Os Isotopes and the Origin of the Tasmanian Dolerites

New Os isotope data obtained for oxides separated from samplesof the Jurassic dolerites of Tasmania (Australia) are used toconstrain the petrogenesis of the Ferrar continental flood basaltprovince. It is proposed here that the unradiogenic initialOs ratio (¹⁸⁷Os/¹⁸⁸Os = 0·145 ± 0·049 2     

Environmental impact of salmon net-pen culture on marine benthic communities in Maine: A case study

The environmental impacts of salmon net-pen aquaculture on the benthic environment were investigated at a commercial fish farm located in coastal Maine waters. This site has a sandy mud bottom and low current velocities, is subjected to episodic sediment resuspension, and way in production for 3 yr prior to this study: We examined both the increase in carbon flux to the benthos caused by the net-pen and the effects of the elevated flux on sediment biogeochemistry and the microbenthic communities. The experimental design involved the establishment of two study sites, an ambient site ca. 100 m from the net-pen and a treatment site around the pen. Sediment traps deployed 1 m above the sediment-water interface indicated that carbon flux to the benthos was increased 1-fold to 6-fold (to a maximum of 5 g m^?2d^?1) at the edge of the net-pen with little or no increase in carbon flux 10 m from the pen. Unlike carbon flux rates, sediment organic matter inventories showed a complex pattern of change over time. Mineral surface area, organic carbon and nitrogen, digestible protein, and sterol content were initially (April 1991) lower beneath the pen than in ambient sediments. During 1991 ambient sediment accumulated organic matter until July after which it decreased, to a low during November. In contrast, organic matter inventories of sediment beneath the pen remained low until July and then increased to a high during November. These latter gains were associated with the development of bacterial mats at the sediment-water interface. Beneath the pen, microbial and macrofaunal communities were shifted toward those commonly associated with organic enrichment but seasonal trends and storm-related resuspension events also significantly affected these sediment communities. When abundant, most epibenthic organisms were more numerous near the pen than in adjacent ambient areas. These results suggest that net-pen aquaculture can alter the benthic ecosystem in Maine Coastal waters but indicate that the effects are spatially limited.     

Cadmium absorption and accumulation in different parts of kidney beans, radishes and pumpkins

This study is done to measure the absorption and distribution of cadmium in different parts of kidney beans, radishes and pumpkins. Three parts of a field was chosen. In one part 65 ppm of cadmium nitrate was added to water and in the other part 130 ppm, the last part was irrigated with normal water. Samples were digested by EPA 3050 method. Cadmium concentration was measured by Unicam 919 absorption unit. Beans accumulate cadmium mostly in root (70 ppm) and a little amount is mobilized through upper parts (12–16ppm), but kidneys did not accumulate a significant amount. In radishes the roots did not accumulate a significant amount of cadmium but stems had 4 ppm and leaves had 25 ppm. Cadmium concentration in soil does not affect its concentration in different parts of pumpkins and beside the stems and leaves (4 ppm) the other parts' concentrations were insignificant. In regard to the results of this study the cadmium concentrations in edible parts of the samples (kidney beans, radish roots and pumpkin fruit) were less than the U.S. EPA standards for agriculture and human beings.     

Rb-Sr whole-rock dating of late diagenetic to anchimetamorphic,palaeozoic sediments in southern France (Montagne Noire)

Rb-Sr whole-rock and mineral analyses are reported from Early Paleozoic sediments of the southern rim of the French Central Massif (Montagne Noire). The sediments—mainly pelites, silt- and sandstones—can be separated into three different zones (A, B, and C) according to their varying degrees of deformation and transformation, which took place during the Hercynian (= Variscan) orogeny (Carboniferous). For the least deformed, folded but not schistose, fossiliferous Lower Ordovician sediments (zone A), a scatter of the data points resulted, at least partly due to the varying amount of detrital muscovites, which did not equilibrate their Sr isotopes with those of the clay minerals. Fossiliferous Middle Cambrian sediments (zone B), however, are colinear in an isochron plot. The rocks are also folded, and show a beginning schistosity in the pelitic layers. The age of 333±16 m.y. therefore does not correspond to the time of sedimentation, as one would expect from most of the interpretations given in the literature. It is, however, in close agreement with the stratigraphically known time of folding and anchimetamorphism. The same result, within analytical error, of 326±17 m.y. was obtained for Lower Ordovician sediments (zone C), which show a schistosity not only in the pelites but also in some psammitic layers. As for the sediments of zone B, this result indicates open whole-rock systems for Rb and/or Sr during folding and anchimetamorphism. Minerals extracted from psammites of zones B and C gave the following results: albite coincides with the isochrons; detrital muscovites do not coincide and yield ages of about 650 m.y. (Cadomian orogeny) for both zone B and C sediments; detrital chlorites from zone B sediments seem to be only partly reset by anchimetamorphism and therefore plot closer to the whole-rock isochron. From this it must be concluded that an increasing amount of these detrital micas could significantly shift the position of the total-rock points, as might be the case for zone A sediments. From the whole-rock results of zone B and C sediments and the mineralogical and petrological changes during diagenesis and anchimetamorphism we conclude that many of the isochrons obtained from stratigraphically uncontrollable Precambrian sediments should be reinterpreted in favour of metamorphic and not sedimentary ages, especially if the metamorphism reached greenschist facies conditions. Devonian and Cambrian limestones intercalated between the pelites, silstones and sandstones contain Sr of a variable and slightly radiogenic isotopic composition in contrast to the expected ancient sea water Sr. This fact is interpreted again in favour of open whole-rock systems during the postdepositional history of the rock, rather than primary scatter of ancient, radiogenic sea water Sr.     

