Current trends in Great Lakes shipping

Shipping on the Great Lakes has changed rapidly in recent years. Internal Great Lakes traffic consists almost entirely of bulk movements, primarily of iron ore, coal, limestone, and grain. Ore shipments are mainly of taconite concentrate. Low-sulfur coal from the western areas of the United States is now moving downbound through the lakes, a movement in the opposite direction from the predominantly upbound movement of Appalachian coal. Opening of a larger lock in 1970 between lakes Superior and Huron has initiated a new generation of lake vessels, which are three times the size of the previous lake ships, and are too large to transit the Welland Canal and the St. Lawrence Seaway; for the first time since 1959 the largest “lakers” are land-locked. General cargo traffic between the Great Lakes and overseas has been declining rapidly since 1970, largely as the result of the rapid development of container ships, and the Interstate highway system, which increases the competitive advantages of salt-water ports.     

Large-scale galactic turbulence: can self-gravity drive the observed H i velocity dispersions?

Observations of turbulent velocity dispersions in the H  i component of galactic discs show a characteristic floor in galaxies with low star formation rates and within individual galaxies the dispersion profiles decline with radius. We carry out several high-resolution adaptive mesh simulations of gaseous discs embedded within dark matter haloes to explore the roles of cooling, star formation, feedback, shearing motions and baryon fraction in driving turbulent motions. In all simulations the disc slowly cools until gravitational and thermal instabilities give rise to a multiphase medium in which a large population of dense self-gravitating cold clouds are embedded within a warm gaseous phase that forms through shock heating. The diffuse gas is highly turbulent and is an outcome of large-scale driving of global non-axisymmetric modes as well as cloud–cloud tidal interactions and merging. At low star formation rates these processes alone can explain the observed H  i velocity dispersion profiles and the characteristic value of  ∼10 km s⁻¹  observed within a wide range of disc galaxies. Supernovae feedback creates a significant hot gaseous phase and is an important driver of turbulence in galaxies with a star formation rate per unit area  ≳10⁻³ M_⊙ yr⁻¹ kpc⁻²  .     

Evaluating sulfur dynamics during storm events for three watersheds in the northeastern USA: a combined hydrological,chemical and isotopic approach

Concerns related to climate change have resulted in an increasing interest in the importance of hydrological events such as droughts in affecting biogeochemical responses of watersheds. The effects of an unusually dry summer in 2002 had a marked impact on the biogeochemistry of three watersheds in the north‐eastern USA. Chemical, isotopic and hydrological responses with particular emphasis on S dynamics were evaluated for Archer Creek (New York), Sleepers River (Vermont) and Cone Pond (New Hampshire) watersheds. From 1 August to 14 September 2002, all three watersheds had very low precipitation (48 to 69 mm) resulting in either very low or no discharge (mean 0·015, 0·15 and 0·000 mm day^?1 for Archer Creek, Sleepers River and Cone Pond, respectively). From 15 September to 31 October 2002, there was a substantial increase in precipitation totals (212, 246 and 198 mm, respectively) with increased discharge. Archer Creek was characterized by a large range of SO₄^2? concentrations (152 to 389 µeq L^?1, mean = 273 µeq L^?1) and also exhibited the greatest range in δ³⁴S values of SO₄^2? (?1·4 to 8·8 ‰ ). Sleepers River's SO₄^2? concentrations ranged from 136 to 243 µeq L^?1 (mean = 167 µeq L^?1) and δ³⁴S values of SO₄^2? ranged from 4·0 to 9·0 ‰ . Cone Pond's SO₄^2? concentrations (126–187 µeq L^?1, mean = 154 µeq L^?1) and δ³⁴S values (2·4 to 4·3 ‰ ) had the smallest ranges of the three watersheds. The range and mean of δ¹⁸O‐SO₄^2? values for Archer Creek and Cone Pond were similar (3·0 to 8·9 ‰ , mean = 4·5 ‰ ; 3·9 to 6·3 ‰ , mean = 4·9 ‰ ; respectively) while δ¹⁸O‐SO₄^2? values for Sleepers River covered a larger range with a lower mean (1·2 to 10·0 ‰ , mean = 2·5). The difference in Sleepers River chemical and isotopic responses was attributed to weathering reactions contributing SO₄^2?. For Archer Creek wetland areas containing previously reduced S compounds that were reoxidized to SO₄^2? probably provided a substantial source of S. Cone Pond had limited internal S sources and less chemical or isotopic response to storms. Differences among the three watersheds in S biogeochemical responses during these storm events were attributed to differences in S mineral weathering contributions, hydrological pathways and landscape features. Further evaluations of differences and similarities in biogeochemical and hydrological responses among watersheds are needed to predict the impacts of climate change. Copyright © 2008 John Wiley & Sons, Ltd.     

