COCORP: new perspectives on the deep crust

Summary. Relict sutures from colliding continents, regions characterized by a "young" Mono, layering and faulting throughout the crust, mid-crustal magma traps, and seismic "bright spots" which suggest deep crustal fluids are among recent COCORP findings. In addition, new studies of signal penetration, noise mitigation, recording geometry, and coherency filtering have yielded better understanding of, and substantial improvements in, data quality. Amplitude anomalies, or "bright spots", in the Basin and Range may be due to magma at mid-crustal levels; in one case, a normal fault appears to link the deep magma with young surface volcanics. Another bright spot. 15 km deep in southeastern Georgia, has a flat geometry that suggests a gas/liquid interface, perhaps within fluids underthrust along an Appalachian suture. The Mono continues to appear relatively undisturbed in many regions of past deformation, suggesting that its formation post-dates these major tectonic episodes. The diversity of reflection patterns from the U.S. Cordillera casts further doubt on the generality of the common model of a reflective, layered lower crust underlying a transparent upper crust.     

MEDICAL GEOGRAPHY: SOME UNSOLVED PROBLEMS

Because medical geography is a dynamic and developing area of thought, a number of conceptual and empirical problems are, as yet, relatively unexplored. This essay constitutes an attempt to delimit these problems, which include the application of geographical analysis to ascertaining disease causation, the prediction of future disease patterns and disease diffusion, and evaluation of the importance of maximizing geographical access to health care facilities.     

Mantle derived crystal-poor rhyolitic ignimbrites: Eruptive mechanism from geochemical and geochronological data of the Piedra Parada caldera,Southern Argentina

Trace elements, isotopic modeling and U-Th-Pb SHRIMP zircon age constraints are used to reconstruct the eruption history and magmatic processes of the Piedra Parada Caldera. In the early Eocene, the crystal-poor Barda Colorada ignimbrite(BCI), having 15% micro-porphyritic crystals with respect to magmatic components, erupted a volume estimated in more than 300 km~3. The Piedra Parada caldera is located in the Patagonian Andes foreland, at the southern end of the calderas field of the Pilcaniyeu Volcanic Belt(PVB). This belt is related to an extensional tectonic setting as a result of the collision of the Farallon-Aluk ridge with South America, which enabled the development of a transform ocean/continental plate margin followed by the detachment of the Aluk plate and the opening of a slab window. The BCI extra-caldera Plateau is a 100 m thick deposit, having a lower unit with high silica(Si O_2 76 wt.%),potassium poor rhyolitic composition(trondhjemitic like magma), and an upper unit with normal to high potassium rhyolitic composition(granitic like magma). A trace elements modeling of the BCI units shows that the BCI lower and upper units did not evolve from fractionation or immiscibility in the shallow magma reservoir. The BCI also have a primitive isotopic signature(initial87 Sr/86 Sr =0.7031-0.7049 and ε_(Nd)= +3.4 to +3.65). Thus, tectonic, compositional and isotopic constraints suggest the fast ascent of high silica magmas to a shallow reservoir, and point to an upper mantle origin for these rhyolitic magmas in a transitional(Orogenic-Anorogenic) tectono-magmatic setting. U-Th-Pb SHRIMP zircon crystallization ages of the Syn-caldera stage BCI units(56 -51.5 Ma) show a protracted life of 5 Ma for this caldera reservoir. The age of 52.9 ± 0.3 Ma is considered the best fit for the possible maximum age for the caldera collapse. The Late-caldera magmatism has trachyandesitic and rhyolitic compositions.The trace element modeling suggests that these rhyolites evolve from the trachyandesites and do not evolve from the BCI residual magma. The trachyandesites have U-Th-Pb SHRIMP zircon crystallization ages of 52 ± 1 Ma, suggesting that the caldera eruption was triggered by the arrival of the trachyandesitic magma.     

