The Negev continental bridge: a chain in an intermodal transport system

This paper is a second follow-up discussion concerning the role, economic viability and operational characteristics of the Negev Continental Bridge in the fluid geo-political atmosphere of the Middle East. The two previous papers (Geoforum8, 29–32 and 311–318) discussed the viability of the Israeli Continental Bridge as an alternative to the Suez Canal. Now, two years after the Canal was re-opened for use by Israeli vessels, the annual amount of cargo movement across the Israeli land bridge is still growing, although it is less economical than the Suez Canal. It is thus suggested that there is a need to view the continental bridge as one part of a chain in an intermodal transport system.     

Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: confirmation of a seawater REE proxy in ancient limestones

Rare earth element and yttrium (REE+Y) concentrations were determined in 49 Late Devonian reefal carbonates from the Lennard Shelf, Canning Basin, Western Australia. Shale-normalized (SN) REE+Y patterns of the Late Devonian samples display features consistent with the geochemistry of well-oxygenated, shallow seawater. A variety of different ancient limestone components, including microbialites, some skeletal carbonates (stromatoporoids), and cements, record seawater-like REE+Y signatures. Contamination associated with phosphate, Fe-oxides and shale was tested quantitatively, and can be discounted as the source of the REE+Y patterns. Co-occurring carbonate components that presumably precipitated from the same seawater have different relative REE concentrations, but consistent REE+Y patterns. Clean Devonian early marine cements (n = 3) display REE+Y signatures most like that of modern open ocean seawater and the highest Y/Ho ratios (e.g., 59) and greatest light REE (LREE) depletion (average Nd_SN/Yb_SN = 0.413, SD = 0.076). However, synsedimentary cements have the lowest REE concentrations (e.g., 405 ppb). Non-contaminated Devonian microbialite samples containing a mixture of the calcimicrobe Renalcis and micritic thrombolite aggregates in early marine cement (n = 11) have the highest relative REE concentrations of tested carbonates (average total REE = 11.3 ppm). Stromatoporoid skeletons, unlike modern corals, algae and molluscs, also contain well-developed, seawater-like REE patterns. Samples from an estuarine fringing reef have very different REE+Y patterns with LREE enrichment (Nd_SN/Yb_SN > 1), possibly reflecting inclusion of estuarine colloidal material that contained preferentially scavenged LREE from a nearby riverine input source. Hence, Devonian limestones provide a proxy for marine REE geochemistry and allow the differentiation of co-occurring water masses on the ancient Lennard Shelf. Although appropriate partition coefficients for quantification of Devonian seawater REE concentrations from out data are unknown, hypothetical Devonian Canning Basin seawater REE patterns were obtained with coefficients derived from modern natural proxies and experimental values. Resulting Devonian seawater patterns are slightly enriched in LREE compared to most modern seawaters and suggest higher overall REE concentrations, but are very similar to seawaters from regions with high terrigenous inputs. Our results suggest that most limestones should record important aspects of the REE geochemistry of the waters in which they precipitated, provided they are relatively free of terrigenous contamination and major diagenetic alteration from fluids with high, non-seawater-like REE contents. Hence, we expect that many other ancient limestones will serve as seawater REE proxies, and thereby provide information on paleoceanography, paleogeography and geochemical evolution of the oceans.     

X-Ray Emission from Comet McNaught-Hartley (C/1999 T1)

Comet McNaught-Hartley was observed in five 1-h exposures on January 8-14 2001 using the advanced CCD imaging spectrometer on board the Chandra X-ray Observatory. The X-ray image of the comet does not show a crescent-like shape. The brightest region is offset from the nucleus between the sunward and comet velocity directions. The comet mean X-ray luminosity is equal to 7.8×10¹⁵ erg s⁻¹ for photon energy E>150 eV and aperture ρ=1.5×10⁵ km where the comet X-ray brightness exceeds 20% of the peak value. Gas production rate was 10²⁹ s⁻¹ during the observations, and the efficiency of X-ray excitation was equal to 4×10⁻¹⁴ erg AU^3/2. Day-to-day variations in X-rays reached a factor of 5. The strongest short-term variation was by a factor of 1.75 for 1600 s. This variation may be explained by a decline in the solar-wind flux by the same factor in ≈800 s. The comet and Earth were seeing different faces of the Sun, and time delay in the solar-wind events on the Earth and the comet was long, equal to 6 days. The best correlation between the comet X-ray luminosity and the solar-wind proton density is for the time delay of 5.5 days and may be explained by the higher velocity of heavy ions.Careful background subtraction made it possible to extract the comet spectrum from 150 to 1000 eV. No signal was detected at E>1000 eV, and a 3σ upper limit to any emission with E>1000 eV is 0.3% of the photon emission at 150-1000 eV. The best χ²-fit model to the spectrum consists of nine narrow emission features. The emission energies and intensities are in good agreement with a charge exchange spectrum calculated by us for the slow solar wind. Using this spectrum, we identify the observed emissions as (Ne⁷⁺+Mg⁷⁺+Mg⁸⁺) at 195 eV, (Mg⁸⁺+Mg⁹⁺+Si⁸⁺) at 250 eV, C⁵⁺ at 370 and 460 eV, O⁶⁺ at 560 eV, O⁷⁺ at 650, 780, and 840 eV, and Ne⁸⁺ at 940 eV. X-ray spectroscopy of comets may be used to diagnose the solar-wind composition and its interaction with comets.     

