Longevity of fluorine-bearing tremolite on Venus

There is a general belief that hydrous minerals cannot exist on Venus under current surface conditions. This view was challenged when Johnson and Fegley (2000, Icarus 146, 301-306) showed that tremolite (Ca₂Mg₅Si₈O₂₂(OH)₂), a hydrous mineral, is stable against thermal decomposition at current Venus surface temperatures, e.g., 50% decomposition in 4 Ga at 740 K. To further explore hydrous mineral thermal stability on Venus, we experimentally determined the thermal decomposition kinetics of fluorine-bearing tremolite. Fluor-tremolite is thermodynamically more stable than OH-tremolite and should decompose more slowly. However how much slower was unknown. We measured the decomposition rate of fluorine-bearing tremolite and show that its decomposition is several times to greater than ten times slower than that of OH-tremolite. We also show that F-bearing tremolite is depleted in fluorine after decomposition and that fluorine is lost as a volatile species such as HF gas. If tremolite ever formed on Venus, it would probably also contain fluorine. The exceptional stability of F-bearing tremolite strengthens our conclusions that if hydrous minerals ever formed on Venus, they could still be there today.     

North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.     

Dynamics of Two Planets in the 3/2 Mean-motion Resonance: Application to the Planetary System of the Pulsar PSR B1257+12

This paper considers the dynamics of two planets, as the planets B and C of the pulsar PSR B1257+12, near a 3/2 mean-motion resonance. A two-degrees-of-freedom model, in the framework of the general three-body planar problem, is used and the solutions are analyzed through surfaces of section and Fourier techniques in the full phase space of the system.On the possibility of existence of a fourth planet in distant orbit, see Wolszczan et al., 2000     

Quintessential inflation models with a nonminimally coupled scalar field

The evolution of a homogeneous, isotropic cosmological model driven by a nonminimally coupled scalar field is studied. The potential for the quintessential inflation model proposed by Peebles and Vilenkin is selected as a scalar potential. Possible scenarios for the cosmological dynamics are described in the conformal Einstein and Jordan representations. It is shown that, unlike in models with a minimal scalar field, here a class of solutions exists for which the scalar field is fixed at finite values during cosmological expansion. __________ Translated from Astrofizika, Vol. 49, No. 3, pp. 487–498 (August 2006).     

Composition of brines in halite‐hosted fluid inclusions in the Upper Ordovician,Canning Basin,Western Australia: new data on seawater chemistry

Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO₄ content.     

Screening of polymers on selected Hawaii soils for erosion reduction and particle settling

In recent years, high‐molecular‐weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory‐scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8·5 cm h^?1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil‐treatment combinations. Among the PAMs, Superfloc A‐836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha^?1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil‐D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation‐exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds. Copyright © 2005 John Wiley & Sons, Ltd.