COMPUTER MODELING OF VERTICAL SEISMIC PROFILING*

There are numerous modeling techniques commonly employed for the computer simulation of seismic wave propagation. The capabilities of these techniques vary according to the theoretical foundations and subsequent approximations upon which the algorithms are based. This paper constitutes a comparative review of seven modeling methods: geometric ray theory, asymptotic ray theory, generalized ray theory, Kirchhoff wave theory, Fourier synthesis, finite differences, and finite elements. These methods can be categorized as ray or wave, acoustic or elastic, and can be contrasted according to their relative abilities to simulate such behavior as wave interference effects, diffractions, and mode conversions. As is implied by their names, geometric ray theory and asymptotic ray theory are both ray methods. The other five methods provide wave theory simulations. Geometric ray theory and Kirchhoff wave theory are normally implemented in acoustic form, while the other methods are readily adapted for computing elastic theory solutions. Generalized ray theory and Fourier synthesis are more limited in the complexity of geological model they can accommodate than are the other techniques. The methods which typically demand the greatest computer resources are the finite-difference and the finite-element techniques. All methods can incorporate at least some multiple events. Diffractions, however, are only inherent in the solutions computed by Kirchhoff wave theory, finite differences and finite elements. Attenuation is readily incorporated in both the Fourier synthesis and the finite-element methods. As an example of the application of seismic modeling, a geological model representative of a typical petroleum exploration target is used to compare vertical seismic profiles calculated by different modeling methods.     

Reply to comments by K.A. Goettel and J.S. Lewis

Uranium has been measured by homogenized fission track analysis in 34 samples of 22 achondrites. Potassium has been determined in aliquots of eleven of these. The results, combined with previous Al data, are not compatible with achondrite formation from chondritic material by previously suggested fractional melting or metal-sulfide segregation processes.     

The axial momentum balance of Earth and its fluid envelope

The emergence of greatly improved data sets over the past decade has heightened awareness of the close relationship between changes in the axial component of the angular momentum of the atmosphere and that of the solid Earth, the latter being reflected in small, though detectable, changes in the planet's rate of rotation. Changes in the large-scale wind field, and hence in atmospheric angular momentum, on intraseasonal through interannual time scales can be associated with a number of identifiable meteorological phenomena, whose further study has been given new impetus by the discovery of their signals in Earth's rotation. Future advances in the subject are apt to occur in connection with new data sets that will help address questions remaining about rapid changes in Earth rotation and the torques responsible for the momentum changes. Also in the coming decade, both new data and modeling approaches should help clarify the role of the oceanic portion of Earth's fluid envelope in the planetary momentum balance.     

Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Melanterite and szomolnokite as weathering products of pyrite from the Bazhenovo Formation

Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO₄ · 7H₂O) and szomolnokite (FeSO₄ · H₂O). Szomolnokite was detected in West Siberia for the first time.