Ground water recharge and flow characterization using multiple isotopes

Stable isotopes of delta(18)O, delta(2)H, and (13)C, radiogenic isotopes of (14)C and (3)H, and ground water chemical compositions were used to distinguish ground water, recharge areas, and possible recharge processes in an arid zone, fault-bounded alluvial aquifer. Recharge mainly occurs through exposed stream channel beds as opposed to subsurface inflow along mountain fronts. This recharge distribution pattern may also occur in other fault-bounded aquifers, with important implications for conceptualization of ground water flow systems, development of ground water models, and ground water resource management. Ground water along the mountain front near the basin margins contains low delta(18)O, (14)C (percent modern carbon [pmC]), and (3)H (tritium units [TU]), suggesting older recharge. In addition, water levels lie at greater depths, and basin-bounding faults that locally act as a flow barrier may further reduce subsurface inflow into the aquifer along the mountain front. Chemical differences in ground water composition, attributed to varying aquifer mineralogy and recharge processes, further discriminate the basin-margin and the basin-center water. Direct recharge through the indurated sandstones and mudstones in the basin center is minimal. Modern recharge in the aquifer is mainly through the broad, exposed stream channel beds containing coarse sand and gravel where ground water contains higher delta(18)O, (14)C (pmC), and (3)H (TU). Spatial differences in delta(18)O, (14)C (pmC), and (3)H (TU) and occurrences of extensive mudstones in the basin center suggest sluggish ground water movement, including local compartmentalization of the flow system.     

Pushover analysis of reinforced concrete frames considering shear failure at beam-column joints

Since most current seismic capacity evaluations of reinforced concrete(RC) frame structures are implemented by either static pushover analysis(PA) or dynamic time history analysis,with diverse settings of the plastic hinges(PHs) on such main structural components as columns,beams and walls,the complex behavior of shear failure at beam-column joints(BCJs) during major earthquakes is commonly neglected.This study proposes new nonlinear PA procedures that consider shear failure at BCJs and seek to assess the actual damage to RC structures.Based on the specifications of FEMA-356,a simplified joint model composed of two nonlinear cross struts placed diagonally over the location of the plastic hinge is established,allowing a sophisticated PA to be performed.To verify the validity of this method,the analytical results for the capacity curves and the failure mechanism derived from three different full-size RC frames are compared with the experimental measurements.By considering shear failure at BCJs,the proposed nonlinear analytical procedures can be used to estimate the structural behavior of RC frames,including seismic capacity and the progressive failure sequence of joints,in a precise and effective manner.     

蒙古中南部地区面波相速度层析成像

本文采用小波变换频时分析技术提取了1893条蒙古中南部地区双台间基阶Rayleigh波相速度频散曲线,通过对提取到的相速度频散进行二维反演,首次重构了蒙古高原中南部10~80 s周期内分辨率为0.5°×0.5°的相速度分布图.结果表明,短周期相速度频散(10~20 s)明显受地表地形控制,表现为杭爱—肯特山盆地为相对高速异常,而南部的戈壁带表现为相对低速异常;在30 s到60 s周期内,南部的戈壁带和北部的杭爱—肯特山盆地都显示出稳定的高速异常,而中部戈壁带则表现为低速异常.该低速异常区与新生代火山岩出露位置的一致性,暗示该低速异常可能与新生代火山活动有关.穿过蒙古高原中部的两条主要断裂带与研究区内的地震波速度分布具有很好的一致性,可能暗示两条断裂带一直延伸到整个岩石圈.此外,蒙古中南部地区的壳幔速度低于全球平均大陆值,且其相速度频散曲线与遭受破坏的克拉通,尤其大陆裂谷很相似,可能暗示着研究区具有薄的、活跃的岩石圈构造.     

Evaluation of the contamination of platinum in estuarine and coastal sediments (Tagus Estuary and Prodelta, Portugal)

Platinum contamination in estuarine and coastal sediments has been evaluated in three cores collected from the Tagus Estuary and Prodelta shelf sediments. Elevated concentrations, up to 25-fold enrichment compared to background values, were found in the upper layers of the estuarine sediments. The degree of Pt enrichment in the estuarine sediments varied depending on the proximity to vehicular traffic sources, with a maximum concentration of 9.5 ng g⁻¹. A considerable decrease of Pt concentrations with depth indicated the absence of significant contamination before the introduction of catalytic converters in automobiles. Platinum distribution in the Tagus Prodelta shelf sediment core showed no surface enrichment; instead a sub-surface maximum at the base of the mixed layer suggested the possibility of post-depositional mobility, thereby blurring the traffic-borne contamination signature in coastal sediments.     

