Metamorphism in Archaean greenstone belts: calculated fluid compositions and implications for gold mineralization

An inescapable consequence of the metamorphism of greenstone belt sequences is the release of a large volume of metamorphic fluid of low salinity with chemical characteristics controlled by the mineral assemblages involved in the devolatilization reactions. For mafic and ultramafic sequences, the composition of fluids released at upper greenschist to lower amphibolite facies conditions for the necessary relatively hot geotherm corresponds to those inferred for greenstone gold deposits (X_CO2= 0.2–0.3). This result follows from the calculation of mineral equilibria in the model system CaO–MgO–FeO–Al₂O₃–SiO₂–H₂O–CO₂, using a new, expanded, internally consistent dataset. Greenstone metamorphism cannot have involved much crustal over-thickening, because very shallow levels of greenstone belts are preserved. Such orogeny can be accounted for if compressive deformation of the crust is accompanied by thinning of the mantle lithosphere. In this case, the observed metamorphism, which was contemporaneous with deformation, is of the low-P high-T type. For this type of metamorphism, the metamorphic peak should have occurred earlier at deeper levels in the crust; i.e. the piezothermal array should be of the ‘deeper-earlier’type. However, at shallow crustal levels, the piezothermal array is likely to have been of ‘deeper-later’type, as a consequence of erosion. Thus, while the lower crust reached maximum temperatures, and partially melted to produce the observed granites, mid-crustal levels were releasing fluids prograde into shallow crustal levels that were already retrograde. We propose that these fluids are responsible for the gold mineralization. Thus, the contemporaneity of igneous activity and gold mineralization is a natural consequence of the thermal evolution, and does not mean that the mineralization has to be a consequence of igneous processes. Upward migration of metamorphic fluid, via appropriate structurally controlled pathways, will bring the fluid into contact with mineral assemblages that have equilibrated with a fluid with significantly lower X_CO2. These assemblages are therefore grossly out of equilibrium with the fluid. In the case of infiltrated metabasic rocks, intense carbonation and sulphidation is predicted. If, as seems reasonable, gold is mobilized by the fluid generated by devolatilization, then the combination of processes proposed, most of which are an inevitable consequence of the metamorphism, leads to the formation of greenstone gold deposits predominantly from metamorphic fluids.     

Material instability for drained and undrained behaviour. Part 1: Shear band generation

To increase the insight into the phenomenon of liquefaction a theoretical study has been performed of material instability for undrained behaviour. Material instability concerns the instability of an equilibrium state of an infinite homogeneous solid for both uniform deformation and shear-band generation. In this paper shear-band generation is considered. In a companion paper the case of uniform deformation is elaborated and combined with the current results. In this paper it is shown that, for a contractant material, shear-band generation is accelerated by decreasing the drainage.     

A high resolution,multiproxy Late‐glacial record of climate change and intrasystem responses in northwest England

A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.     

A sapphirine–phlogopite–cordierite paragenesis in a low-P amphibolite facies terrain, Arunta Inlier, Australia

Summary Silica-undersaturated phlogopite schists from the Cackleberry Metamorphics, Arunta Inlier, central Australia, preserve relatively low-temperature sapphirine-bearing parageneses that developed during low-pressure upper amphibolite facies metamorphism. Peak metamorphic phlogopite–cordierite–sapphirine assemblages are interpreted to have formed during the same event recorded in nearby metapelites, at c.3 kbar and 650–700 °C. Initial cooling of the terrain resulted in the breakdown of sapphirine to corundum–chlorite–phlogopite and corundum–spinel–chlorite assemblages. Further retrogression at greenschist facies conditions resulted in the replacement of sapphirine by diaspore–chlorite intergrowths. The reaction textures are consistent with a near-isobaric heating-cooling path at low-pressure, and provide evidence for the stability of sapphirine at c.700 °C at low pressures in rocks of an appropriate Mg- and Fe³⁺-rich bulk composition. Received August 15, 2001 accepted December 27, 2001     

A chum scale pattern analyzer and stock identification based onscale patterns by discriminant function and power spectrum analysis

An optoelectronic instrument has been developed to analyze the scales and scale patterns of chum salmon. This device, with specially developed software, has been used to study populations of salmon. Fish from two different rivers approximately 200 km apart from each other were grouped with an accuracy of 82% or more. Machine-measured ages coincided with those derived from visual estimation in approximately 80% of the fish sampled. These results suggest the proposed system could be of practical use for measuring and analyzing the scale patterns that allow one to accurately measure both natural and farmed populations of salmon     

Comparison of results from several AOGCMs for global and regional sea-level change 1900–2100

 Sea-level rise is an important aspect of climate change because of its impact on society and ecosystems. Here we present an intercomparison of results from ten coupled atmosphere-ocean general circulation models (AOGCMs) for sea-level changes simulated for the twentieth century and projected to occur during the twenty first century in experiments following scenario IS92a for greenhouse gases and sulphate aerosols. The model results suggest that the rate of sea-level rise due to thermal expansion of sea water has increased during the twentieth century, but the small set of tide gauges with long records might not be adequate to detect this acceleration. The rate of sea-level rise due to thermal expansion continues to increase throughout the twenty first century, and the projected total is consequently larger than in the twentieth century; for 1990–2090 it amounts to 0.20–0.37 m. This wide range results from systematic uncertainty in modelling of climate change and of heat uptake by the ocean. The AOGCMs agree that sea-level rise is expected to be geographically non-uniform, with some regions experiencing as much as twice the global average, and others practically zero, but they do not agree about the geographical pattern. The lack of agreement indicates that we cannot currently have confidence in projections of local sea-level changes, and reveals a need for detailed analysis and intercomparison in order to understand and reduce the disagreements. Received: 1 September 2000 / Accepted: 20 April 2001     

The influence of a non‐associated flow rule on the calculation of the factor of safety of soil slopes

This paper presents a method that incorporates a non‐associated flow rule into the limit analysis to investigate the influence of the dilatancy angle on the factor of safety for the slope stability analysis. The proposed method retain's the advantage of the upper bound method, which is simple and has no stress involvement in the calculation of the energy dissipation and the factor of safety. Copyright © 2001 John Wiley & Sons, Ltd.     

Why Mt Etna?

The Etna volcano is located in an apparently anomalous position on the hinge zone of the Apennines subduction and its Na-alkaline geochemistry does not favour a magma source from the deep slab as indicated for the Aeolian K-alkaline magmatism. The steeper dip of the regional foreland monocline at the front of the Apennines in the Ionian Sea than in Sicily, implies a larger rollback of the subduction hinge in the Ionian Sea. Moreover, the lengthening of the Apennines arc needs extension parallel to the arc. Therefore, the larger southeastward subduction rollback of the Ionian lithosphere with respect to the Hyblean plateau in Sicily, should kinematically produce right-lateral transtension and a sort of vertical 'slab window' which might explain (i) the Plio-Pleistocene alkaline magmatism of eastern Sicily (e.g. the Etna volcano) and (ii) the late Pliocene to present right lateral transtensional tectonics and seismicity of eastern Sicily. The area of transfer of different dip and rollback occurs along the inherited Mesozoic passive continental margin between Sicily and the oceanic Ionian Sea, i.e. the Malta escarpment.     

Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.