Linear discriminant analysis to describe the relationship between rainfall and landslides in Bogotá, Colombia

Bogotá is located in the central Andean region of Colombia, which is frequently affected by landslide processes. These processes are mostly triggered during the rainy season in the city. This fact remarks the importance of determining what rain-derived parameters (e.g. intensity, antecedent rain, daily rain) are better related with the occurrence of landslides. For this purpose, the linear discriminant analysis (LDA), a technique derived from multivariate statistics, was used. The application of this type of analysis led to obtain simple mathematical functions that represent the probability of occurrence of landslides in Bogotá. The functions also allow to identify the most relevant variables derived from records of rainfall linked to the generation of landslides. A proof of concept using the proposed methodology was done using historic rainfall data from a 9-km² area of homogenous climatology and geomorphology in the south part of Bogotá. Landslides needed to be grouped for the LDA. Each one of these grouping categories represents landslides that occurred in similar geomorphologic conditions. Another set of events with no landslides was generated synthetically. Results of the proof of concept show that rainfall parameters such as normalized rainfall intensity I _MAP, normalized daily rainfall R _MAP and rainy-days normal RDN have the best statistical correlation with the landslides observed in the zone of analysis.     

The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2

Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H₂SO₄, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L⁻¹, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO₄–H⁺ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H⁺ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO₄–H⁺ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H⁺ solutions.     

Metamorphic gradients in burial metamorphosed vesicular lavas: Comparison of basalt and spilite in Cretaceous basic flows from central Chile

Partial spilitization of a 9 km thick pile of flood basalts with highly vesicular flow tops gave rise to patterns of secondary mineralogy at different scales: (a) a local pattern of mineralogical variation from the almost unaltered bottom towards the altered top of each flow, and (b) an overall pattern, comparing flow tops throughout the pile, with changes in mineralogical composition within a sequence of metamorphic zones and facies. The local patterns mimic the trend of the overall pattern, but are of opposite direction and telescoped. Thus, a gradual ordering and Andepletion of the secondary albite and increases in the Fe^*/Al ratio of epidote and pumpellyite upwards within individual flows are comparable in range to corresponding overall changes downwards throughout several kilometres. The mineralogical changes within the flows diminish in range towards the more altered deeper part of the pile.The local and overall patterns cannot be interpreted in terms of grade. They represent trends from metastable towards stable equilibrium, this latter only approached in the flow tops of the lower part of the pile. The patterns of secondary mineralogy were formed by an interplay of metamorphic gradients at different scales at any given time, and as burial proceeded. The overall pattern was caused by depth-controlled gradients: increasing P _fluid, temperature and temperature-induced increase of reaction rates, and decreasing fO₂ (downwards in the pile). The local patterns resulted from permeability-controlled gradients: increasing reaction rates, fO₂ and contrast in chemical activity between different domains, and decreasing P _fluid (upwards in each flow). The mineralogical observations reported in this paper fall into line if the overall temperature-induced increase of reaction rates and the local permeability-controlled rate factors played the leading role during burial metamorphism of the pile.     

The Precambrian geology of El Cristo,southern Tandilia Region,Argentina

Metamorphic and granitoid rocks of the El Cristo area, southern part of Tandilia Range, are considered in terms of structural, lithological and geochronological data.The abovementioned area was affected before 2000 m. y. by a first tectono-thermal event that was followed by a second episode of intense SW-NE folding. The latter accompanied or followed by a metamorphism of almandine grade and strong synkinematic to latekinematic granitization during the span 1800-1520 m. y.Succeeding episodes of metamorphism and deformation were less intense and culminated in the local development of a 900 m. y. granite, chloritization and some brittle deformation.

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Zusammenfassung Tektonische, lithologische und geochronologische Daten der metamorphen und granitischen Gesteine der El Cristo Gegend im südlichen Teil des Tandilia Gebirges werden diskutiert.Vor mehr als 2000 Ma wurde dieses Gebiet erstmals von einem tektonothermalen Ereignis erfa\t, gefolgt von einer zweiten Episode starker SW-NE gerichteter Faltung. Letztere wurde begleitet oder gefolgt von einer Almandingrad Metamorphose und starker synbis spÄtkinematischer Granitisierung wÄhrend der Zeitspanne 1800 bis 1520 Ma.Darauffolgende Metamorphosen und Deformationsereignisse waren weniger intensiv und endeten um 900 Ma in Lokaler Granitintrusion, Chloritisierung und spröder Deformation.

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Résumé Des roches métamorphiques et granitoÏdes de la région de Cristo font ici l'objet d'une discussion sur la base de données structurales, lithologiques et géochronologiques.La région mentionnée a été marquée d'abord, il y a plus de 2000 millions d'années, par une phénomène thermo-tectonique, suivi, dans une seconde phase, d'un plissement important dirigé SO-NE. Celui-ci a été accompagné ou suivi par un métamorphisme à almandin et par une intense granitisation syncinématique à tardicinématique au cours de la période 1800-1500 m. a.Des épisodes de métamorphisme et de déformation moins intenses s'ensuivirent, qui aboutirent au développement local, vers 900 m. a., d'une intrusion granitique, avec chloritisation et déformations cassantes.

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Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.     

