Seasonal variation of Mn adsorption on to calcareous surfaces in the English Channel, and its implication on the manganese distribution coefficient

Dissolved and particulate manganese in seawater samples derived from the English Channel has been analyzed using graphite furnace atomic absorption (GFAAS), and inductively coupled plasma atomic emission (ICP—AES) spectroscopies. Because of the high contents of carbonate minerals found in the suspended matter samples, the English Channel constitutes an ideal field area for the study of the Mn²⁺/Ca²⁺/CaCO₃ system. Owing to the chemical speciation of particulate manganese and the combined use of the X-ray diffraction and electron spin resonance spectroscopy we have shown the importance of the carbonate phase in the stabilization of manganese (II). This has been confirmed by p-pH measurements in the field. All these studies have also indicated that: (1) manganese is associated with calcite in the form of a solid solution, Mn_xCa_1−xCO₃; and (2) significant increases in the concentrations of particulate manganese, especially in offshore waters, occur in summer. This seasonal phenomenon has been attributed to the proliferation of coccolithophorids, which are known to be covered with calcified skeletons at high specific surface areas. To appraise the implication of the coccolithophorid-blooms phenomenon on the Mn²⁺/Ca²⁺/CaCO₃ system, we have used the manganese distribution coefficient, D_i, between the liquid phase and CaCO₃ particles. Overall we have shown that: (1) D_i in summer (i.e. when coccoliths considered as very fine-grained calcite are abundant) is much higher than that obtained in winter; and (2) in the vicinity of the French coast, D_i does not vary significantly even in summer. This is because of the high content of chalk-derived particles found in the near-shore waters.     

Short-Term Benthic Recolonization after Dredging in the Harbour of Ceuta, North Africa

Abstract. The benthic recovery after dredging (area: 2625 m²) was studied in a polluted and enclosed area of the harbour of Ceuta, in which the recolonization through the water column (larvae and adult bedload transport) could be limited by the lack of renewal. The benthos was sampled at two sites (control and dredged) using a van Veen grab and adopting a BACI (Before, After, Control, Impacted) approach. Five samplings were conducted after dredging (3, 15, 30, 90, 180 days). The proportion of gravel in the sediment of the dredged site increased after dredging, while the organic matter decreased. The impact on the community was estimated at species level, using both univariate and multivariate analyses. The maximum negative effect on benthic macrofauna was a reduction by 65% for species richness (15 days after dredging) and by 75% for abundance (3 days after dredging). Between 15 and 30 days after dredging, the abundance of some species such as the molluscs Parvicardium exiguum and Retusa obtusa and the polychaete Pseudomalacoceros tridentata increased considerably in the dredged site, while typical ‘opportunistic’ species such as Capitella capitata were disfavoured by the disturbance. For this small‐scale dredging, about 6 months are required for the disturbed area to re‐establish a sediment structure and a macrobenthic community similar to the undisturbed area. Small‐patch dredging operations are proposed in harbour management whenever possible, since they allow a quick re‐adjustment of the initial sediment structure and benthic communities.     

Are Global Tide Gauge Data Stationary in Variance?

Tide gauges distributed all over the world provide valuable information for monitoring mean sea level changes. The statistical models used in estimating sea level change from the tide gauge data assume implicitly that the random model components are stationary in variance. We show that for a large number of global tide gauge data this is not the case for the seasonal part using a variate-differencing algorithm. This finding is important for assessing the reliability of the present estimates of mean sea level changes because nonstationarity of the data may have marked impact on the sea level rate estimates, especially, for the data from short records.     