Calculation of lava effusion rates from Landsat TM data

 We present a thermal model to calculate the total thermal flux for lava flowing in tubes, on the surface, or under shallow water. Once defined, we use the total thermal flux to estimate effusion rates for active flows at Kilauea, Hawaii, on two dates. Input parameters were derived from Landsat Thematic Mapper (TM), field and laboratory measurements. Using these parameters we obtain effusion rates of 1.76±0.57 and 0.78±0.27 m³ s^–1 on 23 July and 11 October 1991, respectively. These rates are corroborated by field measurements of 1.36±0.14 and 0.89±0.09 m³s^–1 for the same dates (Kauahikaua et al. 1996). Using weather satellite (AVHRR) data of lower spatial resolution, we obtain similar effusion rates for an additional 26 dates between the two TM-derived measurements. We assume that, although total effusion rates at the source declined over the period, the shut down of the ocean entry meant that effusion rates for the surface flows alone remained stable. Such synergetic use of remotely sensed data provides measurements that can (a) contribute to monitoring flow-field evolution, and (b) provide reliable numerical data for input into rheological and thermal models. We look forward to being able to produce estimates for effusion rates using data from high-spatial-resolution sensors in the earth observing system (EOS) era, such as Landsat 7, the hyperspectral imager, the advanced spaceborne thermal emission spectrometer, and the advanced land imager. Received: 25 July 1997 / Accepted: 26 February 1998     

Processing contaminated dredged material from the Port of New York-New Jersey

Shipping activities in the Port of New York-New Jersey are currently threatened by restrictions on dredging of navigational channels and private berthing areas becaused of concerns about the environmental effects caused by ocean disposal of the dredged material. Current proposals for solutions to the problem include ocean disposal of uncontaminated material, use of confined disposal facilities (both upland facilities and containment islands), subaqueous barrow pits, and processing and treatment for contaminated materials. A project to produce a complete “treatment train” for processing and decontaminating dredged material is described. The work is divided into several phases: treatability studies of commercial and nonproprietary technologies at volumes of 19 liters (bench scale) and up to 19 m³ (pilot scale); specification of a treatment train; and implementation of a large-scale facility that can process 76,000–382,000 m³ of dredged material per year. The goal is to achieve operational status for the facility by the end of 1999.     

The composition of back-arc basin lower crust and upper mantle in the Mariana Trough: A first report

Abstract The Mariana Trough is an active back-arc basin, with the rift propagating northward ahead of spreading. The northern part of the Trough is now rifting, with extension accommodated by combined stretching and igneous intrusion. Deep structural graben are found in a region of low heat flow, and we interpret these to manifest a low-angle normal fault system that defines the extension axis between 19°45' and 21°10'N. A single dredge haul from the deepest (∼5.5 km deep) of these graben recovered a heterogeneous suite of volcanic and plutonic crustal rocks and upper mantle peridotites, providing the first report of the deeper levels of back-arc basin lithosphere. Several lines of evidence indicate that these rocks are similar to typical back-arc basin lithosphere and are not fragments of rifted older arc lithosphere. Hornblende yielded an ⁴⁰Ar/³⁹Ar age of 1.8 ± 0.6 Ma, which is interpreted to approximate the time of crust formation. Harzburgite spinels have moderate Cr# (<40) and coexisting compositions of clinopyroxene (CPX) and plagioclase (PLAB) fall in the field of mid-ocean ridge basalt (MORB) gabbros. Crustal rocks include felsic rocks (70-80% SiO₂) and plutonic rocks that are rich in amphibole. Chemical compositions of crustal rocks show little evidence for a 'subduction component', and radiogenic isotopic compositions correspond to that expected for back-arc basin crust of the Mariana Trough. These data indicate that mechanical extension in this part of the Mariana Trough involves lithosphere that originally formed magmatically. These unique exposures of back-arc basin lithosphere call for careful study using ROVs and manned submersibles, and consideration as an ocean drilling program (ODP) drilling site.     

