Carbon isotope systematics of individual hydrocarbons in hydrothermal petroleum from Escanaba Trough, northeastern Pacific Ocean

We submitted individual aliphatic and polycyclic aromatic hydrocarbons in samples of hydrothermal petroleum from Escanaba Trough to compound specific isotope analysis to trace their origins. The carbon isotope compositions of the alkanes and polycyclic aromatic hydrocarbons (means -27.5 and -24.7%, respectively) reflect a primarily terrestrial organic matter source.     

Uncertainties in field-line tracing in the magnetosphere. Part II: the complete internal geomagnetic field

The discussion in the preceding paper is restricted to the uncertainties in magnetic-field-iine tracing in the magnetosphere resulting from published standard errors in the spherical harmonic coefficients that define the axisymmetric part of the internal geomagnetic field (i.e. g_n⁰ ± g_n⁰). Numerical estimates of these uncertainties based on an analytic equation for axisymmetric field lines are in excellent agreement with independent computational estimates based on stepwise numerical integration along magnetic field lines. This comparison confirms the accuracy of the computer program used in the present paper to estimate the uncertainties in magnetic-field-line tracing that arise from published standard errors in the full set of spherical harmonic coefficients, which define the complete (non-axisymmetric) internal geomagnetic field (i.e. g_n^m ± g_n^m and h_n^m ± h_n^m). An algorithm is formulated that greatly reduces the computing time required to estimate these uncertainties in magnetic-field-line tracing. The validity of this algorithm is checked numerically for both the axisymmetric part of the internal geomagnetic field in the general case (1 n 10) and the complete internal geomagnetic field in a restrictive case (0 m n, 1 n 3). On this basis it is assumed that the algorithm can be used with confidence in those cases for which the computing time would otherwise be prohibitively long. For the complete internal geomagnetic field, the maximum characteristic uncertainty in the geocentric distance of a field line that crosses the geomagnetic equator at a nominal dipolar distance of 2 R_E is typically 100 km. The corresponding characteristic uncertainty for a field line that crosses the geomagnetic equator at a nominal dipolar distance of 6 R_E is typically 500 km. Histograms and scatter plots showing the characteristic uncertainties associated with magnetic-field-line tracing in the magnetosphere are presented for a range of illustrative examples. Finally, estimates are given for the maximum uncertainties in the locations of the conjugate points of selected geophysical observatories. Numerical estimates of the uncertainties in magnetic-field-line tracing in the magnetosphere, including the associated uncertainties in thelocations of the conjugate points of geophysical observatories, should be regarded as first approximations in the sense that these estimates are only as accurate as the published standard errors in the full set of spherical harmomic coefficients. As in the preceding paper, howerver, all computational techniques developed in this paper can be used to derive more realistic estimates of the uncertainties in magnetic-field-line tracing in the magnetosphere, following further progress in the determination of more accurate standard errors in the spherical harmonic coefficients.Also Visiting Reader in Physics, University of Sussex, Palmer, Brighton, BN1 9QH, UK     

Non-spherical source-surface model of the heliosphere: a scalar formulation

The source-surface method offers an alternative to full MHD simulation of the heliosphere. It entails specification of a surface from which the solar wind flows normally outward along straight lines. Compatibility with MHD results requires this (source) surface to be non-spherical in general and prolate (aligned with the solar dipole axis) in prototypical axisymmetric cases. Mid-latitude features on the source surface thus map to significantly lower latitudes in the heliosphere. The model is usually implemented by deriving the B field (in the region surrounded by the source surface) from a scalar potential formally expanded in spherical harmonics, with coefficients chosen so as to minimize the mean-square tangential component of B over this surface. In the simplified (scalar) version the quantity minimized is instead the variance of the scalar potential over the source surface. The scalar formulation greatly reduces the time required to compute required matrix elements, while imposing essentially the same physical boundary condition as the vector formulation (viz., that the coronal magnetic field be, as nearly as possible, normal to the source surface for continuity with the heliosphere). The source surface proposed for actual application is a surface of constant , where r is the heliocentric distance and B is the scalar magnitude of the B field produced by currents inside the Sun. Comparison with MHD simulations suggests that k 1.4 is a good choice for the adjustable exponent. This value has been shown to map the neutral line on the source surface during Carrington Rotation 1869 (May–June 1993) to a range of latitudes that would have just grazed the position of Ulysses during that month in which sector structure disappeared from Ulysses magnetometer observations.     

Internal migration patterns for U.S. foreign-born, 1985-1990

"Using 1990 census data, this paper calculates the flow [of the foreign-born population in the United States] between states and from abroad; also, a multinomial logistic regression model of destination choice is estimated for resettlers and for migrants from abroad. There are three major findings. Firstly, Florida and California are the largest recipients of foreign-born resettlers; New York is the biggest loser of secondary migrants. Secondly, the presence of large communities of Mexicans in California and Cubans in Florida are very attractive to both resettlers and migrants from abroad. Thirdly, immigrants that are most in need of ethnic support networks (i.e. new arrivals or immigrants with low human capital resources) are most likely to choose one of the traditional immigration states as a destination."     

