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101.
Christopher Hamann Agnese Fazio Matthias Ebert Lutz Hecht Richard Wirth Luigi Folco Alex Deutsch Wolf Uwe Reimold 《Meteoritics & planetary science》2018,53(8):1594-1632
We have investigated silicate emulsions in impact glasses and impact melt rocks from the Wabar (Saudi Arabia), Kamil (Egypt), Barringer (USA), and Tenoumer (Mauritania) impact structures, and in experimentally generated impact glasses and laser-generated glasses (MEMIN research unit) by scanning electron microscopy, electron microprobe analysis, and transmission electron microscopy. Textural evidence of silicate liquid immiscibility includes droplets of one glass disseminated in a chemically distinct glassy matrix; sharp phase boundaries (menisci) between the two glasses; deformation and coalescence of droplets; and occurrence of secondary, nanometer-sized quench droplets in Si-rich glasses. The compositions of the conjugate immiscible liquids (Si-rich and Fe-rich) are consistent with phase separation in two-liquid fields in the general system Fe2SiO4–KAlSi3O8–SiO2–CaO–MgO–TiO2–P2O5. Major-element partition coefficients are well correlated with the degree of polymerization (NBO/T) of the Si-rich melt: Fe, Ca, Mg, and Ti are concentrated in the poorly polymerized, Fe-rich melt, whereas K, Na, and Si prefer the highly polymerized, Si-rich melt. Partitioning of Al is less pronounced and depends on bulk melt composition. Thus, major element partitioning between the conjugate liquids closely follows trends known from tholeiitic basalts, lunar basalts, and experimental analogs. The characteristics of impact melt inhomogeneity produced by melt unmixing in a miscibility gap are then compared to impact melt inhomogeneity caused by incomplete homogenization of different (miscible or immiscible) impact melts that result from shock melting of different target lithologies from the crater's melt zone, which do not fully homogenize and equilibrate due to rapid quenching. By taking previous reports on silicate emulsions in impact glasses into account, it follows that silicate impact melts of variable composition, cooling rate, and crystallization history might readily unmix during cooling, thereby rendering silicate liquid immiscibility a much more common process in the evolution of impact melts than previously recognized. 相似文献
102.
Francesca Sangiorgi Lucilla Capotondi Nathalie Combourieu Nebout Luigi Vigliotti Henk Brinkhuis Simona Giunta Andr F. Lotter Caterina Morigi Alessandra Negri Gert‐Jan Reichart 《第四纪科学杂志》2003,18(8):723-732
Holocene cooling events have been reconstructed for the southern Adriatic Sea (central Mediterranean) by means of analyses of organic walled dinoflagellate cysts, planktonic foraminifera, oxygen isotopes, calcareous nanoplankton, alkenones and pollen from a sediment core. Two cooling events have been detected, during which sea‐surface temperatures (SSTs) were ca. 2°C lower. Unravelling the SST signal into dominant seasonal components suggests maximum winter cooling of 2°C at around 6.0 ka, whereas the cooling at ca. 3.0 ka might be the result of a spring temperature cooling of 2–3°C. The events, lasting several hundred years, are apparently synchronous with those in the Aegean Sea, where they have been related to known cooling events from the Greenland ice‐core record. A distinct interruption in Adriatic Sea sapropel S1 is not clearly accompanied by a local drop in winter temperatures, but seems to be forced by ventilation, which probably occurred earlier in the Aegean Sea and was subsequently transmitted to the Adriatic Sea. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
103.
Harold C. Connolly Caroline Smith Gretchen Benedix Luigi Folco Kevin Righter Jutta Zipfel Akira Yamaguchi Hasnaa Chennaoui Aoudjehane 《Meteoritics & planetary science》2007,42(9):1647-1694
Abstract— In this edition of The Meteoritical Bulletin, 1394 recognized meteorites are reported, 27 from specific locations within Africa, 133 from Northwest Africa, 1227 from Antarctica (from ANSMET, PNRA, and PRIC expeditions), and 7 from Asia. The Meteoritical Bulletin announces the approval of four new names series by the Nomenclature Committee of the Meteoritical Society, two from Africa and one from Asia, including Al Haggounia, from Al Haggounia, Morocco, which is projected to be on the order of 3 metric tons of material related to enstatite chondrites and aubrites. Approved are two falls from Africa, Bassikounou (Mauritania) and Gashua (Nigeria). Approved from areas other than Antarctica are one lunar, two Martian, 32 other achondrites, three mesosiderites, two pallasites, one CM, two CK, one CR2, two CV3, one CR2, and four R chondrites. The Nomenclature Committee of the Meteoritical Society announces 48 newly approved relict meteorites from two new name series, Österplana and Gullhögen (both from Sweden). 相似文献
104.