Distribution of thermal areas on an active lava flow field: Landsat observations of Kilauea,Hawaii, July 1991

A Landsat Thematic Mapper (TM) image acquired on 23 July 1991 recorded widespread activity associated with the Episode 48 of the Pu'u 'O'o-Kupaianaha eruption of Kilauea Volcano, Hawaii. The scene contains a very large number (>3500) of thermally elevated near infrared (0.8–2.35 m) pixels (each 900 m²), which enable the spatial distribution of volcanic activity to be identified. This activity includes a lava lake within Pu'u 'O'o cone, an active lava tube system (7.9 km in length) with skylights between the Kupaianaha lava shield and several ocean entry points, and extensive active surface flows (total area of 1.3 km²) within a much larger area of cooling flows (total16 km²). The production of an average flux density map from the TM data of the flow field, wherein the average flux density is defined in units of Wm^-2, allows for the chronology of emplacement of active and cooling flows to be determined. The flux density map reveals that there were at least three breakouts (>5000 Wm^-2) feeding active flows, but on the day that the data were collected the TM recorded a waning phase of surface activity in this area, based on the relatively large amount of intermediate power-emitting (cooling) flows compared to high power-emitting (active) flows. The production of a comparable flux density map for future eruptions would aid in the assessment of volcanic hazards if the data were available in near-real time.     

Insights into operation of the subduction factory from the oxygen isotopic values of the southern Izu–Bonin–Mariana Arc

Abstract Oxygen is the most abundant element in the earth, and isotopic analysis of this element in island arc lavas potentially provides sensitive constraints on the proportion of oxygen recycled from subducted material, relative to that extracted from the mantle. Here we report on 225 new oxygen isotopic analyses of whole‐rock and glass samples, and clinopyroxene separates, from lavas collected from the southernmost 1500 km of the Izu–Bonin–Mariana (IBM) convergent margin. Whole‐rock samples clustered around a mean of 6.11 ± 0.47‰, whereas Mariana Trough glasses and mafic melts, calculated to be in equilibrium with mafic phenocrysts, clustered narrowly around a mean of 5.7‰. These data demonstrate that unequivocal identification of magmatic oxygen requires analysis of fresh glass or mafic minerals, and that the source of southern IBM Arc melts is entirely, or almost entirely, in equilibrium with normal mantle oxygen. If the elemental enrichments characteristic of the subduction component originate in subducted materials, these oxygen isotopic data are most consistent with the interaction of a small amount of sediment melt (<4%; mostly less than 1%) with mantle peridotite to yield the hybrid mantle that melts to form IBM Arc magmas.     

Archean adakites from the Ashuanipi complex,eastern Superior Province,Canada: geochemistry,geochronology and tectonic significance

Contributions to Mineralogy and Petrology - Adakitic geochemical features characterize the Desliens suite of pre-tectonic diorite to tonalite sills intruded into volcanogenic greywackes of the...     

Enviromental genotoxicity evaluation: Bayesian approach for a mixture statistical model

 The data analyzed in this paper are part of the results described in Bueno et al. (2000). Three cytogenetics endpoints were analyzed in three populations of a species of wild rodent – Akodon montensis – living in an industrial, an agricultural, and a preservation area at the Itajaí Valley, State of Santa Catarina, Brazil. The polychromatic/normochromatic ratio, the mitotic index, and the frequency of micronucleated polychromatic erythrocites were used in an attempt to establish a genotoxic profile of each area. It was assumed that the three populations were in the same conditions with respect to the influence of confounding factors such as animal age, health, nutrition status, presence of pathogens, and intra- and inter-populational genetic variability. Therefore, any differences found in the endpoints analyzed could be attributed to the external agents present in each area. The statistical models used in this paper are mixtures of negative-binomials and Poisson variables. The Poisson variables are used as approximations of binomials for rare events. The mixing distributions are beta densities. The statistical analyzes are under the bayesian perspective, as opposed to the frequentist ones often considered in the literature, as for instance in Bueno et al. (2000).