Biomass burning in the tropical savannas of Ivory Coast: An overview of the field experiment Fire of Savannas (FOS/DECAFE 91)

FOS/DECAFE 91 (Fire of Savannas/Dynamique et Chimie Atmosphérique en Forêt Equatoriale) was the first multidisciplinary experiment organized in Africa to determine gas and aerosol emissions by prescribed savanna fires. The humid savanna of Lamto in Ivory Coast was chosen for its ecological characteristics representative of savannas with a high biomass density (900 g m^–2 dry matter). Moreover the vegetation and the climate of Lamto have been studied for more than twenty years. The emission ratios (X/CO₂) of the carbon compounds (CO₂, CO, NMHC, CH₄, PAH, organic acids and aerosols), nitrogen compounds (NO_x, N₂O, NH₃ and soluble aerosols) and sulfur compounds (SO₂, COS and aerosols) were experimentally determined by ground and aircraft measurements. To perform this experiment, 4 small plots (100×100 m) and 2 large areas (10×10 km) were prepared and burnt in January 1991 during the period of maximum occurrence of fires in this type of savanna. The detailed ecological study shows that the carbon content of the vegetation is constant within 1% (42 g C for 100 g of vegetal dry matter), the nitrogen content (0.29 g N for 100 g of dry matter) may vary by 10% and the sulfur content (0.05 g S/100 d.m.) by 20%. These variations of the biomass chemical content do not constitute an important factor in the variation of the gas and particle emission levels. With the emission ratios characteristic of humid savanna and flaming conditions (CO/CO₂ of 6.1% at the ground and 8% for airborne measurements), we propose a set of new emission factors, taking into account the burning efficiency which is about 80%: 74.4% of the carbon content of the savanna biomass is released to the atmosphere in the form of CO₂, 4.6% as CO, 0.2% as CH₄, 0.5% as NMHC and 0.7% as aerosols. 17.2% of the nitrogen content of the biomass is released as NO_x, 3.5% as N₂O, 0.6% as NH₃ and 0.5% as soluble aerosols.     

On the bogussing of tropical cyclones in numerical models: A comparison of vortex profiles

Summary At the resolutions currently in use, and with the sparse oceanic data coverage, numerical analyses cannot adequately represent tropical cyclone circulations for use in numerical weather prediction models. In many cases there is no circulation present at all. Most numerical weather prediction centers therefore employ a bogussing scheme to force a tropical cyclone vortex into the numerical analysis. The standard procedure is to define a synthetic data distribution based on an analytically prescribed vortex, which is passed to the analysis scheme as a set of high quality observations.In this study, four commonly used bogus vortices are examined by comparing resultant forecast tracks in an environment at rest, and in a background flow that simulates a typical monsoon trough-subtropical ridge structure. There are three main findings, each of which has significance for operational tropical cyclone track prediction. First, great care is needed in the choice of the characteristics of the bogus vortex, such as the radius and magnitude of the maximum wind. Second, the tropical cyclone trajectories can be very sensitive to their initial position in the idealised environment. Third, the bogus vortex can substantially influence the environment, especially over longer time periods and for vortices of larger size.With 9 Figures     

Geology of the volcanic-hosted Brockman rare-metals deposit,Halls Creek Mobile Zone,northwest Australia. l. Volcanic environment,geochronology and petrography of the Brockman volcanics

Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.

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Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite

Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.

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Deceased     

Potential cauchy-poisson waves generated by submarine eruptions of kick 'em Jenny volcano

Kick 'em Jenny is the only known currently active submarine volcano in the Lesser Antilles. The volcano has erupted at least 10 times since first being discovered in 1939 and the summit has shoaled from a depth of 232 m in 1962 to its present-day depth of 150 m. Kick 'em Jenny is located in a province of explosive volcanism, has a known history of explosive eruptions and erupts magma of an explosive type. Future eruptions are likely to become increasingly more violent as the effect of the overlying water pressure becomes less. A preliminary study (Smith and Shepherd, 1993) suggests that Kick 'em Jenny is a prime candidate for tsunamigenic eruptions on a potentially hazardous scale, possibly affecting the whole of the eastern Caribbean region.The classic approach to problems of water waves generated by sudden disturbances of the free surface makes use of the Cauchy-Poisson-Lamb theory. A large number of theoretical developments to this theory have been made for specific forms of surface disturbance. A development by Unoki and Nakano (1953a, b) considers both two- and three-dimensional Cauchy-Poisson waves generated by finite initial elevations and impulses applied to a free surface of infinitely deep water. Unoki and Nakano's results compared well to the wave systems recorded following submarine eruptions of the Myojinsho Reef volcano in 1952–53.Given the similarity of the two situations, Unoki and Nakano's theory is applied to Kick 'em Jenny to provide estimates of potential Cauchy-Poisson wave heights throughout the eastern Caribbean for a range of eruption magnitudes. The results show that, although the waves generated are unlikely to pose much of a threat to the eastern Caribbean as a whole, they should be considered a hazard to the islands immediately adjacent to the volcano including Grenada, the Grenadines, and St Vincent.     