The Middle Jurassic radiolarites and pelagic limestones of the Nieves unit (Rondaide Complex, Betic Cordillera): basin starvation in a rifted marginal slope of the western Tethys

Middle Jurassic radiolarites and associated pelagic limestones occur in the Rondaide Nieves unit of the Betic Cordillera, southern Spain. The Rondaide Mesozoic includes: (a) a thick succession of Triassic platform carbonates, comparable to the Alpine Hauptdolomit and Kössen facies; (b) Lower Jurassic pelagic limestones comparable to the Alpine Hierlatz and Adnet facies; (c) the Middle Jurassic Parauta Radiolarite Formation, described herein; and (d) a thin Upper Jurassic-Cretaceous condensed limestone succession. The Parauta Radiolarite Formation and associated limestones were studied with respect to stratigraphy, petrography, micropalaeontology (radiolarians, calcareous nanno- and microfossils) and facies. Radiolarite sedimentation occurred in the Middle Bathonian in a restricted and dysoxic deep Nieves basin, perched in the distal zone of a continental margin fringing the Tethyan ocean. This margin was adjacent to a young narrow oceanic basin between the South-Iberian margin and a continental block called Mesomediterranean Terrane. The Nieves basin was part of a marine corridor between the Proto-Atlantic and Piedmont-Ligurian basins of the Alpine Tethys. The regional tectonic position, the stratigraphical evolution since the Triassic, the age and the nature of the Mesozoic facies and the palaeogeographic relations to adjacent domains show striking analogies between the Betic Rondaide margin and coeval units of the Alps.     

Metal-enriched nanoparticles and black carbon: A perspective from the Brazil railway system air pollution

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.     

An iron-bearing wave-dominated siliciclastic shelf: Facies analysis and palaeogeographic implications (Silurian-Lower Devonian Sierra Grande Formation,Southern Argentina)

The Sierra Grande Formation (Silurian-Early Devonian) consists of quartz arenites associated with clast supported conglomerates, mudstones, shales and ironstones. Eight sedimentary facies are recognized: cross-stratified and massive sandstone, plane bedded sandstone, ripple laminated sandstone, interstratified sandstone and mudstone, laminated mudstone and shale, oolitic ironstone, massive conglomerate and sheet conglomerate lags. These facies are interpreted as shallow marine deposits, ranging from foreshore to inner platform environments. Facies associations, based on vertical relationships among lithofacies, suggest several depositional zones: (a) beach to upper shoreface, with abundant plane bedded and massive bioturbated sandstones; (b) upper shoreface to breaker zone, characterized by multistorey cross-stratified and massive sandstone bodies interpreted as subtidal longshore-flow induced sand bars; (c) subtidal, nearshore tidal sand bars, consisting of upward fining sandstone sequences; (d) lower shoreface zone, dominated by ripple laminated sandstone, associated with cross-stratified and horizontal laminated sandstone, formed by translatory and oscillatory flows; and (e) transitional nearshore-offshore and inner platform zones, with heterolithic and pelitic successions, and oolitic ironstone horizons. Tidal currents, fair weather waves and storm events interacted during the deposition of the Sierra Grande Formation. However, the relevant features of the siliciclastics suggest that fair weather and storm waves were the most important mechanisms in sediment accumulation. The Silurian-Lower Devonian platform was part of a continental interior sag located between southern South America and southern Africa. The Sierra Grande Formation was deposited during a second order sea level rise, in which a shallow epeiric sea flooded a deeply weathered low relief continent.     

Multiphase structural evolution of the western margin of the Girardot subbasin, Upper Magdalena Valley, Colombia

More than 1400 km of two-dimensional seismic data were used to understand the geometries and structural evolution along the western margin of the Girardot Basin in the Upper Magdalena Valley. Horizons are calibrated against 50 wells and surface geological data (450 km of traverses). At the surface, low-angle dipping Miocene strata cover the central and eastern margins. The western margin is dominated by a series of en echelon synclines that expose Cretaceous–Oligocene strata. Most synclines are NNE–NE trending, whereas bounding thrusts are mainly NS oriented. Syncline margins are associated mostly with west-verging fold belts. These thrusts started deformation as early as the Eocene but were moderately to strongly reactivated during the Andean phase. The Girardot Basin fill records at least four stratigraphic sequences limited by unconformities. Several periods of structural deformation and uplifting and subsidence have affected the area. An early Tertiary deformation event is truncated by an Eocene unconformity along the western margin of the Girardot Basin. An Early Oligocene–Early Miocene folding and faulting event underlies the Miocene unconformity along the northern and eastern margin of the Girardot Basin. Finally, the Late Miocene–Pliocene Andean deformation folds and erodes the strata along the margins of the basin against the Central and Eastern Cordilleras.     

The First Mesozoic Heterodactyl Bird from China

1 Introduction Enantiornithines were the dominant birds nearly worldwide throughout the entire span of the Cretaceous (Chiappe, 1995; Feduccia, 1996). The adaptive radiation of opposite birds is little known besides the disparity of rostral morphology in Boluochia (Zhou, 1995), Longipteryx (Zhang et al., 2001), Longirostravis ( Hou et al., 2004), and the presence of stomach contents that reflect a diversity of diets. Like the structure of rostrum, differentiation of the locomotor apparatu…