Paleomonsoon precipitation deduced from a sediment core from the equatorial Indian Ocean

Rapid shifts in past climate recorded in polar ice sheets have elicited various explanations relating to either thermohaline circulation changes by ice-rafting or natural greenhouse gas concentrations modulated by climatic conditions in the tropics. To compare the tropical paleoclimate record with the polar record, one must choose sediment cores from highly productive ocean regions. Necessarily, such regions reflect the wind records in the tropics, because high productivity is associated with upwelling driven by winds. Comparing tropical precipitation records with high-latitude records is, however, a more difficult task because sediments recording paleoprecipitation usually have low sedimentation rates, and offer coarser resolution relative to polar ice cores. Here, we present δ ¹⁸O data of three planktonic species of Foraminifera (a proxy for precipitation) from such a sediment core, spanning the past 35 ka for the equatorial Indian Ocean, which falls under the southwest monsoon (SWM) realm. Results show that minimum SWM precipitation occurred at the Last Glacial Maximum, with a subsequent increase at Termination IA. During the Holocene, SWM precipitation intensified uniformly up to the core top (∼2.2 ka b.p.), as revealed by generally decreasing δ ¹⁸O values. Variations in precipitation are consistent with climate changes recorded in polar ice sheets. Although the different resolutions of the two records preclude a rigorous comparison, abrupt cooling/warming events appear to be accompanied by sudden reduction/enhancement in (SWM) rainfall. Thus, mechanisms with time scales much shorter than a millennium, such as natural greenhouse warming (e.g., CH₄ concentration), controlled by emissions from the tropics, could have played a major role in high-latitude climate change.     

Shipborne GPS attitude determination during MMST-93

The attitude parameters of a ship underway were measured using a configuration of four 10-channel NovAtel Model 951 narrow-correlator-spacing receivers. These C/A code receivers have output rates of up to 10 Hz and maintain effective carrier phase lock under relatively harsh ship dynamics. The attitude parameters are calculated independently at each epoch using differential carrier phase measurements, carrier phase ambiguities are resolved on-the-fly by constraining the approximately known distances between the antennas that are rigidly mounted on the ship. Carrier phase thermal noise and multipath are minimized by mounting the antennas as far apart as possible. The four-antenna configuration provides redundancy and further improves accuracy. During the Matthew Motion Sensor Trials (MMST-93) conducted off the coast of Halifax, Nova Scotia, in June-July 1993, the GPS-derived attitude parameters were compared with those obtained with a Honeywell HG1050 ring laser gyro inertial navigation system (INS) which provides roll and pitch with an accuracy of 15 arcsecs and heading with an accuracy of 2 arcmins. To simulate rough weather conditions, sharp maneuvers were performed to induce roll angles in excess of 10°. No accuracy degradation nor any loss of GPS measurements occurred. The RMS agreement between GPS and INS derived attitude parameters is better than 2 arcmins in heading, 1 arcmin in pitch and 3 arcmins in roll. This level of accuracy demonstrates the capability of GPS for cost-effective shipborne attitude determination at an accuracy level of 0.05     

两种涡鞭毛藻的周日垂直迁移特性研究

Ａｌｅｘａｎｄｒｉｕｍ ｌｕｓｉｔａｎｉｃｕｍ于１９８７年采自葡萄牙沿海，Ｙ－１００于１９８９年采自德国湾。在暗室中用一根柱长１５０ｃｍ，内径３．４ｃｍ的玻璃柱对两种涡鞭毛藻的垂直行特性进行研究。结果表明，两种藻均进行有规律的周日垂直迁移，且均在始前２ｈ开始向上迁移，光照结束前３ｈ开始向移速度约为２８０μｍ／ｓ，向下约为１４０μｍ／ｓ向下约为８５０μｍ／ｓ；Ｙ－１００向上迁移速度约为２８０μｍ／ｓ     

Artificial Reefs in the Low Productive Marine Environments of the Southeastern Mediterranean

Abstract. Fishery yields in the oligotrophic waters of the Southeastern Mediterranean arc low due to habitat and food limitations. A four year study of a complex of artificial structures established in the coastal waters of Israel points to several possible solutions to these problems. One approach is the artificial enrichment of the man-made reef with trash fish. This, together with the configuration of the reef, caused a significant increase in the abundance of fish predators such as groupers of the genus Epinephclus. Omnivores and herbivores were attracted only by the presence of artificial structures. Some species, such as the slipper lobster Scyllurides lulus, only use the man-made reef for shelter during part of the day or season; they forage over a much larger area the rest of the time and are important "importers" of food to the artificial habitat. Artificial kelp were effective in recruiting juveniles and small fishes to the site.