Experimental stream acidification — the influence of sediment and streambed vegetation

An acidification experiment was conducted on a small stream in the Loch Ard area of central Scotland. The stream was chosen because of its large, flow related, variation in pH (5.9-4.0). Two acid additions were made to approximately pH 3.5–3.7. The results indicated a strong correlation between labile aluminium and hydrogen, and a noticeable hysteresis in the response of calcium and hydrogen. It is hypothesised that divalent cation response is a result of ion-exchange mechanisms involving the streambed vegetation, with aluminium release resulting primarily from exchange reactions with streambed sediment stores. Data from a program of stream spot sampling have been analysed in an attempt to elucidate the contribution of different sources of aluminium under different flow conditions. Streambed sources of aluminium contribute significantly under low flow conditions; however, at high flow, additional sources of aluminium must contribute to match observed streamwater chemistry.     

Hydrological characteristics of vegetated river flows: a laboratory flume study

Abstract

Laboratory flume experiments were undertaken to measure the vertical profiles of mean flow velocity for three different flow discharges and four different stem densities of Hydrilla verticillata. The data were used to calculate three parameters, namely Manning's roughness coefficient, the Reynolds number and the Froude number. In addition, empirical equations were obtained for the vertical distribution of measured flow velocity within the transitional zone and above the plant canopy. The results show that: (a) the vertical distribution of measured flow velocity exhibits three zone profiles; (b) Manning's roughness coefficient decreases with increasing depth-averaged flow velocity; (c) the relationship between Manning's roughness coefficient and the depth-averaged flow velocity is within the smooth left inverse curve; (d) Manning's roughness coefficient significantly changes with increasing density of Hydrilla; (e) the Froude number is independent of the density of Hydrilla; and (f) both the Reynolds number and the Froude number increase with increasing depth-averaged flow velocity.

Citation Shi, J.Z., Li, Y.-H., Hughes, J.M.R., and Zhao, M., 2013. Hydrological characteristics of vegetated river flows: a laboratory flume study. Hydrological Sciences Journal, 58 (5), 1047–1058.

Editor Z.W. Kundzewicz     

Microbiological Processes in the Gor'kovskoe Reservoir

The abundance of various groups of bacteria and the rate of microbiological processes of organic decay and methane cycle in the water and soils of the Gor'kovskoe Reservoir are determined, and the ecological characterization of its river reach is presented. The autochthonous and allochthonous impact on the bacterial community of the reservoir was found to be tolerable; however, some restricted areas were revealed, where the ecosystem is strongly affected by domestic and industrial wastewater, and where the abundance and activity of anaerobic methane-producing and sulfate-reducing soil bacteria increase.     

Trapped Xe and I-Xe ages in aqueously altered CV3 meteorites

Twenty-two dark inclusions (DIs) from Allende (18), Leoville (2), Vigarano (1) and Efremovka (1) were studied by the I-Xe method. All except two of these DIs (Vigarano 2226 and Leoville LV2) produce well-defined isochrons, and precise I-Xe ages. The Allende DIs formed a tight group about 1.6 Ma older than Shallowater (4.566 ± 0.002 Ga), about 5 Ma older than four previously studied Allende CAIs. Most of the dark inclusions require trapped Xe with less ¹²⁹Xe (or more ¹²⁸Xe) than conventional planetary Xe (well restricted in composition by Q-Xe or OC-Xe). Studies of an irradiated/unirradiated DI pair from Allende demonstrate that the ¹²⁸Xe/¹³²Xe ratio in trapped is normal planetary, so that a ¹²⁹Xe/¹³²Xe ratio below planetary seems to be required. Yet, this is not possible given constraints on ¹²⁹Xe evolution in the early solar system. Trends among all of the Allende DIs suggest that an intimate mixture of partially decayed iodine and Xe formed a pseudo trapped Xe component enriched in both ¹²⁹Xe and ¹²⁷I, and subsequently in ¹²⁸Xe after n-capture during reactor irradiation. Enrichment in radiogenic ¹²⁹Xe, but with a ¹²⁹Xe/¹²⁷I ratio less than that observed in the iodine host phase, places closure of this trapped mixture ≥13 Ma after precipitation of the major iodine-bearing phase. Because the I-Xe isochron is a mixing line between iodine-derived and trapped Xe (pseudo or not), I-Xe ages, given by the slope of this mixing line, are not compromised by the presence of pseudo trapped Xe, and the precision of the I-Xe ages is given by the statistics of the line fit.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.     

