An improved specific interaction model for seawater at 25°C and 1 atmosphere total pressure

Equations recently developed by Pitzer are applied to a seawater model on the assumption that only interactions between ions of opposite charge sign are significant. This model is shown to give good agreement with available experimental data for the osmotic coefficient and for the mean-ion activity coefficients of the major electrolyte components. The results are compared with the predictions of the ion-association model and with a number of models using the concept of specific ionic interaction. The relative merits of the various models are discussed. Pitzer's original equations are modified to enable the calculation of conventional single-ion activity coefficients. These values are compared with those obtained on the basis of alternative conventions and an encouraging measure of agreement is observed. It is concluded that the new model introduces a fluency into the specific interaction approach that should greatly facilitate the incorporation of trace components into future models.     

Mean current velocity measurement from a movable base

This paper discusses the possibility of measurement of the current velocity vector characteristics averaged over the time of continuous regular down-up probings from a moving carrier. The measurements can be carried out either from a moving vessel or from a helicopter, floating on or hovering above the sea surface. As an illustration for the suggested technique,in situ observations compiled by a free-component (±XYZ) VEGA-3 probe in the Guiana current region in March 1990 are provided. Comparison of the results with buoy data shows good agreement within the accuracy limits of the instruments employed.Translated by Vladimir A. Puchkin.     

Fine structure of the temperature field and the transfrontal exchange in the East Kamchatka current

CTD data are used to study the relationship between the temperature field fine structure and the location of the frontal zones and synoptic eddies in the region adjacent to the eastern coast of the Kamchatka peninsula. High levels of fine structure activity were observed in the frontal zone of the East Kamchatka current and in the peripheries of anticyclonic eddies. Estimates of the coefficient of the horizontal turbulent exchange and the transfrontal (lateral) heat flux are derived.Translated by Mikhail M. Trufanov.     

Remote determination of momentum-flux profiles in the lower atmospheric boundary layer

An acoustic locator—a sodar—is a unique instrument for getting the objective characteristics of the current state of the atmospheric boundary layer (ABL) owing to a combination of such properties as remoteness, mobility, resolution, and information content. This study demonstrates the capabilities of a sodar to obtain data on the second moments of the field of wind-velocity fluctuations, in particular, the profiles of momentum flux in the lower ABL, which are very important in practical applications. A corresponding method is described, and the results of its experimental verification and some examples of its application under the conditions of different ABL stratification are presented.     

On the collapse of a vertical packet of mixed patches. Laboratory and field studies

Visualization of a collapsing vertical packet of patches in a laboratory experiment and the results of acoustical sounding under field conditions allowed us to discriminate the stage of its evolution which was previously unknown. It is defined by the variations of the horizontal dimensions of patches and their effective scattering surface with a period ofT=150–250/N, whereN is the Brunt-Väisälä frequency. The horizontal dimensions of patches can reach 40% of their final dimensions at the evolution stage discriminated.Translated by Mikhail M. Trufanov.     

Oxidative stress in ecotoxicology: from the analysis of individual antioxidants to a more integrated approach

An integrate approach will be discussed for investigations on oxidative stress in xenobiotic toxicity. While the analysis of individual antioxidants is useful for their sensitivity and to understand the mode of action of a stressor, the integration with the analysis of the total antioxidant capacity provides a more holistic assessment of the overall biological significance of such variations. TOSC has a greater predictive value on the health condition of the organisms and allows to discriminate the different role of specific ROS in oxidative stress syndrome.     

Secondary flow caused by differential roughness,Langmuir circulations,and their effect on the development of sand ribbons

The process of Differential Roughness Secondary Flow (DRSF), hitherto little recognized, recently was demonstrated in a wind tunnel and in a flume. It is suggested here the DRSF may, in the natural environment, play an important part in the persistence and sharp definition of sand ribbons, previously initiated by other processes. In 1980 Karl described a series of sand ribbons, alternating with exposed substrate, which he attributed to the effect of Langmuir circulations. Although Langmuir Circulation Secondary Flow (LCSF) may indeed, in some cases, initiate sand ribbons, the sharply-defined edges typical of these features are explained better by DRSF.     

Palaeo-carbonate seep structures above an oil reservoir, Gryphon Field, Tertiary, North Sea

Petrographic and geochemical analyses performed on a North Sea core from the Gryphon Field reveal the presence of palaeo-degassing features surrounded by injected sandstones in the Eocene interval. The injected sandstones are oil-stained and poorly cemented by carbonate and quartz. ¹⁸O isotope analyses indicate that carbonate cementation occurred during shallow burial (likely less than about 300 m). Depleted ¹³C (around –30 V-PDB) carbonate cement suggests that bicarbonate was derived from the microbial oxidation of oil and gas. Late quartz overgrowths enclose oil present in the injected units. The tubular degassing conduits are composed of zoned cements and have ¹⁸O and ¹³C isotope values similar to the injected sandstones, indicating that oil and gas seepage induced the precipitation of authigenic carbonate in the shallow subsurface. Oil inclusions in inter- and intra-crystal cement sites in both injected sandstones and degassing conduits indicate that oil seepage was an ongoing feature at shallow burial. A proposed model involves oil and gas seepage and the formation of the degassing conduits, followed by a sand injection phase. It seems likely that oil and gas continued to leak towards the seabed by exploiting the network of permeable injected sandstones and the horizons of porous degassing features.     

X-band sea-clutter nonstationarity: influence of long waves

In this paper, we deal with the problem of modeling the backscattering from sea surface for low-grazing-angle and high-resolution radar systems. Based on the electromagnetic two-scale model, we analyzed both the amplitude and frequency modulations induced on the small-scale Bragg resonant waves by the large-scale surface tilt and advection due to the swell presence. Evidence of sea-clutter nonstationarity has been verified and the relationship between the variations of clutter spectral features, such as texture, Doppler centroid, and bandwidth, have been studied by processing real sea-clutter data recorded by the IPIX radar of McMaster University, Hamilton, ON, Canada. An autoregressive nonstationary process is proposed and validated to model the physical phenomenon.     

Ecotone or Ecocline: Ecological Boundaries in Estuaries

Two main ecological boundaries, ecotone and ecocline, have been defined in landscape ecology. At this scale, the estuary represents a boundary between rivers and the sea, but there has been no attempt to fit empirical data for estuaries to these boundary models. An extensive data set from the Thames estuary was analysed using multivariate techniques and species-range analysis, in order to investigate whether the ecocline or the ecotone model was most relevant to this estuary. Data for periods of high and low freshwater flow allowed the impact of large-scale fluctuations implicit in both models to be determined.A continuum of assemblages existed along the salinity gradient from freshwater river to the North Sea, with shifts in the ranges of organisms apparent in response to changes in freshwater flow. This pattern closely fits an ecocline model. However, the estuary differs from previously defined ecoclines in having two overlapping gradients in the major stressor: from river to mid-estuary for freshwater species and from sea to mid-estuary for marine species. We propose, therefore, that the estuary represents a two-ecocline model, with fauna inhabiting the mid-estuary being either freshwater or marine species at the edge of their range, rather than ‘ true estuarine organisms ’. This allows a redefinition of the Remane diagram, with estuarine species removed, and supports previous arguments that brackish-water species do not exist. Such two-ecocline models may also exist in other marine systems, such as rocky shores.