaces (starspots, flares, ...) indicate they are most likely magnetic stars. But polarimetric methods have always failed in these stars, probably due to the complex magnetic topologies encountered which even prevented until now a simple detection (Borra, Edwards, and Mayor, 1984). With the Zeeman broadening measurement technique proposed by Robinson (1980), no reliable results can be derived for rapid rotators, which are otherwise presumed to be the best candidates for magnetic detections. Once more, if temperature inhomogeneity charts are already available for solar-type stars (Vogt, 1987), spatial information on their magnetic distributions has conversely not yet been obtained.The new option, recently proposed by Semel (1989) and qualified by Donati, Semel, and Praderie (1989), is based on the rotational modulation study of a rapid rotator Stokes parameter V(), obtained with both high spectral resolution R, and high signal-to-noise ratio S/N. Since the magnetic information used refers to localized strips on the stellar disc (as a consequence of the star rotation), multipolar structures can thus be resolved.A new instrumentation and observing procedure have been defined for ZDI, in order to obtain very high S/N data. The method has been successfully tested on two bright magnetic Ap stars: a magnetic detection was obtained on UMa and a 15-point phase coverage of ² CVn is available for the reconstruction of complete 2D abundance and magnetic mappings of its photosphere.Concerning solar-type stars, a numerical simulation was carried out in order to determine the observational constraints required for the detection of typical magnetic field similar to those reported in slow rotators with the Robinson method (Saar, 1988). The specifications needed are S/N 400 per 40 mÅ pixel and R - 6 × 10⁴.