Stratigraphic Model Predictions of Geoacoustic Properties

Geoacoustic properties of the seabed have a controlling role in the propagation and reverberation of sound in shallow-water environments. Several techniques are available to quantify the important properties but are usually unable to adequately sample the region of interest. In this paper, we explore the potential for obtaining geotechnical properties from a process-based stratigraphic model. Grain-size predictions from the stratigraphic model are combined with two acoustic models to estimate sound speed with distance across the New Jersey continental shelf and with depth below the seabed. Model predictions are compared to two independent sets of data: 1) Surficial sound speeds obtained through direct measurement using in situ compressional wave probes, and 2) sound speed as a function of depth obtained through inversion of seabed reflection measurements. In water depths less than 100 m, the model predictions produce a trend of decreasing grain-size and sound speed with increasing water depth as similarly observed in the measured surficial data. In water depths between 100 and 130 m, the model predictions exhibit an increase in sound speed that was not observed in the measured surficial data. A closer comparison indicates that the grain-sizes predicted for the surficial sediments are generally too small producing sound speeds that are too slow. The predicted sound speeds also tend to be too slow for sediments 0.5-20 m below the seabed in water depths greater than 100 m. However, in water depths less than 100 m, the sound speeds between 0.5-20-m subbottom depth are generally too fast. There are several reasons for the discrepancies including the stratigraphic model was limited to two dimensions, the model was unable to simulate biologic processes responsible for the high sound-speed shell material common in the model area, and incomplete geological records necessary to accurately predict grain-size     

The A.D. 79 eruption as a future explosive scenario in the Vesuvian area: evaluation of associated risk

 Due to the lack of an effective policy of planning and prevention, over the past decades the area around Mt. Vesuvio has undergone a steady increase in population and uncontrolled housing development. Consequently, it has become one of the most hazardous volcanic areas in the world. In order to mitigate the damage that the impact of an explosive event would cause in the area, the Department of Civil Defense has worked out an Emergency Management Plan using the A.D. 1631 subplinian eruption as the most probable short-term event. However, from 25 000 years B.P. to present, the activity of the Somma-Vesuvio volcano has shown a sequence of eight eruptive cycles, which always began with a strong plinian eruption. In this paper we utilize the A.D. 79 eruption as an example of a potential large explosive eruption that might occur again at Vesuvio. A detailed tephrostratigraphic analysis of the eruption products was processed by a multivariate statistical analysis. This analysis proved useful for identifying marker layers in the sequences, thus allowing the recognition of some major phases of synchronous deposition and hence the definition of the chronological and spatial evolution of the eruption. By combining this reconstruction with land-use maps, a scenario is proposed with time intervals in the eruptive sequence similar to those reported in Pliny's letter. Thus, it was calculated that, after 7 h from the start of the eruption, a total area of approximately 300 km² would be covered with the eruption products. In the following 11 h, a total area of approximately 500 km² would be involved. The third and last phase of deposition would not cause significant variation in the total area involved, but it would bring about an increase in the thickness of the pyroclastic deposits in the perivolcanic area. Received: 30 November 1996 / Accepted: 29 May 1997     

Soil–pile–structure interaction: experimental outcomes from shaking table tests

An effective way to study the complex seismic soil‐structure interaction phenomena is to investigate the response of physical scaled models in 1‐g or n‐g laboratory devices. The outcomes of an extensive experimental campaign carried out on scaled models by means of the shaking table of the Bristol Laboratory for Advanced Dynamics Engineering, University of Bristol, UK, are discussed in the present paper. The experimental model comprises an oscillator connected to a single or a group of piles embedded in a bi‐layer deposit. Different pile head conditions, that is free head and fixed head, several dynamic properties of the structure, including different masses at the top of the single degree of freedom system, excited by various input motions, e.g. white noise, sinedwells and natural earthquake strong motions recorded in Italy, have been tested. In the present work, the modal dynamic response of the soil–pile–structure system is assessed in terms of period elongation and system damping ratio. Furthermore, the effects of oscillator mass and pile head conditions on soil–pile response have been highlighted, when the harmonic input motions are considered. Copyright © 2015 John Wiley & Sons, Ltd.     

