A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Petrology of the Jurassic Shah-Kuh granite (eastern Iran), with reference to tin mineralization

The Shah-Kuh granitic pluton of eastern Central Iran was emplaced 165 Ma ago, in an active continental margin setting. It is made of two main units: a granodioritic unit (SiO₂=63–71 wt%) to the north–west and a syenogranitic unit (SiO₂=73–77 wt%) to the south–east. The former unit displays seriate medium-grained textures and contains locally abundant mafic enclaves. The latter unit is medium- to coarse-grained and porphyritic, with 0.5–3 cm long K-feldspar megacrysts. Fine-grained granitic bodies are present in both units. The rocks are metaluminous to slightly peraluminous (I-type) and peraluminous (S-type) and belong to the ilmenite-series granites. Fractional crystallization appears to have been a very effective differentiation process in both units, and the fractionated mineral assemblages are determined by mass balance calculations. Isotopic data (Sr_i=0.7065 and εNdt=−2.5) are consistent with a young upper crustal protolith. Tin mineralization in sheeted quartz-tourmaline (-cassiterite) veins is spatially associated with the granodioritic unit. The veins formed by hydraulic fracturing when the granodioritic to monzogranitic magma became water-saturated and exsolved a fluid phase during crystallization. The reduced nature of this magma is responsible for the incompatible behaviour of Sn, likely to favour Sn concentration in the residual melt and then in the exsolved fluid. Another fluid phase was exsolved by the syenogranitic magma and was responsible for local greisenized granites, characterized by high Y and HREE-contents and non-fractionated REE distribution patterns. Field and mineralogical data show that the (B, Sn) vein-forming fluid was different from the (F, Li) greisen-forming fluid.     

Spatial pattern of variation in populations of Acacia nilotica in semi-arid environment

Variability among populations was analyzed in five provenances of Acacia nilotica from spatially variable habitats. Populations of A. nilotica developed in response to their habitat conditions. The level of variability was significantly high among the populations. Phenotypic variability was extremely high for leaf and stipular spine characteristics. The nature of morphological variability for vegetative traits appeared environmentally controlled. The differentiation of leaf and stipular spine expression seems to have an adaptive significance for the species in terms of water economy. Although, seed and pod characteristics are genetically controlled showing a lower proportion of variability but these traits supported r and k-selection that may allow the species to survive under a wide array of contrasting habitats. The study suggested that populations of A. nilotica are differentiated in relation to the heterogeneity of environment. These populations became adapted to their habitat through the variability of morphological expressions. The morphologically differentiated populations of the species had allowed them to maintain themselves in a wide array of environmental situations enabling A. nilotica to occupy ample ecological ranges.     

Modeling of packed absorption tower for volatile organic compounds emission control

Development of chemical industry and high vapor pressure of volatile organic compounds (VOCs) have been caused that these materials recently be considered as a source of air pollution. These are different methods for separation of VOC from air that absorption by suitable and selective solvent is an efficient method. In this research, mathematical modeling of a packed absorption tower for separation of VOCs from air has been presented. Then, acetone vapors separation in this tower and with Intalox saddle packing has been investigated. Concentration of acetone in inlet air stream was 1.5 mol % which has reduced to 150 ppm (0.015 mol %) in effluent air stream. The results show that the packed absorption tower with this type of packing can separate 99% of acetone vapors. Comparison of the results obtained by Intalox saddle packing with the results obtained by another type of packing (with trade mark of Kerapak patented by Sulzer Company) shows that the tower gives the same efficiency for acetone separation. Thus, the efficiency of absorption process, mainly, depends on solvent type, composition of VOC in feed air, desired composition of VOC in outlet air (or percentage of VOC separation) and pressure drop.     

Potassium induced salinity tolerance in wheat (Triticum aestivum L.)

Water culture experiments were conducted to study the response of ten wheat genotypes to external K application (10 mmol KCI dm^?3) at seedling stage under saline condition (0 and 100 mmol NaCl dm^?3). The data showed that there was an increase in the shoot and root length with the application of external K. The increase was more pronounced under control than under saline conditions. The better performing genotypes under two treatments were Bhitai, NIAB-41, NIAB-I076 and Khirman. The enhanced growth of these genotypes under saline condition might be due to the quick response to external K application, resulting in high K/Na ratio. The results indicated that the genotypes, which have the ability of enhanced K/Na discrimination, might perform better under saline conditions when sufficient potassium is applied in the rooting medium.     

