A new versatile constitutive law for modelling the monotonic response of soft rocks and structured fine-grained soils

This paper deals with a new critical state–based constitutive model for soft rocks and fine-grained soils. The model, formulated in the single-surface plasticity framework, is characterised by the following main features: (i) a generalised three-invariant yield surface capable of reproducing a wide set of well-known criteria, (ii) the dependency of the elastic stiffness on the current stress state by means of a hyperelastic formulation, (iii) the ability of simulating the plastic strain–driven structure degradation processes by a set of appropriate isotropic hardening laws, and (iv) a nonassociate flow rule in the meridian plane. The adopted formulation is hierarchical, such that the various features of the model can be activated or excluded depending on the specific kind of geomaterial to be modelled and on the quality and quantity of the related available experimental results. The constitutive model was implemented in a commercial finite element code by means of an explicit modified Euler scheme with automatic substepping and error control. The procedure does not require any form of stress correction to prevent drift from the yield surface. The performance of the model is first analysed by means of a wide set of parametric analyses, in order to highlight the main features and to evaluate the sensitivity of the formulation with reference to the input parameters. The model is then adopted to simulate the experimental response observed on three different geomaterials, ranging from soft clays to soft rocks.     

Thermal springs,fumaroles and gas vents of continental Yemen: Their relation with active tectonics,regional hydrology and the country’s geothermal potential

Most thermal springs of continental Yemen (about 65 emergences at 48 sampling sites) and a couple of fumaroles and boiling water pools have been sampled and analyzed for chemical and isotopic composition in the liquid phase and the associated free-gas phase. Whatever the emergence, all the water discharges have an isotopic signature of meteoric origin. Springs seeping out from high altitudes in the central volcanic plateau show a prevalent Na–HCO₃-composition, clearly affected by an anomalous flux of deep CO₂ deriving from active hydrothermal systems located in the Jurassic Amran Group limestone sequence and/or the Cretaceous Tawilah Group, likely underlying the 2000–3000 m thick volcanic suite. At lower elevations, CO₂ also affects the composition of some springs emerging at the borders of the central volcanic plateau.     

The macrozoobenthos of the Karavasta lagoon system (Albania): local assemblages and geographical comparisons

The macrozoobenthic assemblage from the Karavasta lagoon system, the main wetland of Albania, was studied on soft bottoms and artificial hard substrates. Three different communities were identified: the typical ‘brackish‐water community’, an ‘outlet community’ dominated by filter‐feeders, and a typical ‘marine community’, inhabiting fine sandy bottoms, where polychaetes are dominant, together with a few species of tunicates and bivalves, which colonize hard substrates. The occurrence of build‐ups of the bryozoan Conopeum seurati, settled on the upper portion of long submerged wooden poles, was the main feature of faunistic interest. The faunistic affinity between the zoobenthic assemblage recorded in the hyperhaline lagoon of Karavasta and the assemblages from two Italian lagoons, the brackish Lake of Lesina and the euhaline Lake of Fogliano, was considered according to the different hydrological conditions and the geographical location. Hydrological confinement and salinity were likely to be the leading factors influencing the benthic community composition in the Karavasta wetland area. Therefore, on a vaster spatial scale, the isolation and geographical proximity of the ecosystems and colonizing ability and dispersal changes of the species appear to be the main factors liable to produce faunal variations.     