Lithological and Structural Controls on Regional 3-D Fluid Flow Patterns during Greenschist Facies Metamorphism of the Dalradian of the SW Scottish Highlands

Greenschist facies metabasite sills enclosed within phyllitesand psammites of the Dalradian Supergroup of the SW ScottishHighlands have been used as quantitative sensors of fluid flow,from which ‘fossil’ fluid flow-paths have been mapped.Infiltration of H₂O–CO₂ fluid caused carbonation of themetabasite assemblage. Consequently, metabasite sills have developeda characteristic asymmetric zonation of reacted (carbonate-bearing)margins and unreacted (carbonate-absent) interiors. Reactionfront advection theory has been used to constrain the time-integratedfluid flux and flow direction in one dimension, for each sill,from the widths of the reacted margins. Three-dimensional fluxesand flow directions have been constrained from one-dimensionalfluxes by geometrical computation, and regional fluid flow patternshave been deduced. On a regional scale, fluid flow was channelled through phyllitesand focused towards the axial zone of major antiformal foldstructures. Fluid flow was channelled through the 6 km thickArdrishaig Phyllites, within which fluid fluxes were found toincrease exponentially with proximity to the axial surface ofthe Ardrishaig Anticline. Fluid flow through the psammites waslimited to narrow zones of intense deformation associated withmetabasic or phyllitic intercalations. Although time-integratedfluid fluxes were locally high (4 10² m³/m²), average fluxes(100 m¹/m²) are compatible with availability of fluid from underlyingdevolatilizing rocks. Complete isotopic homogenization of phyllites,psammites and metabasites within the axial region of the ArdrishaigAnticline is predicted by these high measured fluxes. KEY WORDS: 3-D flow; Dalradian; SW Scotland; greenschist facies; metabasites ^*Corresponding author. Telephone: 0131-650-5885 Fax: 0131-668-3184 E-mail: askelton{at}glg.ed.ac.uk     

Reaction Textures in a Suite of Spinel Granulites from the Eastern Ghats Belt, India: Evidence for Polymetamorphism, a Partial Petrogenetic Grid in the System KFMASH and the Roles of ZnO and Fe2O3

Spinel granulites, with or without sapphirine, occur as lensesin garnetiferous quartzofeldspathic gneisses (leptynites) nearGokavaram in the Eastern Ghats Belt, India. Spinel granulitesare mineralogically heterogeneous and six mineral associationsoccur in closely spaced domains. These are (I) spinel–quartz–cordierite,(II) spinel–quartz–cordierite–garnet–orthopyroxene–sillimanite,(III) spinel–cordierite–orthopyroxene–sillimanite,(IV) spinel–quartz–sapphirine–sillimanite–garnet,(V) spinel–quartz-sapphirine–garnet and (IV) rhombohedral(Fe–Ti) oxide–cordierite–orthopyroxene–sillimanite.Common to all the associations are a porphyroblastic garnet(containing an internal schistosify defined by biotite, sillimaniteand quartz), perthite and plagioclase. Spinel contains variableamounts of exsolved magnetite and is distinctly Zn rich in thesapphirine-absent associations. X_Mg in the coexisting phasesdecreases in the order cordierite–biotite–sapphirine–orthopyroxene–spinel–garnet–(Fe–Ti)oxides. Textural criteria and compositional characteristicsof the phases document several retrograde mineral reactionswhich occurred subsequent to prograde dehydration melting reactionsinvolving biotite, sillimanite, quartz, plagioclase and spinel.The following retrograde mineral reactions are deduced: (1)spinel + quartz cordierite, (2) spinel + quartz garnet + sillimanite,(3) garnet + quartz cordierite + orthopyroxene, (4) garnet+ quartz + sillimanite cordierite, (5) spinel + cordierite orthopyroxene + sillimanite, (6) spinel + sillimanite + quartz sapphirine, (7) spinel + sapphirine + quartz garnet + sillimanite,and (8) spinel + quartz sapphirine + garnet. A partial petrogeneticgrid for the system FeO–MgO–Al₂O₃–SiO₂–K₂O–H₂Oat high fo₂, has been constructed and the effects of ZnO andFe₂O₃ on this grid have been explored Combining available experimentaland natural occurrence data, the high fo₂ invariant points inthe partial grid have been located in P–T space. Geothermobarometricdata and consideration of the deduced mineral reactions in thepetrogenetic grid show that the spinel granulites evolved throughan anticlockwise P–T trajectory reaching peak metamorphicconditions >9 kbar and 950C, followed by near-isobaric cooling(dT/dP = 150C/kbar). This was superimposed by an event of near-isothermaldecompression (dT/dP = 15C/kbar). The studied spinel granulites,therefore, preserve relic prograde mineral associations andreaction textures despite being metamorphosed at very high temperatures,and bear evidence of polymetamorphism. KEY WORDS: spinel granulite; Eastern Ghats; India; polymetamorphism; geothermometry; geobarometry Corresponding author