Soil geochemistry of Mother Lode-type gold deposits in the Hodson mining district, central California, U.S.A.

The Hodson mining district is in the westernmost foothills of the Sierra Nevada in California, about 17 km west of the town of Angels Camp. This district is part of the West Gold Belt, which lies about 12–16 km west of, and generally parallel to, the better known Mother Lode Gold Belt in central California. The district produced several million dollars worth of Au between about 1890 and 1940.     

Kenntnis der Randstrukturen des Witwatersrand-Beckens im nördlichen Oranje-Freistaat-Goldfeld (Südafrika)

Zusammenfassung Eine Analyse der Randstrukturen des Witwatersrand-Beckens im nördlichen Oranje-Freistaat-Goldfeld zeigt, daß das tektonische Bild der Beckenrandregion nacheinander durch verschiedene Deformationsakte von unterschiedlichem Charakter geprägt worden ist. Auf eine Einengungsphase von spät-Witwatersrand-Alter, die zur Bildung einer randlichen Aufrichtungszone und zum Aufreißen eines Systems von 'normalen und antivergenten Aufschiebungen führte, folgte während des Unteren Ventersdorp eine jüngere Zerrungsphase, bei der es zu einem staffeiförmlgen Zerbrechen der ursprünglich eingeengten Scholle kam. Die Zerrung hängt sehr wahrscheinlich mit dem Zerbrechen der Beckenrandregion während oder unmittelbar nach der Extrusion der Unteren Ventersdorp-Laven zusammen. Dabei wurde ein schmaler randparalleler Streifen der Beckenfüllung in einem Graben versenkt ('Odendaalsrus-Graben). Die abgesunkenen Schollenteile sind in sich noch stark zerbrochen und gewöhnlich schiefgestellt. Da der versenkte Streifen durch ein primäres Einmuldungsstadium hindurchgegangen ist, deutet die Grabenbildung offenbar eine Fortsetzung der Beckenbildungsvorgänge 'mit anderen Mitteln an. — Die Bewegungen haben ein Alter von etwa 2,1 Mrd. Jahren; sie fallen somit ins frühe Präkambrium und sind keinesfalls 'intraalgonkisch, wie es noch bis in die jüngste Vergangenheit angenommen wurde.Tektonische Experimente haben ergeben, daß sich die wichtigsten Störungssysteme der realen Beckenrandstrukturen bei entsprechend gewählter Versuchsanordnung auch künstlich erzeugen lassen.

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The Orange Free State goldfield represents the southernmost part of the Witwatersrand Basin (Fig. 1) which is completely buried under a cover of Ventersdorp and Karroo rocks. The pre-Karroo geology of this area is characterized by a major rift system trending SSW-NNE ('Odendaalsrus graben), followed to the east by a V-shaped horst and two minor rift blocks (Fig. 2). The main graben is bounded by two principal faults (Border Fault, De Bron Fault, Fig. 4) which are roughly parallel to the western rim of the basin.A tectonic analysis of the basin-edge structures in the northern part of the graben reveals that the basin rim has been subjected to a sequence of deformational acts working over a considerable period of time. A primary compression of the basin-edge region in Upper Witwatersrand times resulted in the formation of a marginal fold; since sedimentation continued, the different stages of the folding process were sometimes preserved by a set of minor unconformities within the youngest sediments (Elsburg A Reefs, Fig. 5). With increasing lateral pressure a couple of reverse faults developed to support the folding (faults No. 10 and 11, Figs. 6 and 7); the minor thrust faults No. 19 and 21 represent the second component of this fault system. A reconstruction of the original depositional plain of the Lower Agglomerate shows that the main thrust faults (No. 10 and 11) are definitely older than the Elsburg A 1 Reef and have been obviously revived after the younger sediments had been laid down (Fig. 8 a).In a later stage compression gave way to tensional forces bringing about a fracturing of the overturned limb of the marginal fold along normal faults (faults No. 4 and 7, Figs. 6 and 7). There is reason to believe that the tensional phase was associated with the incipient rifting during early Ventersdorp times and that these faults were more or less contemporaneous with the general tilting of the basin-edge as displayed to-day (cf. Figs. 3 and 4). Because of the westerly tilt the Boulder Beds dip towards the west, although they must have been originally deposited on a ± horizontal or slightly basinward dipping plain. Faulting was mostly accomplished before deposition of the Ventersdorp sediments and the Upper Ventersdorp Lavas took place; the latter are seldom or only to a small degree affected by the fractures (Figs. 3 and 4). — The age of the tectonics is about 2,1×10⁹ years, i. e. early Precambrian and not Algonkian as formerly supposed.Experimental work aiming at an imitation of the observed basin-edge structures has shown that the principal tectonic features can be produced artificially (Figs. 8 a and b). This refers in particular to the main system of thrust-faults as well as to the younger step-faults caused by tension.