Organic matter in small mesopores in sediments and soils

The three-way correlation among organic matter concentrations, specific surface area and small mesopores observed for many soils and sediments led to the hypothesis that enclosure within the pores might explain the apparent protection of organic matter by minerals. We test this hypothesis by examining whether the bulk of organic matter resides within small mesopores. Pore volumes as a function of pore width were measured before and after organic matter removal, and the volume differences ascribed to organic matter filling of pores. Minor changes in small mesopore size distributions upon treatments such as centrifugation and muffling indicate the robustness of the mineral matrices that form these pores. We developed an additional method to assess organic matter densities using high-resolution pycnometry, and used these densities to convert pore volumes to organic matter contents. Although smaller mesopores are shown to have sufficient volumes to contain significant fractions of the total organic matter, only small fractions of total organic matter were found to reside in them. These results are consistent with preferential association between organic matter and aluminous clay particle edges, rather than the largely siliceous clay faces that contribute most surface area and form pore walls. While simple enclosure within smaller mesopores cannot, therefore, explain protection, network effects working at larger size scales may account for exclusion of digestive agents and hence organic matter protection.     

Zur statistischen Mechanik der Lufthülle der Erde

Zusammenfassung Es wird versucht, die Methoden der statistischen Mechanik auf die statistische Behandlung der kontinuierlichen Mannigfaltigkeit der Erdatmosphäre zu übertragen. Dazu ist es notwendig, daß die hydrodynamischen Bewegungsgleichungen auf eine Hamiltonsche Form gebracht werden. In Analogie zur statistischen Mechanik wird ein Gibbsscher Ansatz einer kanonischen Gesamtheit gemacht, in den die Energiefunktion, die die Atmosphäre als Ganzes beschreibt, eingeht. Mit diesem Ansatz wird die Wahrscheinlichkeit angegeben, daß ein bestimmter Zustand der Atmosphäre, der als Phasenpunkt in einem Phasenraum aufgefaßt wird, in einem Volumelement dieses Phasenraumes anzutreffen ist. Diese Ausgangswahrscheinlichkeit gestattet es, in einem Anwendungsbeispiel eine Verbindung zwischen der mittleren geometrischen Temperaturzustandskurve und der Verteilung der Gesamtmasse der Atmosphäre auf die verschiedenen Dichtewerte herzustellen.

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Summary An attempt is made to apply methods of statistical mechanics to the continuous diversity of the terrestrial atmosphere. To this purpose the hydrodynamic equations of motion must be expressed in Hamiltonian form. In analogy to statistical mechanics a Gibbs arrangement of a canonical totality is set up involving the energy-function by which the atmosphere is described as a whole. By this arrangement the probability is given that a certain state of the atmosphere considered as phase point in a phase space exists in a volume-element of this phase space. This initial probability makes it possible to establish, in a practical example, a relation between the average geometrical curve of temperature state and the distribution of the whole mass of the atmosphere over the different density values.

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Résumé On tente d'appliquer les méthodes de la mécanique statistique au traitement statistique de la diversité continue de l'atmosphère terrestre. Il est nécessaire pour cela de ramener les équations hydrodynamiques du mouvement aux formes de Hamilton. Par analogie à la mécanique statistique on établit un théorème de Gibbs concernant un ensemble canonique et dans lequel s'insère la fonction d'énergie décrivant l'atmosphère dans son ensemble. Ce théorème fournit la probabilité qu'un état détermié de l'amtosphère considéré comme point de phase dans un espace de phase est rencontré dans un élément de volume de cet espace. Cette probabilité initiale permet, dans un exemple concret, d'établir une relation entre la courbe géométrique moyenne d'état de température et la distribution de la masse totale de l'atmosphère selon les différentes valeurs de la densité.