Soft X-ray spectroscopy of Compton-thick Seyfert 2 galaxies with BeppoSAX

We present an X-ray spectroscopic study of the bright Compton-thick Seyfert 2 galaxies NGC 1068 and the Circinus Galaxy, performed with BeppoSAX . Matt et al. interpreted the spectrum above 4 keV as the superposition of Compton reflection and warm plasma scattering of the nuclear radiation. When this continuum is extrapolated downwards to 0.1 keV, further components arise. The NGC 1068 spectrum is rich in emission lines, mainly owing to K _α transitions of He-like elements from oxygen to iron, plus a K _α fluorescent line from neutral iron. If the ionized lines originate in the warm scatterer, its thermal and ionization structure must be complex. From the continuum and line properties, we estimate a column density, N _warm, of the warm scatterer less than a few×10²¹ cm⁻². In the Circinus Galaxy, the absence of highly ionized iron is consistent with a scattering medium with U _X≲5 and N _warm∼ a few×10²² cm⁻². In both cases the neutral iron line is most naturally explained as fluorescence in the medium responsible for the Compton reflection continuum. In NGC 1068 an optically thin plasma emission with kT ≃500 eV and strongly sub-solar metallicity is required, while such a component is only marginal in the Circinus Galaxy. We tentatively identify this component as emission of diffuse hot gas in the nuclear starbursts. Possible causes for the metal depletion are discussed.     

Evolution and depositional environments of the Eberswalde fan delta, Mars

The Eberswalde crater and its contributing basins have been analyzed in detail in order to reconstruct the geological evolution of the water-related landforms with particular focus on the Eberswalde delta-like feature. Based on a complex strata organization characterized by a topset-foreset-bottomset geometry, typical of delta progradation on Earth, we interpret the Eberswalde feature to be a fan delta associated with a lacustrine system. Depositional sub-environments have been recognized and mapped and the sedimentary processes discussed. A sequence stratigraphy approach has been used to evaluate the system, which we interpret to result from three depositional sequences. These sequences suggest relative water level fluctuations and a longer trend over time towards decreasing water content inside the basin.     

A unified framework for earthquake risk assessment of transportation networks and gross regional product

Natural threats like earthquakes, hurricanes or tsunamis have had serious impacts on communities. In the past, major earthquakes in the United States like Loma Prieta 1989, Northridge 1994, or recent events in Italy like L’Aquila 2009 or Emilia 2012 emphasized the importance of preparedness and awareness to reduce social impacts. In addition to that, earthquake damaged businesses dramatically reduced the gross regional product. Generating scenario earthquakes in a proper way is important to suitably assess the risk in bridge networks and social losses in terms of gross regional product reduction. Seismic hazard is traditionally assessed by means of probabilistic seismic hazard analysis (PSHA). Although PSHA well represents the hazard at a specific location it is not suitable for spatially distributed systems. Scenario earthquakes can overcome this problem; they represent the actual distribution of ground shaking for a spatially distributed system while being hazard consistent. In this work a methodology to generate scenario earthquakes has been proposed using a novel approach with the aim of being the basic step for investigating possible earthquake consequences in seismic areas and contributing to reduce losses.     

Speleogenesis of an exhumed hydrothermal sulphuric acid karst in Cambrian carbonates (Mount San Giovanni,Sardinia)

In the past few years the systematic study of caves intercepted by mine workings in southwest Sardinia has permitted us to observe morphologies due to rare speleogenetic and minerogenetic processes related to ancient hydrothermal activity. These relic morphologies are slowly being overprinted by recent speleogenetic processes that tend to obscure the hypogene origin of these caves. A combined geomorphological and mineralogical investigation has permitted a fairly detailed reconstruction of the various phases of evolution of these caves. Cave formation had already started in Cambrian times, but culminated in the Carboniferous, when most of the large voids still accessible today were formed. A key role in carbonate dissolution was played by sulphuric acid formed by the oxidation of the polymetallic ores present in the rocks since the Cambrian. During the Quaternary a variety of minerals formed inside the caves: calcite and aragonite, that yielded sequences of palaeo‐environmental interest, and also barite, phosgenite, hydrozincite, hemimorphite and many others. These minerals are in part due to a phreatic thermal hypogenic cave forming phase, and in part to later epigene overprinting in an oxidizing environment rich in polymetallic ores. Massive gypsum deposits, elsewhere typical of this kind of caves, are entirely absent due to dissolution during both the phreatic cave formation and the later epigenic stage. Copyright © 2013 John Wiley & Sons, Ltd.     