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Résumé Les structures tectoniques au bord du Bassin de Witwatersrand dans le district de mines d'or septentrional de la République d'Orange (Afrique du Sud) ont été analysées. Il s'est montré qu'elles sont déterminées par l'action de plusieurs phases de déformation successives de caractères différents. Une phase de compression d'âge Witwatersrand supérieur a d'abord amené un redressement des couches dans une zone marginale du bassin, avec chevauchements à vergences «normales» et inverses. Elle était suivie pendant le Ventersdorp inférieur d'une phase de traction qui produisit des cassures en gradins dans le secteur primitivement comprimé. La traction est très vraisemblablement en relation avec l'effondrement de la zone marginale du bassin pendant ou peu après l'extrusion des laves inférieures de Ventersdorp. Une bande étroite de sédiments, parallèle au bord du bassin, fut alors affectée d'un affaissement (formation du «graben d'Odendaalsrus») où de nombreuses cassures à l'intérieur des compartiments affaissés ont résulté dans la formation de blocs plus ou moins inclinés. Puisque cette zone a d'abord passé par un stade synclinal, on a l'impression que l'effondrement du graben ne représente que la reprise de l'affaissement général du bassin à l'aide d'une «technique nouvelle». - Les mouvements ont un âge de 2.1 milliards d'années, ils datent par conséquent du Précambrien inférieur et ne sont point «intra-algonkiques» comme il fut encore admis tout récemment.Il a été possible de reproduire artificiellement les systèmes de failles les plus importants de la zone marginale du bassin, si les conditions de l'expériment étaient favorables.

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ROTATIONAL SLUMPS AND SLUMP SCARS IN SILURIAN ROCKS, WESTERN IRELAND

Curved or planar discordant surfaces occurring within a limited stratigraphic range immediately beneath shallow marine deposits represent penecontemporaneous shear surfaces along which slumps have moved. Rotated packets of strata frequently retained within the curved discordant surfaces show both internal and external evidence of having moved laterally. Movement is considered to have been triggered off by a sudden shock or shocks which may have been either of sedimentary or tectonic origin. The slumping occurred at the change in gradient between slope and shallow marine shelf deposits.     

Carbon,oxygen and sulphur isotope variations in concretions from the Upper Lias of N.E. England

Carbon, oxygen and sulphur isotope data for transects across two pyrite-bearmg carbonate concretions, and their host sediments, from the Upper Lias of N.E. England show symmetrical zonation. δ¹³C_PDB values of the calcite cement (?12.9 to ?15.4%.) indicate that most of it originated from organic matter by bacterial reduction of sulphate, augmented with marine and, to a lesser extent, fermentation derived carbonate. Organic carbon (δ¹³C_PDB = ?26.1 to ?37.0%.). reflects the admixture of allochtho-nous terrestrial organic matter with marine material and the selective preservation of isotopically light organic material through microbiological degradation.Two phases of pyrite are present in each concretion. The earlier framboidal pyrite formed throughout the sediment prior to concretionary growth and has δ³⁴S_CD values of ?22 to ?26%. indicating formation by open system sulphate reduction. The later euhedral phase is more abundant and reaches values of ? 2.5 to ? 5.5%. at concretion margins. This phase of sulphate reduction provided the carbonate source for concretionary growth and occurred in a partially closed system. The δ¹³C and δ³⁴S data are consistent with mineralogical and chemical evidence which suggest that both concretions formed close to the sediment surface. The δ₁₈O values of the calcite in one concretion (δ¹⁸O_PDB = 2.3 to ?4.8%.) indicate precipitation in pore waters whose temperature and isotopic composition was close to that of overlying seawater. The other concretion is isotopically much lighter (δ¹⁸O_PDB?8.9 to ?9.9%.) and large δ¹⁸O differences between concretions in closely-spaced horizons imply that local factors control the isotopic composition of pore waters.     