Antarctic sea-ice relationships with indices of the atmospheric circulation of the Southern Hemisphere

A link between the Antarctic sea-ice extent and low-frequency atmospheric variations, particularly ENSO, has been suggested by recent modeling and empirical studies. This question is examined here using a high-resolution (by week, by region) data base of Antarctic sea-ice extent for the 1973–1982 period. Although of relatively short duration by Northern Hemisphere standards, such a data base offers an opportunity rare in Southern Hemisphere climate studies. The seaice variations are examined in the context of longer-term indices of the large-scale atmospheric circulation. These are a Southern Oscillation Index (SOI) and an index of sea-level pressure (SLP) wavenumber one in the Southern Hemisphere extratropics. The indices are updated through 1982, and their associations with regional-scale pressure indices in the Australia-New Zealand sector are also examined. The 1973–1982 period is anomalous when compared with the period 1951–1972. Correlation analysis of the monthly sea ice and circulation index values reveals that much of the apparent link between the ice and the SOI suggested in previous studies arises from autocorrelations present in both data sets and the strong annual cycle of sea-ice extent. Removing these effects from the data and re-running the correlations reveals that most of the resulting significant associations between the ice and one or other of the circulation indices can probably be explained on the basis of chance. In order to reconcile these findings with previous studies that show some strong ice-circulation interactions on regional scales, only those months in which significant correlations occur between both largescale circulation indices and the sea ice are examined further. These occur preferentially in the Ross and Weddell sectors, which constitute the regions contributing most to the variability of Antarctic sea ice. The analysis suggests that the sea-ice-extent changes lag the SOI by several months but may precede changes in extratropical SLP wavenumber one. Confirmation of these tentative regional ice extent-circulation teleconnections necessarily awaits the forward extension of the high-resolution sea-ice data base beyond the 10 years available here.This paper is based on material presented at the Conference on Mechanisms of Interannual and Longer-Term Climatic Variations held at the University of Melbourne, Australia: December 8–12, 1986.     

Lessons Learned from 25 Years of Research at the MADE Site

Field studies at well‐instrumented research sites have provided extensive data sets and important insights essential for development and testing of transport theories and mathematical models. This paper provides an overview of over 25 years of research and lessons learned at one of such field research sites on the Columbus Air Force Base in Mississippi, commonly known as the Macrodispersion Experiment (MADE) site. Since the mid‐1980s, field data from the MADE site have been used extensively by researchers around the world to explore complex contaminant transport phenomena in highly heterogeneous porous media. Results from field investigations and modeling analyses suggested that connected networks of small‐scale preferential flow paths and relative flow barriers exert dominant control on solute transport processes. The classical advection‐dispersion model was shown to inadequately represent plume‐scale transport, while the dual‐domain mass transfer model was found to reproduce the primary observed plume characteristics. The MADE site has served as a valuable natural observatory for contaminant transport studies where new observations have led to better understanding and improved models have sprung out analysis of new data.     

Determination of the isotopic composition of molybdenum in the bottom sediments of freshwater basins

This paper presents the results of measurements of the Mo isotopic composition in the bottom sediments (BS) of freshwater basins. Mo isotopic ratios were measured using a multicollector inductively coupled plasma mass spectrometer (MC ICP MS). Efficient methods were used in this study for Mo separation from the elements of the sample matrix and correction for instrumental mass discrimination. This allowed us to achieve a high accuracy of 0.06, 0.08, and 0.14‰ (2 σ) for the measurement of ⁹⁷Mo/⁹⁵Mo, ⁹⁸Mo/⁹⁵Mo, and ¹⁰⁰Mo/⁹⁵Mo, respectively. The range of variations in Mo isotope ratios observed in the collected BS columns was ～2.2‰ in terms of δ⁹⁷Mo/⁹⁵Mo. The results obtained here suggest that geochemical processes occurring during Mo migration with land water can change the isotopic composition of Mo. It is pointed out that the potential use of Mo isotopic systematics for reconstructions of redox conditions in seawater over the geologic past requires the quantification of isotopic effects of Mo accompanying its migration on land and the extent of possible variations in the isotopic composition of Mo entering the ocean.