Potassium chlorate—hydrochloric acid: a sulphide selective leach for bedrock geochemistry

Potassium chlorate—hydrochloric acid is compared to ascorbic acid—hydrogen peroxide, aqua regia, and nitric—perchloric as a sulphide-selective leach for bedrock geochemistry. Results obtained on granodiorite samples containing copper sulphides indicate that the procedure is probably more selective than the other leaches and has the advantages of rapidity and simplicity.     

Identifying saltcedar with hyperspectral data and support vectormachines

Saltcedar (Tamarix spp.) are a group of dense phreatophytic shrubs and trees that are invasive to riparian areas throughout the United States. This study determined the feasibility of using hyperspectral data and a support vector machine (SVM) classifier to discriminate saltcedar from other cover types in west Texas. Spectral measurements were collected with a ground-based hyperspectral spectroradiometer (spectral range 350–2500 nm) in December 2008 and April 2009. Spectral data consisting of 1698 spectral bands (400–1349, 1441–1789, 1991–2359 nm) were subjected to a support vector machine classification to differentiate saltcedar from other vegetative and non-vegetative classes. For both dates, a linear kernel model with a C value (error penalty) of 100 was found optimum for separating saltcedar from the other classes. It identified saltcedar with accuracies ranging from 95% to 100%. Findings support further exploration of hyperspectral remote sensing technology and SVM classifiers for differentiating saltcedar from other cover types.     

Zirconolite and xenotime U–Pb age constraints on the emplacement of the Golden Mile Dolerite sill and gold mineralization at the Mt Charlotte mine,Eastern Goldfields Province,Yilgarn Craton,Western Australia

In situ SHRIMP U–Pb dating of magmatic zirconolite (CaZrTi₂O₇) in the Golden Mile Dolerite from the Mt Charlotte gold deposit (Yilgarn Craton, Australia) has yielded the first robust emplacement age (2,680 ± 9 Ma) for the principle host-rock of gold mineralization in the Kalgoorlie district. In contrast, co-magmatic zircon gave ages from ~2.68 Ga to ~2.17 Ga, reflecting isotopic resetting of high-U and -Th crystals. In situ SHRIMP analysis of hydrothermal xenotime (YPO₄), which co-exists with gold in alteration pyrite, provided a Pb/Pb isochron age of 2,655 ± 13 Ma. This date indicates that the youngest deposit in the Kalgoorlie district (Mt Charlotte) formed at ~2.65 Ga, and provides a new minimum age for the structurally older Golden Mile deposit. Our results indicate that gold mineralization at Mt Charlotte is ~50 million years older than indicated by recent ⁴⁰Ar/³⁹Ar dating and places new constraints on the timing of late-stage regional faulting (D₄) in the province.     

Radiogenic heating and craton‐margin plate stresses as drivers for intraplate orogeny

The Proterozoic belts that occur along the margins of the West Australian Craton, as well as those in intraplate settings, generally share similar geological histories that suggest a common plate‐margin driver for orogeny. However, the thermal drivers for intraplate orogenesis are more poorly understood. The Mutherbukin Tectonic Event records a protracted period of Mesoproterozoic reworking of the Capricorn Orogen and offers significant insight into both the tectonic drivers and heat sources of long‐lived intraplate orogens. Mineral assemblages and tectonic fabrics related to this event occur within a 50 km‐wide fault‐bound corridor in the central part of the Gascoyne Province in Western Australia. This zone preserves a crustal profile, with greenschist facies rocks in the north grading to upper amphibolite facies rocks in the south. The P–T–t evolution of 13 samples from 10 localities across the Mutherbukin Zone is investigated using phase equilibria modelling integrated with in situ U–Pb monazite and zircon geochronology. Garnet chemistry from selected samples is used to further refine the P–T history and shows that the dominant events recorded in this zone are prolonged D₁ transpression between c. 1,320 and 1,270 Ma, followed by D₂ transtension from c. 1,210 to 1,170 Ma. Peak metamorphic conditions in the mid‐crust reached >650°C and 4.4–7 kbar at c. 1,210–1,200 Ma. Most samples record a single clockwise P–T evolution during this event, although some samples might have experienced multiple perturbations. The heat source for metamorphism was primarily conductive heating of radiogenic mid‐ and upper crust, derived from earlier crustal differentiation events. This crust was thickened during D₁ transpression, although the thermal effects persisted longer than the deformation event. Peak metamorphism was terminated by D₂ transtension at c. 1,210 Ma, with subsequent cooling driven by thinning of the radiogenic crust. The coincidence of a sedimentary basin acting as a thermal lid and a highly radiogenic mid‐crustal batholith restricted to the Mutherbukin Zone accounts for reworking being confined to a discrete crustal corridor. Our results show that radiogenic regions in the shallow to mid crust can elevate the thermal gradient and localize deformation, causing the crust to be more responsive to far‐field stresses. The Mutherbukin Tectonic Event in the Capricorn Orogen was synchronous with numerous Mesoproterozoic events around the West Australian Craton, suggesting that thick cratonic roots play an important role in propagating stresses generated at distant plate boundaries.     