The standard thermodynamic properties at 25°C, 1 bar (ΔG
fo, ΔH
fo, S
o, C
Po, V
o, ω) and the coefficients of the revised Helgeson–Kirkham–Flowers equations of state were evaluated for several aqueous complexes
formed by dissolved metals and either arsenate or arsenite ions. The guidelines of Shock and Helgeson (Geochim Cosmochim Acta
52:2009–2036, 1988) and Sverjensky et al. (Geochim Cosmochim Acta 61:1359–1412, 1997) were followed and corroborated with alternative approaches, whenever possible. The SUPCRT92 computer code was used to generate
the log K of the destruction reactions of these metal–arsenate and metal–arsenite aqueous complexes at pressures and temperatures required
by the EQ3/6 software package, version 7.2b. Apart from the AlAsO4o and FeAsO4o complexes, our log K at 25°C, 1 bar are in fair agreement with those of Whiting (MS Thesis, Colorado School of Mines, Golden, CO, 1992). Moreover, the equilibrium constants evaluated in this study are in good to fair agreement with those determined experimentally
for the Ca–dihydroarsenate and Ca–hydroarsenate complexes at 40°C (Mironov et al., Russ J Inorg Chem 40:1690, 1995) and for Fe(III)–hydroarsenate complex at 25°C (Raposo et al., J Sol Chem 35:79–94, 2006), whereas the disagreement with the log K measured for the Ca–arsenate complex at 40°C (Mironov et al., Russ J Inorg Chem 40:1690, 1995) might be due to uncertainties in this measured value. The implications of aqueous complexing between dissolved metals and
arsenate/arsenite ions were investigated for seawater, high-temperature geothermal liquids and acid mine drainage and aqueous
solutions deriving from mixing of acid mine waters and surface waters.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献
105.
Luigi Tosi Pietro Teatini Laura Carbognin Jane Frankenfield 《Environmental Geology》2007,52(5):889-898
The paper deals with the implementation of a levelling and Global Positioning System (GPS) network to control land subsidence
in the coastal area north of the Venice Lagoon. About 480 km of levelling lines with 527 benchmarks, 45 of which suited for
Differential GPS measurements, were established in 2004. A complete survey of the net was carried out in 2004 soon after its
establishment. The 2004 records have been compared with previous scattered data obtained by the use of levelling surveys,
DGPS and SAR interferometry. The results show a trend in land settlement that increases from the lagoon margin to the north
and jeopardize the Venice coastland. Groundwater withdrawals for domestic, agricultural, and health spas uses, peat oxidation
of reclaimed marshlands for farming, natural consolidation of the Holocene deposits, and tectonics of the pre-Quaternary basement
are the causes of land subsidence in the study area. Since most of the area lies below the mean sea level and on account of
the expected sea level rise due to global change, a detailed monitoring of land displacements in the near future will be of
paramount importance to plan necessary works for coastland protection. 相似文献
106.
Luigi Folco Massimo D'Orazio Alessandro Burroni 《Meteoritics & planetary science》2006,41(8):1183-1198
Abstract— The Frontier Mountain (FRO) 93001 meteorite is a 4.86 g fragment of an unshocked, medium‐ to coarse‐grained rock from the acapulcoite‐lodranite (AL) parent body. It consists of anhedral orthoenstatite (Fs13.3 ± 0.4Wo3.1 ± 0.2), augite (Fs6.1 ± 0.7Wo42.3 ± 0.9; Cr2O3 = 1.54 ± 0.03), and oligoclase (Ab80.5 ± 3.3Or3.1 ± 0.6) up to >1 cm in size enclosing polycrystalline aggregates of fine‐grained olivine (average grain size: 460 ± 210 μm) showing granoblastic textures, often associated with Fe,Ni metal, troilite, chromite (cr# = 0.91 ± 0.03; fe# = 0.62 ± 0.04), schreibersite, and phosphates. Such aggregates appear to have been corroded by a melt. They are interpreted as lodranitic xenoliths. After the igneous (the term “igneous” is used here strictly to describe rocks or minerals that solidified from molten material) lithology intruding an acapulcoite host in Lewis Cliff (LEW) 86220, FRO 93001 is the second‐known silicate‐rich melt from the AL parent asteroid. Despite some similarities, the silicate igneous component of FRO 93001 (i.e., the pyroxene‐plagioclase mineral assemblage) differs in being coarser‐grained and containing abundant enstatite. Melting‐crystallization modeling suggests that FRO 93001 formed through high‐degree partial melting (≥35 wt%; namely, ≥15 wt% silicate melting and ?20 wt% metal melting) of an acapulcoitic source rock, or its chondritic precursor, at temperatures ≥1200 °C, under reducing conditions. The resulting magnesium‐rich silicate melt then underwent equilibrium crystallization; prior to complete crystallization at ?1040 °C, it incorporated lodranitic xenoliths. FRO 93001 is the highest‐temperature melt from the AL parent‐body so far available in laboratory. The fact that FRO 93001 could form by partial melting and crystallization under equilibrium conditions, coupled with the lack of quench‐textures and evidence for shock deformation in the xenoliths, suggests that FRO 93001 is a magmatic rock produced by endogenic heating rather than impact melting. 相似文献
107.