Source ambiguity from an estimation of the scaling exponent of potential field power spectra

An analysis of the field scaling power spectrum yields useful information about the source distribution, but it is uncertain whether deterministic, random, fractal or mixed approaches have to be used for the interpretation. To this end, the scaling properties of potential field spectra are analysed for a number of different source models of geological interest. Besides the models of Naidu (purely random sources) and Spector and Grant (gross block statistical ensembles) we consider other types of density and magnetization distributions with spectral exponents in the fractal range, such as a single homogeneous body with a random white source distribution. Spectral slopes in the fractal range are obtained.
We also study the effects of important natural sources, such as salt domes and sedimentary basins, representing them with simple Gaussians or combinations of Gaussian signals. The same spectral slopes as for gravity signals generated by 3-D fractal source distributions are found for them. Hence the power law decay of the field is not a characteristic only of fractal source models.
If a 3-D fractal source distribution is assumed a priori , a way of verifying the goodness of the model is to examine the whitened field at source level. The probability that the whitened field derives from a random white population is estimated for synthetic and real anomalies by applying the usual statistical tests.     

Mantle derived crystal-poor rhyolitic ignimbrites: Eruptive mechanism from geochemical and geochronological data of the Piedra Parada caldera,Southern Argentina

Trace elements, isotopic modeling and U-Th-Pb SHRIMP zircon age constraints are used to reconstruct the eruption history and magmatic processes of the Piedra Parada Caldera. In the early Eocene, the crystal-poor Barda Colorada ignimbrite(BCI), having 15% micro-porphyritic crystals with respect to magmatic components, erupted a volume estimated in more than 300 km~3. The Piedra Parada caldera is located in the Patagonian Andes foreland, at the southern end of the calderas field of the Pilcaniyeu Volcanic Belt(PVB). This belt is related to an extensional tectonic setting as a result of the collision of the Farallon-Aluk ridge with South America, which enabled the development of a transform ocean/continental plate margin followed by the detachment of the Aluk plate and the opening of a slab window. The BCI extra-caldera Plateau is a 100 m thick deposit, having a lower unit with high silica(Si O_2 76 wt.%),potassium poor rhyolitic composition(trondhjemitic like magma), and an upper unit with normal to high potassium rhyolitic composition(granitic like magma). A trace elements modeling of the BCI units shows that the BCI lower and upper units did not evolve from fractionation or immiscibility in the shallow magma reservoir. The BCI also have a primitive isotopic signature(initial87 Sr/86 Sr =0.7031-0.7049 and ε_(Nd)= +3.4 to +3.65). Thus, tectonic, compositional and isotopic constraints suggest the fast ascent of high silica magmas to a shallow reservoir, and point to an upper mantle origin for these rhyolitic magmas in a transitional(Orogenic-Anorogenic) tectono-magmatic setting. U-Th-Pb SHRIMP zircon crystallization ages of the Syn-caldera stage BCI units(56 -51.5 Ma) show a protracted life of 5 Ma for this caldera reservoir. The age of 52.9 ± 0.3 Ma is considered the best fit for the possible maximum age for the caldera collapse. The Late-caldera magmatism has trachyandesitic and rhyolitic compositions.The trace element modeling suggests that these rhyolites evolve from the trachyandesites and do not evolve from the BCI residual magma. The trachyandesites have U-Th-Pb SHRIMP zircon crystallization ages of 52 ± 1 Ma, suggesting that the caldera eruption was triggered by the arrival of the trachyandesitic magma.     

Temporal Changes in Seawater Carbonate Chemistry and Carbon Export from a Southern California Estuary

Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (F_DIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?10³ to 9.5±0.7?×?10³?mol C h^?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?10⁶?mol C year^?1. Following a major rain event (36 mm rain in 3 days), F_DIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?10³?mol C h^?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?10⁶?mol C year^?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small.