Protracted storage of CR chondrules in a region of the disk transparent to galactic cosmic rays

Renazzo‐type carbonaceous (CR) chondrites are accretionary breccias that formed last. As such they are ideal samples to study precompaction exposures to cosmic rays. Here, we present noble gas data for 24 chondrules and 3 dark inclusion samples (DIs) from Shi?r 033 (CR2). The meteorite was selected based on the absence of implanted solar wind noble gases and an anomalous oxygen isotopic composition of the DIs; the oxygen isotopes match those in CV3 and CO3 chondrites. Our samples contain variable mixtures of galactic cosmic ray (GCR)‐produced cosmogenic noble gases and trapped noble gases of presolar origin. Remarkably, all chondrules have cosmogenic ³He and ²¹Ne concentrations up to 4.3 and 7.1 times higher than the DIs, respectively. We derived an average ³He‐²¹Ne cosmic ray exposure (CRE) age for Shi?r 033 of 2.03 ± 0.20 Ma (2 SD) and excesses in cosmogenic ³He and ²¹Ne in chondrules (relative to the DIs) in the range (in 10^?8 cm³STP/g) 3.99–7.76 and 0.94–1.71, respectively. Assuming present‐day GCR flux density, the excesses translate into average precompaction ³He‐²¹Ne CRE ages of 3.1–27.3 Ma depending on the exposure geometry. The data can be interpreted assuming a protracted storage of a single chondrule generation prior to the final assembly of the Shi?r 033 parent body in a region of the disk transparent to GCRs.     

Diffusion-limited REE uptake by eclogite garnets and its consequences for Lu–Hf and Sm–Nd geochronology

Garnets from the Zermatt-Saas Fee eclogites contain narrow central peaks for Lu + Yb + Tm ± Er and at least one additional small peak towards the rim. The REE Sm + Eu + Gd + Tb ± Dy are depleted in the cores but show one prominent peak close to the rim. These patterns cannot be modeled using Rayleigh fractionation accompanied by mineral breakdown reactions. Instead, the patterns are well explained using a transient matrix diffusion model where REE uptake is limited by diffusion in the matrix surrounding the porphyroblast. Observed profiles are well matched if a roughly linear radius growth rate is used. The secondary peaks in the garnet profiles are interpreted to reflect thermally activated diffusion due to temperature increase during prograde metamorphism. The model predicts anomalously low ¹⁷⁶Lu/¹⁷⁷Hf and ¹⁴⁷Sm/¹⁴⁴Nd ratios in garnets where growth rates are fast compared to diffusion of the REE, and these results have important implications for Lu–Hf and Sm–Nd geochronology using garnet.     

Miocene shallow-water limestones from São Nicolau (Cabo Verde): Caribbean-type benthic fauna and time constraints for volcanism

Shallow-water limestones of presumed Late Cretaceous and Eocene age, interbedded with basaltic lavas, were described by earlier authors from São Nicolau in the northwestern part of the Cabo Verde archipelago. If confirmed, these ages would imply late Mesozoic shallow-marine and subaerial volcanic activity in the Cabo Verde archipelago, and document a geological history very different from that known so far from other Cabo Verde Islands, from which no subaerial volcanic activity before the mid-Cenozoic is known. Our re-investigation of the foraminiferal fauna indicates a Late Miocene age for the presumed Late Cretaceous and Eocene limestones. The hypothesis of a long-lived hot spot, active by the Early Cretaceous, and of a major island-building stage in the Cabo Verde Islands during this period, is therefore not supported by the present bio- or chronostratigraphic data.     