108.
109.
Adriana Giangrande Margherita Licciano Roberto Schirosi Luigi Musco Loredana Stabili 《Marine Ecology》2014,35(1):36-45
In the marine environment, sessile invertebrates have developed an impressive array of mechanisms to avoid predation, bacterial exploitation, and epibiotic overgrowth. In the present study we investigated several defensive strategies adopted by six sabellids: the hard bottom species Sabella spallanzanii (Gmelin, 1791), Branchiomma luctuosum Grube, 1869, Branchiomma bairdi (McIntosh, 1885), and Sabellastarte spectabilis (Grube, 1878), and the soft bottom species Myxicola infundibulum (Renier, 1804), and Megalomma lanigera (Grube, 1846), which have different morphological characteristics and geographical distribution. We examined and compared some defensive features such as branchial crown toughness, tube structure and strength, amount of released mucus, and antibacterial lysozyme‐activity in the mucus. The investigated species utilize a combination of defence and deterrence strategies that seems to be related to the colonized habitat. Tube strength was, higher in the hard bottom species compared with the soft bottom ones, where the tubes are generally buried and protected within the sediment. Branchial crown appeared stronger and resistant in hard bottom species, except for S. spallanzanii, which is the species showing the strongest tube. Sabella spallanzanii, M. infundibulum and S. spectabilis secreted high amount of mucus with high lysozyme‐like activity. By contrast, B. luctuosum, B. bairdi, and M. lanigera produced low amounts of mucus exerting lower antibacterial activity. 相似文献
110.
Daniela Mele Roberto Sulpizio Pierfrancesco Dellino Luigi La Volpe 《Bulletin of Volcanology》2011,73(3):257-278
New volcanological studies allow reconstruction of the eruption dynamics of the Pomici di Mercato eruption (ca 8,900 cal.
yr B.P.) of Somma-Vesuvius. Three main Eruptive Phases are distinguished based on two distinct erosion surfaces that interrupt
stratigraphic continuity of the deposits, indicating that time breaks occurred during the eruption. Absence of reworked volcaniclastic
deposits on top of the erosion surfaces suggests that quiescent periods between eruptive phases were short perhaps lasting
only days to weeks. Each of the Eruptive Phases was characterised by deposition of alternating fall and pyroclastic density
current (PDC) deposits. The fallout deposits blanketed a wide area toward the east, while the more restricted PDC deposits
inundated the volcano slopes. Eruptive dynamics were driven by brittle magmatic fragmentation of a phonolitic magma, which,
because of its mechanical fragility, produced a significant amount of fine ash. External water did not significantly contribute
either to fragmentation dynamics or to mechanical energy release during the eruption. Column heights were between 18 and 22 km,
corresponding to mass discharge rates between 1.4 and 6 × 107 kg s−1. The estimated on land volume of fall deposits ranges from a minimum of 2.3 km3 to a maximum of 7.4 km3. Calculation of physical parameters of the dilute pyroclastic density currents indicates speeds of a few tens of m s−1 and densities of a few kg m−3 (average of the lowermost 10 m of the currents), resulting in dynamic pressures lower than 3 kPa. These data suggest that
the potential impact of pyroclastic density currents of the Pomici di Mercato eruption was smaller than those of other Plinian
and sub-Plinian eruptions of Somma-Vesuvius, especially those of 1631 AD and 472 AD (4–14 kPa), which represent reference
values for the Vesuvian emergency plan. The pulsating and long-lasting behaviour of the Pomici di Mercato eruption is unique
in the history of large explosive eruptions of Somma-Vesuvius. We suggest an eruptive scheme in which discrete magma batches
rose from the magma chamber through a network of fractures. The injection and rise of the different magma batches was controlled
by the interplay between magma chamber overpressure and local stress. The intermittent discharge of magma during a large explosive
eruption is unusual for Somma-Vesuvius, as well as for other volcanoes worldwide, and yields new insights for improving our
knowledge of the dynamics of explosive eruptions. 相似文献