The major‐ and trace‐element whole‐rock fingerprints of Egyptian basalts and the provenance of Egyptian artefacts

Discrimination diagrams have been developed that source Egyptian basaltic artefacts using whole‐rock major element geochemistry. These include K₂O versus SiO₂, TiO₂ and P₂O₅ against MgO/Fe₂O₃^t (total Fe as Fe₂O₃), and a discriminant analysis diagram using SiO₂, Fe₂O₃^t, CaO, and MnO. A complementary set of diagrams uses easily obtained trace element data (Nb/Y versus Zr/Nb; Zr [ppm] versus Rb/Sr; TiO₂ [wt % volatile free] versus V; and Cr [ppm] versus Zr/Y) to determine the bedrock sources. These diagrams have been applied to seven First Dynasty basalt vessels (Abydos), two Fourth Dynasty basalt paving stones (Khufu's funerary temple, Giza), and two Fifth Dynasty paving stones (Sahure's complex, Abu Sir). They show that the bedrock source for all the artefacts was the Haddadin flow in northern Egypt. Multidimensional scaling and cluster analysis applied to the whole‐rock data (major elements and trace elements together) and previously published mineral fingerprinting studies confirm these results. Comparing mineral versus whole‐rock fingerprinting techniques, a major advantage of the former is the small sample size required (0.001 g compared to ≥ 0.1 g). Analytical costs are similar for both methods assuming that a comparison (bedrock) database can be assembled from the literature. For most archaeological problems, a whole‐rock bedrock database is more likely to exist than a mineral database, and whole‐rock analyses on artefacts will generally be easier to obtain than mineral analyses. Whole‐rock fingerprinting may be more sensitive than mineral‐based fingerprinting. Thus, if sample quantity is not an issue, whole‐rock analysis may have a slight cost, convenience, and technical advantage over mineral‐based methods. Our results also emphasize that the Egyptians cherished their Haddadin basalt flow and used it extensively and exclusively for manufacturing basalt vessels and paving stones for at least 600 years (∼3150 B.C. to 2500 B.C., approximate ages of the vessels and Abu Sir paving stones, respectively). © 2001 John Wiley & Sons, Inc.     

Geologic sources and geographic distribution of sand tempers in prehistoric potsherds from the Mariana Islands

Temper sands in prehistoric potsherds of the Mariana Islands include terrigenous detritus derived from Paleogene volcanic bedrock and calcareous grains derived chiefly from modern fringing reefs, but also in part from uplifted Neogene limestones overlying volcanic bedrock. Calcareous sands are nondiagnostic of island of origin, but volcanic sands and the terrigenous component of hybrid sands composed of mixed terrigenous and calcareous grain types can be traced to geologic sources on Saipan and Guam, the only occupied islands where volcanic bedrock is extensively exposed. Quartzose tempers of several types were derived exclusively from dacitic volcanic rocks on Saipan. Nonquartzose tempers of andesitic parentage derive from both Saipan and Guam, but abundance of orthopyroxene as well as clinopyroxene is diagnostic of Saipan andesitic tempers, the presence of olivine is diagnostic of selected tempers from Guam, and placer temper sands rich in heavy ferromagnesian minerals occur only in sherds on Guam. Temper analysis documents widespread ceramic transfer from Saipan to other islands throughout Mariana prehistory, and more restricted ceramic transfer from Guam to nearby Rota, although the origin of some andesitic temper types is petrographically indeterminate. © 2001 John Wiley & Sons, Inc.     

Mapping of benthic enrichment patterns in Narragansett Bay,Rhode Island

A synoptic reconnaissance survey was performed over a five-day period in August 1988 to assess benthic habitat quality throughout Narragansett Bay, Rhode Island, using REMOTS^® sediment-profile photography and analysis in combination with measurements of the levels ofClostridium perfringens spores (a fecal indicator) in sediments. Three main areas of degraded benthic habitat quality related to either excessive organic enrichment or physical disturbance were identified based solely on the REMOTS^® analysis: the Providence River Reach, Greenwich Bay and its associated coves and harbors, and an area located along the southwest side of Prudence Island. Sediments at many stations in these areas exhibited shallow apparent redox-potential discontinuity (RPD) depths, high apparent oxygen demand, and low-order benthic successional stages. ElevatedClostridium perfringens spore counts in surface sediments were attributed to inputs from wastewater treatment facilities. The highest spore counts occurred at the head of the bay, where wastewater treatment discharges and associated combined sewer overflows are numerous. Using data from the REMOTS^® analysis and the sediment inventory ofC. perfringens spores, a distinction was made between organic enrichment of the bottom from sewage, versus nonsewage enrichment or physical disturbance. The combination of techniques employed in this investigation could be used to design more efficient monitoring programs to assess eutrophication effects in estuaries and determine the effectiveness of regulatory or management initiatives to reduce organic overenrichment of benthic habitats.     