Les laves du mont Bangou : une première manifestation volcanique éocène, à affinité transitionnelle,de la Ligne du Cameroun

Mount Bangou, an Eocene volcano (⁴⁰K–⁴⁰Ar ages between 44.7 and 43.1 ± 1 Ma) is the oldest dated volcano of the Cameroon Line. In this region, two magmatic series, evolving by fractional crystallization, show transitional affinities that are exceptionally known in this sector. Mineral compositions of basaltic rocks (scarce modal olivine and occurrence of normative hypersthene) as well as geochemical characteristics (low Ba, La, Ta contents and high Y/Nb ratios) are in agreement with this trend. The succession of magmas evolving in time from transitional to more typical alkaline compositions is evidenced in a continental setting. To cite this article: J. Fosso et al., C. R. Geoscience 337 (2005).     

Analysis of pressuremeter geometry effects in clay using critical state models

The conventional interpretation methods of pressuremeter testing effectively approximate pressuremeter membranes as infinitely long. As a result, the effects of the two‐dimensional geometry of pressuremeters are ignored, leading to an overestimation of soil shear strength by pressuremeter testing, as demonstrated in several previous studies. This paper presents results of a numerical study of two‐dimensional geometry effects on self‐boring pressuremeter tests in undrained clay. The results are obtained using critical state soil models with an effective stress formulation. This is in contrast to most (if not all) existing studies on pressuremeter geometry effects, which were based on perfectly plastic soil models (e.g. Yu (Cavity expansion theory and its application to the analysis of pressuremeters. DPhil Thesis, The University of Oxford, 1990), Yeung and Carter (Proc. 3rd Int. Symp. on Pressuremeters, 1990), and Houlsby and Carter (Géotechnique, 1993; 43 (4):567–576)). The present study suggests that the overestimation of soil strength due to the neglect of finite pressuremeter length is significantly affected by the soil model used in the calculations. It is found that for clays with a high overconsolidation ratio (OCR) the strength overestimation predicted using critical state soil models could be considerably smaller than that predicted using perfectly plastic soil models. The main conclusion of this numerical study is that care must be exercised before directly applying any numerically determined pressuremeter geometry correction factors in practice. Copyright © 2005 John Wiley & Sons, Ltd.     

Intraplate deformation and 3D rheological structure of the Rhine Rift System and adjacent areas of the northern Alpine foreland

The lithosphere of the Northern Alpine foreland has undergone a polyphase evolution during which interacting stress-induced intraplate deformation and upper mantle thermal perturbations controlled folding of the thermally weakened lithosphere. In this paper we address relationships among deeper lithospheric processes, neotectonics and surface processes in the Northern Alpine foreland with special emphasis on tectonically induced topography. We focus on lithosphere memory and neotectonics, paying special attention to the thermo-mechanical structure of the Rhine Graben System and adjacent areas of the northern Alpine foreland lithosphere. We discuss implications for mechanisms of large-scale intraplate deformation and links with surface processes and topography evolution.     

Gamma-ray bursts from a close pulsar binary system?

The close neutron-star binary system comprised of the radio pulsars PSR J0737-3039 A,B is discussed. An analysis of the observational data indicates that the wind from pulsar A, which is more powerful than the wind from pulsar B, strongly distorts the magnetosphere of pulsar B. A shock separating the relativistic wind from pulsar A and the corotating magnetosphere of pulsar B should form inside the light cylinder of pulsar B. A weakly diverging “tail” of magnetic field is also formed, which stores a magnetic energy on the order of 10³⁰ erg. This energy could be liberated over a short time on the order of 0.1 s as a result of reconnection of the magnetic-force lines in this “tail,” leading to an outburst of electromagnetic radiation with energies near 100 keV, with an observed flux at the Earth of 4 × 10^?11 erg cm^?2 s^?2. Such outbursts would occur sporadically, as in the case of magnetic substorms in the Earth’s magnetosphere.