Winter severity in Europe: The fourteenth century

The fourteenth century is known to include a period of winter cooling in Central and Western Europe, but its timing and magnitude are not clearly established. An attempt to obtain a coherent picture from verified documentary evidence yielded 2133 records from a region covering Central Europe and Northern Italy, mostly originating from the Monumenta Germaniae Historica. Temperatures were assessed using semi-quantitative indices on the basis of proxy information on snow-cover, ice and untimely activity of vegetation. Results: A run of cold winters from 1303 to 1328 was followed by a run of average winters up to 1354. Then winter temperatures were extremely variable up to 1375. For the rest of the century they fluctuated somewhat below the average of the twentieth century. The pattern in the first five decades is compared to that in the Late Maunder Minimum (1675–1715). The possible role of forcing factors (variations in solar output, North Atlantic Deep Water formation) is briefly discussed.     

Contemporary 14C radiocarbon levels of oxygenated polybrominated diphenyl ethers (O-PBDEs) isolated in sponge-cyanobacteria associations

Considerable debate surrounds the sources of oxygenated polybrominated diphenyl ethers (O-PBDEs) in wildlife as to whether they are naturally produced or result from anthropogenic industrial activities. Natural radiocarbon (¹⁴C) abundance has proven to be a powerful tool to address this problem as recently biosynthesized compounds contain contemporary (i.e. modern) amounts of atmospheric radiocarbon; whereas industrial chemicals, mostly produced from fossil fuels, contain no detectable ¹⁴C. However, few compounds isolated from organisms have been analyzed for their radiocarbon content. To provide a baseline, we analyzed the ¹⁴C content of four O-PBDEs. These compounds, 6-OH-BDE47, 2′-OH-BDE68, 2′,6-diOH-BDE159, and a recently identified compound, 2′-MeO-6-OH-BDE120, were isolated from the tropical marine sponges Dysidea granulosa and Lendenfeldia dendyi. The modern radiocarbon content of their chemical structures (i.e. diphenyl ethers, C₁₂H₂₂O) indicates that they are naturally produced. This adds to a growing baseline on, at least, the sources of these unusual compounds.     

Using low-density discrete Airborne Laser Scanning data to assess the potential carbon dioxide emission in case of a fire event in a Mediterranean pine forest

The aim of study is to map the carbon dioxide (CO₂) emission of the aboveground tree biomass (AGB) in case of a fire event. The suitability of low point density, discrete, multiple-return, Airborne Laser Scanning (ALS) data and the influence of several characteristics of these data and the study area on the results obtained have been evaluated. A sample of 45 circular plots representative of Pinus halepensis Miller stands were used to fit and validate the model of AGB. The ALS point clouds were processed to obtain the independent variables and a multivariate linear regression analysis between field data and ALS-derived variables allowed estimation of AGB. Then, the influence of several characteristics on the residuals of the model was analyzed. Finally, conversion factors were applied to obtain the CO₂ values. The AGB model presented a R² value of 0.84 with a relative root-mean-square error of 27.35%. This model included ALS variables related to vegetation height variability and to canopy density. Terrain slope, aspect, canopy cover, scan angle and the number of laser returns did not influence AGB estimations at plot level.     

A procedure for identifying significant environmental aspects in sea ports

A new methodology has been designed to identify and rank the significant environmental aspects in sea ports. The main objective of the Strategic Overview of Significant Environmental Aspects (SOSEA) is to help port managers to identify significant environmental aspects and to reinforce the awareness about them in order to prioritise work in environmental management. Developed in close collaboration with port environmental managers and tested in a set of ports, it is a user-friendly tool that can be applied in approximately half a working day. It is based on ISO 14001 vocabulary and requirements and it can be considered as the base for the implementation of any Environmental Management System for port communities.     

230Th-238U radioactive disequilibria in tholeiites from the FAMOUS zone (Mid-Atlantic Ridge, 36°50′N): Th and Sr isotopic geochemistry

We analyzed, U, Th and²³⁰Th/²³²Th activity ratios for a few tholeiites from the Mid-Atlantic Ridge FAMOUS zone at 36°50′N. The results show a fairly wide scatter for both Th/U and (²³⁰Th/²³²Th) ratios. Seawater contamination appears to be responsible for this scatter and, for the uranium, produces an increase in content yielding a (²³⁴U/²³⁸U) ratio greater than 1 and, for the Th, an increase of the (²³⁰Th/²³²Th) ratio which is a very sensitive indicator for contamination. Also, the latter often is selective: U, Th and Sr are not affected in the same manner.When discarding all data for contaminated samples, the FAMOUS zone appears to be very homogeneous with aTh/U ratio value of 3.05 and a (²³⁰Th/²³²Th) ratio value of 1.24. Comparison with other active volcanic areas reveals a negative correlation between (²³⁰Th/²³²Th) and⁸⁷Sr/⁸⁶Sr ratios for present lavas which is indicative of a consistency in Th-U and Rb-Sr fractionation in the source regions of these magmas. The Th isotopic geochemistry can thus provide useful information for the study of present volcanism, information as valuable as that from Sr, Pb or Nd isotopes.