Integration of a limit-equilibrium model into a landslide early warning system

Landslides are a significant hazard in many parts of the world and exhibit a high, and often underestimated, damage potential. Deploying landslide early warning systems is one risk management strategy that, amongst others, can be used to protect local communities. In geotechnical applications, slope stability models play an important role in predicting slope behaviour as a result of external influences; however, they are only rarely incorporated into landslide early warning systems. In this study, the physically based slope stability model CHASM (Combined Hydrology and Stability Model) was initially applied to a reactivated landslide in the Swabian Alb to assess stability conditions and was subsequently integrated into a prototype of a semi-automated landslide early warning system. The results of the CHASM application demonstrate that for several potential shear surfaces the Factor of Safety is relatively low, and subsequent rainfall events could cause instability. To integrate and automate CHASM within an early warning system, international geospatial standards were employed to ensure the interoperability of system components and the transferability of the implemented system as a whole. The CHASM algorithm is automatically run as a web processing service, utilising fixed, predetermined input data, and variable input data including hydrological monitoring data and quantitative rainfall forecasts. Once pre-defined modelling or monitoring thresholds are exceeded, a web notification service distributes SMS and email messages to relevant experts, who then determine whether to issue an early warning to local and regional stakeholders, as well as providing appropriate action advice. This study successfully demonstrated the potential of this new approach to landslide early warning. To move from demonstration to active issuance of early warnings demands the future acquisition of high-quality data on mechanical properties and distributed pore water pressure regimes.     

Ground motion amplification due to shallow cavities in nonlinear soils

Subsurface cavities or stiff inclusions represent mechanical discontinuities for seismic waves propagating in soils. They modify the propagation pattern of seismic waves and alter soil response in correspondence to the ground level or building foundations. In the literature, different analytical and numerical solutions have been proposed to account for the effect of underground cavities or inclusions on the motion generated by P, S or R waves. In these former studies, the subsoil was assimilated to a homogeneous, isotropic and linear elastic halfspace containing one or more cavities. In the present study, the effect of subsurface cavities on ground motion amplification has been analysed accounting for soil stiffness degradation and associated damping increase with increasing levels of shear strains, a fundamental aspect of soil behaviour under earthquakes. The analysed model was inspired to a real case represented by the village of Castelnuovo (Italy), which during the 2009 Abruzzo earthquake suffered huge damage. The main shock (6 April 2009) caused the collapse of 50 % of the whole built environment. The historical centre of Castelnuovo rises on a hill. In its subsoil, there are many cavities with roofs 2–3 m below the ground level. The longitudinal NW–SE section of the hill has been investigated by 2D nonlinear site response analyses. A preliminary site response analysis was performed without modelling cavities, to identify ground motion amplification due to mere stratigraphic and topographic factors. The numerical model was later refined inserting: (1) a single cavity below the hilltop, (2) multiple cavities placed below the ground surface of the hill and (3) multiple cavities filled with concrete (inclusions). The performed study highlights the important role exerted by underground cavities on the ground motion computed at the hill surface. This effect should be properly considered for both microzonation studies and the correct determination of the seismic actions on specific buildings.     

Microcrystals of Th-rich monazite (La) with a negative Ce anomaly in metadiorite and their role for documenting Cretaceous metamorphism in the Slavonian Mountains (Croatia)

Microcrystals (1–15 μm) of unusual monazite (La) with 41–47 mol% cheralite [ThCa(PO₄)₂] component and a strong negative Ce anomaly are described from a metadiorite from the SW Slavonian Mountains, Psunj, Croatia. The dioritic host rock still shows a relictic igneous fabric on macroscopic scale. However, metamorphic reaction textures can be recognized in thin section. These include partial recrystallization of igneous plagioclase to albite coupled with the formation of epidote. Furthermore, partial replacement of igneous hornblende by a fine-grained orthoamphibole-chamosite-epidote paragenesis can be observed and replacement of ilmenite by titanite. The compositions of the metamorphic minerals indicate upper greenschist facies conditions (460–500 °C according to two-feldspar geothermometry) under a high oxygen fugacity. Microstructures show that the monazite crystals belong to the metamorphic paragenesis and formed at the expense of magmatic allanite. Their negative Ce anomalies reflect the oxidizing conditions of metamorphism. Application of the xenotime in monazite solvus geothermometer provides unrealistically high temperatures of ~500–660 °C which disagree with the greenschist facies metamorphic paragenesis. We interpret that the presence of cheralite has a profound effect on the nature of the monazite-xenotime solvus curve and hence the existing calibrations of this geothermometer may be generally unsuitable for cheralite-rich monazite. An important geological result is that the Th-U-total Pb ages of the monazite grains are uniformingly Upper Cretaceous. Our data thus suggest that the imprint of the Alpine orogeny on the Slavonian Mountains was stronger than presumed until now.     