Two magmatic series with island arc affinities within the vourinos ophiolite

Within the Vourinos ophiolite evidence of two magmatic series has been preserved in cognate cumulates and in effusive and hypabyssal rocks, which constitute the earlier Krapa sequence and the younger Asprokambo sequence. The Asprokambo dyke basic magmas which are poor in incompatible elements and relatively Ni and Cr rich, bear some resemblance to very low Ti basalts (transitional to boninites) found in subduction related arcs or interarc basins. Krapa series magmas from sills, massive and pillow lavas are best equated with low-K tholeiites of island arc suites. Compositions of Al- and Ti- poor Cpx in lavas from both series are comparable to those in island arc basalts, the Asprokambo Cpx being richer in Ca and Cr than those from Krapa.The large volume of cumulates from the Krapa sequence displays the following crystallization order: Ol±Sp, Cpx, Pl±Opx, Mt. Periodic influx of fresh magma batches into the magma chamber occurred mainly during the formation of the lower cumulates (wehrlite, Ol-clinopyroxenite and melagabbro). The upper cumulates, gabbronorite and leucogabbronorite with minor Mt-bearing gabbronorite, crystallized in the upper levels of a magma chamber which became progressively smaller with time. In the Asprokambo sequence, Ol+Sp, Opx, Cpx, PI and Amph are the successively crystallizing phases. The ortho to heteradcumulates consist of websterite, Pl-websterite, gabbronorite, amphibole bearing leuconorite, diorite and granophyre. In cumulates, especially in the lower Krapa sequence, significant subsolidus reaction was probably induced by the persistence of high geothermal gradients linked to continuous magmatism. Petrological features indicate that the evolution of the Krapa series is more compatible with an intermediate fractional/equilibrium crystallization history in an initially open system, whereas nearly perfect fractional crystallization in closed system may have occurred in the small Asprokambo magma chambers. Chemical variations in the lavas of both series can be explained in terms of crystallization of the observed cumulates. Significantly, the Asprokambo intrusives have igneous Mg-hornblende and vanadium bearing, chromian, aluminous titaniferous magnetite, crystallization of which is responsible for the calcalkaline evolutionary trend of these rocks. Major and trace element modelling necessitates a two stage model for the petrogenesis of the Vourinos parental melts, involving high-degree remelting of previously depleted mantle sources favoured by the influx of subduction derived hydrous fluids. The primary magmas parental to the Krapa and Asprokambo series could have been derived respectively by 20 and 30% equilibrium partial fusion of variably depleted lherzolitic sources, leaving residua having a harzburgitic to dunitic composition.     

Significance of Europium anomalies in silicate melts and crystal-melt equilibria: a re-evaluation

Although europium speciation in silicate melts partly reflects prevailing oxygen fugacities, melt composition and structure play the major role in determining Eu²⁺/ Eu³⁺ ratios and europium partitioning into mineral phases. Experimental evidence by different investigators on the magnitude of the compositional effect on Eu²⁺/Eu³⁺ provides consistent results only if account is taken of the oxygen buffer system employed in the experiments. The medium-dependent reduction of europium can be understood in terms of the preferential stabilization of Eu²⁺ by a strong aluminosilicate complex in the melt phase, and to a much lesser degree by metasilicate complexes. The stability of these complexes increases as the field strength of the associated cation species decreases. Hence Eu²⁺-aluminosilicate complexes are preferentially stabilized relative to trivalent lanthanides in melts of appropriate composition and their presence minimizes the enthalpy of the melt. The influence of these complexes is particularly pronounced in melts with a high feldspathic component and a strongly polymerized structure. Their petrogenetic influence is best documented through the behaviour of europium relative to the other lanthanides during anhydrous anatexis in high-grade metamorphic terrains and in the anomalous europium partition coefficients of phenocryst phases which formed during the crystallization of highly silicic magmas.