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

Modelling ecohydrological feedbacks in forest and grassland plots under a prolonged drought anomaly in Central Europe 2018–2020

Recent studies have highlighted the importance of understanding ecohydrological drought feedbacks to secure water resources under a changing climate and increasing anthropogenic impacts. In this study, we monitored and modelled feedbacks in the soil–plant-atmosphere continuum to the European drought summer 2018 and the following 2 years. The physically based, isotope-aided model EcH₂O-iso was applied to generic vegetation plots (forest and grassland) in the lowland, groundwater-dominated research catchment Demnitzer Millcreek (NE Germany; 66 km²). We included, inter alia, soil water isotope data in the model calibration and quantified changing “blue” (groundwater recharge) and “green” (evapotranspiration) water fluxes and ages under each land use as the drought progressed. Novel plant xylem isotope data were excluded from calibration but were compared with simulated root uptake signatures in model validation. Results indicated inter-site differences in the dynamics of soil water storage and fluxes with contrasting water age both during the drought and the subsequent 2 years. Forest vegetation consistently showed a greater moisture stress, more rapid recovery and higher variability in root water uptake depths from a generally younger soil water storage. In contrast, the grassland site, which had more water-retentive soils, showed higher and older soil water storage and groundwater recharge fluxes. The damped storage and flux dynamics under grassland led to a slower return to younger water ages at depth. Such evidence-based and quantitative differences in ecohydrological feedbacks to drought stress in contrasting soil-vegetation units provide important insights into Critical Zone water cycling. This can help inform future progress in the monitoring, modelling and development of climate mitigation strategies in drought-sensitive lowlands.     

Statistical-dynamical downscaling of wind roses over the Czech Republic

The present study describes a new method for statistical-dynamical downscaling that combines two different approaches, namely, a set of patterns simulated with a numerical flow model and a transformation function used to process both calculated data and measurements at a reference station. The combined method produces wind roses and wind speed histograms at an arbitrary location in the model domain. The inflow wind direction represented the key parameter to define a set of wind field simulations. The other two inflow parameters, namely, thermal stratification and geostrophic wind speed, were derived from corresponding averaged soundings. The results showed that in the Czech Republic, there are areas where wind roses are deformed by the surrounding terrain. The deformations occur in relatively shallow and wide valleys, and they are more sensitive to the inflow wind direction. Calculated wind roses are compared to corresponding observations at 22 synoptic stations. The most frequent wind direction sector in simulations agreed with measurements at 17 stations. The resulting error in frequency in that sector was under 5 % at 10 stations. In general, the main features of the wind roses are modelled well, even at a relatively large distance from the reference station. However, better performance was achieved for smaller distances between reference station and the site. In further studies, a more extensive set of flow patterns with reduced intervals of thermal stratification and wind speed will likely improve calculated wind roses.     

Low melting temperature for calcite at 1000 bars on the join CaCO3‐H2O – some geological implications

Melting experiments of calcite were performed on the join CaCO₃‐H₂O at a pressure of 1000 bars. The system evolves to the ternary CaO‐H₂O‐CO₂ system during melting experiments. Our experiments show that partial melting of calcite begins at a low temperature, below 650 °C. Such a low partial melting temperature for carbonates revives the debate about the presence of carbonate melts in the upper crust. More specifically, the conditions for carbonate partial melting are present in carbonate host rocks undergoing contact metamorphism at high temperatures in the presence of water‐rich fluid. The presence of carbonate melts influences physical parameters such as viscosity and permeability in contact aureoles, and, furthermore, decarbonation reactions release massive amounts of CO₂.     

Robotic telescopes for high energy astrophysics in Ondřejov

We report on two small aperture robotic telescopes called BART and D50 operated in Ondřejov. Both telescopes are capable of automatic observation of gamma ray burst (GRB) optical afterglows. Coordinates of GRBs are taken from alerts distributed via Internet. Telescopes observe other interesting high energy sources when there is not any alert. The smaller telescope BART has aperture D = 254 mm. The bigger telescope D50 has a primary mirror of diameter D = 500 mm. Both telescopes are controlled by free software package RTS2 and are accessible through Internet. We describe the two telescopes and related software and show some results such as our first observed optical counterpart of GRB.