Wetland conservation and sustainable coastal governance in Japan and England

Coastal wetlands present particular challenges for coastal governance and for the implementation of the Ramsar Convention, not least because coastal areas are focal points of human activity and of governance ambiguity. Through the evaluation of Ramsar delivery at both national and local levels in Japan and England, the relationship between Ramsar implementation and coastal governance was examined. In England, Ramsar status is primarily treated as a nature conservation designation which limits the wider opportunities inherent in the designation. In contrast, in Japan, the Ramsar Convention is used as a policy driver at the national level and as a leverage to encourage citizen engagement, economic benefit, and wetland conservation at the local level. It was concluded that through the implementation of the Ramsar Convention in important coastal wetland areas, significant steps can be taken towards delivering integrated approaches to coastal governance.     

Validation of Arenicola marina in field toxicity bioassays using benthic cages: biomarkers as tools for assessing sediment quality

Sediment toxicity assessments using caged organisms present advantages over using laboratory and native community studies. The use of caged Arenicola marina in sediment toxicity assessments was evaluated. Lugworms were exposed in situ to sediments from coastal and port areas in Spain for seven days, and the activities of the biotransformation enzymes ethoxyresorufin O-deethylase, dibenzylfluorescein dealkylase and glutathione S-transferase, the activities of the antioxidant enzymes glutathione reductase and glutathione peroxidase and lipid peroxidation were then analyzed as biomarkers. Biomarker results and sediment physicochemical data were integrated. Cádiz Bay (SW Spain) sediments presented metal contamination that was not linked to a biochemical response. In LPGC Port (SW Spain), Pb contamination exhibited a moderate toxic potential, while PAHs, and presumably pharmaceuticals, provoked biochemical responses that efficiently prevented lipid peroxidation. In Santander Bay (N Spain), exposure to PAHs and, presumably, pharmaceuticals induced biomarker responses, but lipid peroxidation occurred nevertheless. These results indicated that caged A. marina were effective for the assessment of sediment quality and that the selected biomarkers were sufficiently sensitive to identify chemical exposure and toxicity.     

Cytochrome P450 1A1 expression in cetacean skin biopsies from the Indian Ocean

The study describes cytochrome P450 1A1 (CYPA1) expression in the skin of different cetacean species (Megaptera novaeangliae, n = 15; Stenella attenuata, n = 7 and Stenella longirostris, n = 24) from the Mozambique Channel island of Mayotte. Immunohistochemical examination was performed with a monoclonal antibody against scup cytochrome CYPA1. The sex was determined using a molecular approach consisting in the genotyping sex-specific genes. CYPA1 was detected at the junction between epidermis and blubber on dolphins only, mostly in the endothelial cells. Similar observation was obtained in the dermis of one M. novaeangliae. Immunohistochemical slides were scored to evaluate the expression of the CYPA1 and a higher expression was observed in S. longirostris, suggesting a higher exposure to pollutants for this species. The difference of expression between sexes was not significant.     

Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea)

After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure.     

Occurrence and accumulation features of polycyclic aromatic hydrocarbons and synthetic musk compounds in finless porpoises (Neophocaena phocaenoides) from Korean coastal waters

Reports of the occurrence and accumulation patterns of polycyclic aromatic hydrocarbons (PAHs) and synthetic musk compounds (SMCs) in marine mammals are scarce. In this study, the concentrations and accumulation profiles of PAHs and SMCs were determined in blubber from finless porpoises in Korean coastal waters. Total concentrations of PAHs and SMCs ranged from 6.0 to 432 (mean: 160) ng/g lipid weight and from 17 to 144 (mean: 52) ng/g lipid weight, respectively. Residue levels of PAHs were lower than those reported from other studies, while residue levels of SMCs were relatively higher than those reported in other studies. Naphthalene was the most abundant PAH and HHCB was the dominant SMC observed in finless porpoises. The concentrations of PAHs and SMCs were not correlated with each other, but were significantly correlated within the same chemical groups. No correlations were found between body size and residue levels of PAHs and SMCs.