Experimental determination of argon solubility in silicate melts: An assessment of the effects of liquid composition and temperature

The argon solubility of 38 liquids in the system Na₂O-CaO-MgO-Al₂O₃-SiO₂ (NCMAS) has been determined at 1873 K and 1 bar, the argon concentration of presaturated glasses being measured using a static mass spectrometer. For compositions in the subsystem diopside (CaMgSi₂O₆), nepheline (NaAlSiO₄), albite (NaAlSi₃O₈), anorthite (CaAl₂Si₂O₈), argon solubility is generally a linear function of the relative proportion of each end member, solubility being lowest in diopside melt (1.53 10⁻⁵ cm³ STP · g⁻¹ · bar⁻¹) and highest in albite melt (2.88 10⁻⁴ cm³ STP · g⁻¹ · bar⁻¹). For the tectosilicate joins studied (SiO₂-Na₂Al₂O₄, SiO₂-CaAl₂O₄, SiO₂-MgAl₂O₄) solubility decreases with decreasing silica content in all cases, being highest for Na-bearing liquids and lowest for Mg-bearing liquids at constant molar silica content. Where comparison is possible our results are in good agreement with data from the literature. When our data are considered in isolation we find that argon solubility shows an excellent correlation with calculated ionic porosity. The covariation of argon solubility and liquid density is also reasonable, that with molar volume less convincing and that with polymerization state (as defined by the ratio of the number of nonbridging oxygens and tetrahedral network forming cations; NBO/T) nonexistent. However, when our data are combined with those from the literature no well constrained correlation between argon solubility and ionic porosity is apparent. Based upon this observation and consideration of the temperature dependence of noble gas solubility it is concluded that ionic porosity is not a universally applicable parameter which may be used to predict noble gas solubility as a function of composition, temperature and pressure. Two new models for calculating argon solubility are proposed, both employing the notion of partial molar argon solubilities. The first uses oxide components, for which partial molar argon solubility is directly proportional to partial molar ionic porosity calculated at 1873 K, irrespective of the temperature of experimental equilibration. The second model, which offers the best fit to the available data, employs tetrahedral units rather than oxides as the proposed melt components. This latter model successfully accounts for reported argon solubilities in simple Al-free systems, in simple Al-bearing systems and in natural liquids. This is interpreted to infer that argon is incorporated in large sites in the liquid structure (such as the space within rings of n-tetrahedra) although further work is required to understand the quantitative links between melt structure and noble gas solubility.     

The impact of shade on establishment of shrubs adapted to the high light irradiation of semi-arid environments

Light may be an important limiting resource that influences community structure of chenopod shrublands. As part of a larger study that aimed to determine the factors that influence chenopod community structure, the focus of this study was the influence of plant canopy on the growth and establishment of smaller plants. We therefore measured the height and cover of three chenopods (Enchylaena tomentosa, Maireana brevifolia and Maireana georgei) when growing within and outside of the canopy of Atriplex bunburyana under field conditions. All three chenopods had lower cover and E. tomentosa was taller when growing within the canopy of A. bunburyana in comparison to those growing outside of the canopy. The chenopods were then grown under three artificial shade regimes. Plant height, cover, biomass, relative leaf area and photosynthetic surface area measurements showed that each species responded differently to shade. E. tomentosa biomass was facilitated by shade. This was inferred by an increase in total plant biomass. M. brevifolia, in contrast, tolerated shade by increasing above-ground biomass allocation. M. georgei was adversely affected by the shade regimes: root biomass decreased in response to shade. Competition for light is, therefore, likely to influence chenopod community structure of semi-arid and arid environments.     

Yucatán karst features and the size of Chicxulub crater

The buried Chicxulub impact structure is marked by a dramatic ring of sinkholes (called cenotes if containing water), and adjacent less prominent partial rings, which have been shown to coincide with maxima in horizontal gravity gradients and a topographic depression. These observations, along with the discreteness and spacing of the features, suggest a formation mechanism involving faulting in the outer slump zone of the crater, which would thus have a diameter of approximately 180 km.
An opposing view, based primarily on the interpretation of gravity data, is that (he crater is much larger than the cenote ring implies. Given the association of the known cenote ring with faults, we here examine northern Yucatan for similar rings in gravity, surface features and elevation, which we might expect to be associated with outer concentric faults in the case of a larger, possibly multiring, structure.
No such outer rings have been found, although definite patterns are seen in the distribution of karst features outside the crater rim. We explain these patterns as resulting mainly from deformation related to the block fault zone that parallels tbe shelf edge of eastern Yucatan.     

Basic equations for constructing geopotential models from the gravitational potential derivatives of the first and second orders in the terrestrial reference frame

This research represents a continuation of the investigation carried out in the paper of Petrovskaya and Vershkov (J Geod 84(3):165–178, 2010) where conventional spherical harmonic series are constructed for arbitrary order derivatives of the Earth gravitational potential in the terrestrial reference frame. The problem of converting the potential derivatives of the first and second orders into geopotential models is studied. Two kinds of basic equations for solving this problem are derived. The equations of the first kind represent new non-singular non-orthogonal series for the geopotential derivatives, which are constructed by means of transforming the intermediate expressions for these derivatives from the above-mentioned paper. In contrast to the spherical harmonic expansions, these alternative series directly depend on the geopotential coefficients ${\bar{{C}}_{n,m}}$ and ${\bar{{S}}_{n,m}}$ . Each term of the series for the first-order derivatives is represented by a sum of these coefficients, which are multiplied by linear combinations of at most two spherical harmonics. For the second-order derivatives, the geopotential coefficients are multiplied by linear combinations of at most three spherical harmonics. As compared to existing non-singular expressions for the geopotential derivatives, the new expressions have a more simple structure. They depend only on the conventional spherical harmonics and do not depend on the first- and second-order derivatives of the associated Legendre functions. The basic equations of the second kind are inferred from the linear equations, constructed in the cited paper, which express the coefficients of the spherical harmonic series for the first- and second-order derivatives in terms of the geopotential coefficients. These equations are converted into recurrent relations from which the coefficients ${\bar{{C}}_{n,m}}$ and ${\bar{{S}}_{n,m}}$ are determined on the basis of the spherical harmonic coefficients of each derivative. The latter coefficients can be estimated from the values of the geopotential derivatives by the quadrature formulas or the least-squares approach. The new expressions of two kinds can be applied for spherical harmonic synthesis and analysis. In particular, they might be incorporated in geopotential modeling on the basis of the orbit data from the CHAMP, GRACE and GOCE missions, and the gradiometry data from the GOCE mission.     

Super earth explorer: a coronagraphic off-axis space telescope

The Super-Earth Explorer is an Off-Axis Space Telescope (SEE-COAST) designed for high contrast imaging. Its scientific objective is to make the physico-chemical characterization of exoplanets possibly down to 2 Earth radii. For that purpose it will analyze the spectral and polarimetric properties of the parent starlight reflected by the planets, in the wavelength range 400–1,250 nm.     

A simple strategy for dynamic substructuring: I. Concept and development

Dynamic substructuring refers to physical testing with computational models in the loop. This paper presents a new strategy for such testing. The key feature of this strategy is that it decouples the substructuring controller from the physical subsystem. Unlike conventional approaches, it does not explicitly include a tracking controller. Consequently, the design and implementation of the substructuring controls are greatly simplified. This paper motivates the strategy and discusses the main concept along with details of the substructuring control design. The focus is on configurations that use shake tables and active mass drivers. An extensive experimental assessment of the new strategy is presented in a companion paper, where the influence of various factors such as virtual subsystem dynamics, control gains, and nonlinearities is investigated, and it is shown that robustly stable and accurate substructuring is achieved.     

Venusian novae (Astra): Classification and associations to different geological environments

On the Venusian surface, there can be found a rather large population of structures with prominent radial features. The term “nova” or “astrum/astra” are used to describe this special group of volcanotectonic structures with a stellate fracture pattern radiating around a central summit or fracture. In this paper, we studied the distribution and characteristics of 74 novae to determine if there are suitable ways to categorize them and to find out how this categorization could explain the differences in nova characteristics. The nova locations establish that these structures are not distributed sporadically, but they display both latitudinal and longitudinal concentrations. In addition, it is evident that the geological environments represent the major differences between individual novae. Most of them, in general, are connected to some larger volcanotectonic unit. The differences in geological surroundings can be used as the basis for characterizing novae by dividing them into different categories: (a) novae located either within or close to a rather large deformation zone, (b) novae located on plains, (c) novae located close to tessera terrain, and (d) novae situated within volcanic areas either close to volcanoes or within an area with a high density of coronae. The analysis of this characterization establishes that geological environments are the main cause for divergent nova characteristics, i.e., differences in morphology, volcanism, and topography, which, on the other hand, are possible ways to classify novae. In particular, the morphological classification (Type I, novae with features radiating from the same point; Type II, radial structures radiating from a fissure or other linear structure; Type III, lava flows or fields covering radiant point area; Type IV, semiradial structures which do not radiate from a well-defined radiant point, fissure, or area) shows some correlations between geological environments and the type of nova, indicating that the morphological appearance and the location—and, thereby, the geologic environment—of the novae are correlated to some extent.     

Artificial Maturation of Organic Matter from Recent Venezuelan Sediments

Laboratory simulation of the catagenesis of organic matter in sedimentary rocks has been used to provide an understanding of the processes involved in petroleum generation. Several of these studies have focused on the thermal evolution of organic matter (OM) present in Recent sediments. This study examines the geochemical characteristics and experimental thermal evolution of primary organic matter from two organic facies that are thought to be major contributors to Venezuelan hydrocarbon source rocks. A third facies, generally considered unimportant for petroleum formation, is used to contrast the experimental results. Hydrous pyrolysis maturation experiments were performed for three intermediate temperatures. The products of the final 330°C stage are shown in this paper because they best illustrate the changes in the OM during catagenesis. Results from the hydrous pyrolysis experiments show that at 280°C and higher all three samples yield liquid hydrocarbons similar in composition to natural crudes and the transformed organic matter is similar to kerogen that occurs in natural source rocks. Chromatograms from the saturated fraction of extracts at 330°C are similar to natural crudes with respect to n-alkane distribution and abundance of beta; and beta;alpha; hopanes. The only difference seems to be the relative abundance of 22R over 22S isomers, which indicates immature oil. This is in contrast to indications from the R _o and T _max parameters measured on the accompanying kerogen.     

Effect of polychromatic X‐ray microtomography imaging on the amino acid content of the Murchison CM chondrite

X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.     

GMOS spectroscopy of the S0 galaxy NGC 3115

We present Gemini Multi-Object Spectrograph longslit spectroscopy of the isolated S0 galaxy NGC 3115. We have determined kinematical data and Lick/IDS absorption line-strength indices for the major axis out to around 9 kpc and for the minor axis out to around 5 kpc (around 2R _e ). Using stellar population models which include the effects of variable [α/Fe] ratios, we derive metallicities, abundance ratios and ages for the stellar population of NGC 3115. We find that [α/Fe] remains fairly constant with increasing radius at around  [α/Fe]= 0.17  for the major axis but increases rapidly for the minor axis to around  [α/Fe]= 0.3  . We also find that to first order, this behaviour can be explained by a simple spheroid + disc model, where the spheroid has  [α/Fe]= 0.3  and the disc shows close to solar abundance ratios. The disc also appears considerably younger than the spheroid, having an age of around 6 Gyr compared to 12 Gyr for the spheroid. We compare these results to those previously presented for the globular cluster system of NGC 3115.