Failure to protect beaches under slowly rising sea level

The increase in population and the improvement of life standards are stretching the boundaries between water-energy-land management, and demanding innovative and holistic solutions. This article proposes an approach for increasing the water availability of two or more water basins taking into consideration land use and wind patterns, and was named Land, Water, and Wind Watershed Cycle (L3WC). This approach can be applied to one watershed or a combination of watersheds. In the first case, if wind patterns blow mainly in the opposite direction of the main river flow, plantations with high water demand should be focused on the lowest part of the basin. The transpired moisture would then return to the basin with the wind and possibly increase the water availability of the basin. Applying this method to a series of basins, water is transposed from one basin to another, used for irrigated agriculture, returned to the atmosphere with evapotranspiration and pushed back to the basin where the water was extracted by the wind. Case studies of this methodology are presented in the São Francisco basin and between the Tocantins, Amazonas, and Paraná basins and the São Francisco basin in Brazil. The São Francisco basin was selected because it is located in a dry region, its flow has considerably reduced in the past decade and because the trade winds blow constantly from the ocean into the continent all year around. L3WC is a strategy to plan the allocation of water consumption in a watershed, taking into account wind patterns to support the sustainable development of a region. It has the potential of increasing water availability and creating a climate change adaptation mechanism to control the climate and reduce vulnerability to climatic variations.     

Modelling of stormwater biofilters under random hydrologic variability: a case study of a car park at Monash University,Victoria (Australia)

Biofiltration systems represent an effective technology for the management of urban stormwater runoff volumes and quality. The performance of these systems, although largely dependent on their physical characteristics, is also strongly affected by the natural variability of runoff occurrence and volumes. This article presents a model that describes the statistical behaviour of the main variables involved in the water balance of a biofiltration system, given its main physical properties (filter media and vegetation types) and accounting for the natural inflow variability in terms of occurrence and water volumes. The model permits the analytical derivation of the long‐term (e.g. annual) probability density function of the soil water content in the filter media and the estimation of the main statistics of water fluxes, that is, outflow, evapotranspiration and overflow. By relating the soil water content in the filter media before inflow events to the outflow total nitrogen concentrations, the model also gives estimates of the statistics of nitrogen removal performance as a function of inflow variability. The model was tested against field data collected at a stormwater biofiltration system in Melbourne, Australia. The model could be used to rapidly assess the hydrologic and nitrogen treatment performance of alternative applications of biofiltration for stormwater management across a range of climates. Copyright © 2011 John Wiley & Sons, Ltd.     

A New Understanding of the Provinces of the Amazon Craton Based on Integration of Field Mapping and U-Pb and Sm-Nd Geochronology

New conventional and sensitive high-resolution ion microprobe zircon U-Pb dating has led to a new understanding of the subdivision and evolution of the Amazon Craton during Precambrian time, with major improvements and changes made to the previous Rb-Sr based model. The interpretation of U-Pb and Sm-Nd isotopic data identifies eight main Precambrian tectonic provinces in the Craton, with ages ranging from 3.1 to 0.99 Ga. Some of the provinces were generated by accretional, arc-related processes (Carajás, Transamazonic, Tapajós-Parima and Rondônia-Juruena) and others by recycling of continental crust (Central Amazon, Rio Negro and Sunsas). The exposed Archean crust is restricted to the east (Carajás and south Amapá in Brazil) and north (Imataca in Venezuela) of the craton, indicating that the Amazon Craton is largely a Proterozoic crust. The Carajás-Imataca (3.10–2.53 Ga) and Transamazonian (2.25–2.00 Ga) Provinces are composed predominantly of granite-greenstone terranes. The Tapajós-Parima (2.10–1.87 Ga) and Rondônia-Juruena (1.75–1.47 Ga) Provinces represent new crust added as orogenic belts, while the Rio Negro (1.86–1.52 Ga) and Sunsas (1.33–0.99 Ga) Provinces originated mainly by magmatic-tectonic recycling of the above two orogenic belts. The only zone with a prominent northeast trend is the poorly known K'Mudku Shear Belt, characterized by a 1.20 Ga shear zone which deforms the rocks of at least three different provinces (Rio Negro, Tapajós-Parima and Transamazonic). The Central Amazon Province comprises mostly Orosirian volcano-plutonic rocks (Uatumã Magmatism) and is a terrane in which the exposed crustal structure and deformation are pluton-related. The Sm-Nd T_DM model ages and _Nd suggest that the Central Amazon Province was generated by the partial melting of Archean continental crust (Carajás Province?), perhaps related to underplating that began at the end of the Tapajós-Parima Orogeny (1.88–1.86 Ga).