http://www.sciencedirect.com/science/article/pii/S1674987112001533

The collision of a divergent ocean ridge may evolve into two end cases:in the continuity of ocean-floor subduction.or in the detachment of the subducted plate.The northern Patagonia active plate margin has the unique situation that in Cenozoic time it has been subjected to two divergent ridge collisions,each one representing one of the end members.The Neogene Antarctica-Nazca divergent ridge collision evolved as a continuous ocean-floor subduction system,promoting a magmatic hiatus at the arc axis,the obduction of part of the ridge ocean-floor in the fore-arc.and basaltic volcanism in the back-arc.In contrast,the Paleogene Farallon-Aluk divergent ridge collision evolved into a transform margin,with the detachment and sinking of the Aluk plate and the development of a large slab window.As in the previous case,this collision promoted a magmatic hiatus at the arc axis,but the tectono-magmatic scenario changed to postorogenic synextensional volcanism that spread to the former fore-arc（basalt,andesite,rhyolite） and former back-arc（bimodal ignimbrite flare-up,basalt）.Geochemistry of this slab window synextensional volcanism shows more MORB-like basalts towards the former fore-arc,and MORB-OIB-like basalts towards the former back-arc.Instead,an isolated undeformable crustal block in the former back-arc,with an "epeirogenic" response to the slab window and extensional regime,was covered by OIB-type basalts after uplift.Major elements show that slab window basalts reach TiCh values up to 3 wt%,as compared with the top value of 1.5 wt%of arc magmas.Besides,the MgO with respect to（FeO^t + Al₂O₃） ratio helps to distinguish slab window magma changes from the former fore-arc to the former back-arc and also with respect to the "epeirogenic" block.Higher contents of HFS elements such as Nb and Ta also help to distinguish this slab window from arc magmas and also,to distinguish slab window magma changes from the former fore-arc to the former back-arc and "epeirogenic" block settings.The isotope compositions of slab window magmatism show a disparate coeval array from MORB to crustal sources,interpreted as a consequence of the lack of protracted storage and homogenization due to the extensional setting.     

Mass Flux Analysis of Abiotic Tetrachloroethene Dense Nonaqueous Phase Liquid Pool Dissolution in a Heterogeneous Flow Environment

Porous aquifer materials are often characterized by layered heterogeneities that influence groundwater flow and present complexities in contaminant transport modeling. Such flow variations also have the potential to impact the dissolution flux from dense nonaqueous phase liquid (DNAPL) pools. This study examined how these heterogeneous flow conditions affected the dissolution of a tetrachloroethene (PCE) pool in a two-dimensional intermediate-scale flow cell containing coarse sand. A steady-state mass-balance approach was used to calculate the PCE dissolution rate at three different flow rates. As expected, aqueous PCE concentrations increased along the length of the PCE pool and higher flow rates decreased the aqueous PCE concentration in the effluent. Nonreactive tracer studies at two flow rates confirmed the presence of a vertical flow gradient, with the most rapid velocity located at the bottom of the tank. These results suggest that flow focusing occurred near the DNAPL pool. Effluent PCE concentrations and pool dissolution flux rates were compared to model predictions assuming local equilibrium (LE) conditions at the DNAPL pool/aqueous phase interface and a uniform distribution of flow. The LE model did not describe the data well, even over a wide range of PCE solubility and macroscopic transverse dispersivity values. Model predictions assuming nonequilibrium mass-transfer-limited conditions and accounting for vertical flow gradients, however, resulted in a better fit to the data. These results have important implications for evaluating DNAPL pool dissolution in the field where subsurface heterogeneities are likely to be present.     

Attribution of uranium ore concentrates using elemental and anionic data

The capability to correctly identify the geological or geographical source of unknown uranium ore concentrates (UOCs) has obvious nuclear security benefits. This paper reports on a scoping study where the trace elemental and anionic compositions of 24 UOC samples, sourced mainly from mines in Australia and Canada, were examined for their ability to allow attribution of the sample to a particular geological U deposit type or to a particular geographical source. Results of statistical analysis using canonical analysis of principal coordinates (CAP) showed that samples originating from certain U ore deposit types, especially phosphorite and quartz-pebble conglomerate, contained a distinct impurity composition. Samples grouped according to their geographical region of origin appeared to contain distinctive impurities in certain cases (Elliot Lake and Bancroft, Ontario). The key impurities responsible for differentiating groups of samples from a particular geological deposit type were identified and the use of certain impurities as signatures of processing history is discussed. The methodology described in this scoping study provides a promising approach for more comprehensive databases.     

Magmatism and fenitization in the Cretaceous potassium-alkaline-carbonatitic complex of Ipanema S?o Paulo State, Brazil

The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks (⁸⁷Sr/⁸⁶Sr?=?0.70661–0.70754 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51169–0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks.