PCBs and PAHs in surficial sediments from aquatic environments of Mexico City and the coastal states of Sonora,Sinaloa, Oaxaca and Veracruz (Mexico)

Concentrations of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were measured in 13 surficial sediment samples collected at three lacustrine locations in the surroundings of Mexico City and four coastal areas of the States of Sinaloa, Sonora, Oaxaca and Veracruz. Total PCB concentrations span the interval 3.18–621 ng g⁻¹. The highest values (63.7–621 ng g⁻¹) were found in Mexico City, which is a highly anthropogenically impacted area, whereas low concentrations (3.18–12.9 ng g⁻¹) were characteristic of seven places, some of them subject to intense hydrodynamics. In these latter cases, values increase by 18–73 times if normalised against the fine fraction (silt plus clay) content in sediment. Two samples from Mexico City exceed the ERM (Effect Range Median) guidelines and are likely to cause adverse effects. Samples contain only lower chlorinated PCBs (mainly 2-, 3- and 4-CB), thus suggesting that the most used PCB commercial mixture was Aroclor 1242. The homologue composition of the sample taken close to the nuclear power plant of Laguna Verde is identical to this commercial mixture. PAHs in the same samples have relatively low concentrations (14.9–287 ng g⁻¹), well below ERL (Effect Range Low) guidelines. The composition of PAH mixtures accounts for the influence of both petrogenic and pyrolitic sources, with these latter prevailing at some places in Mexico City.     

Early detection of volcanic hazard by lidar measurement of carbon dioxide

Volcanic gases give information on magmatic processes. In particular, anomalous releases of carbon dioxide precede volcanic eruptions. Up to now, this gas has been measured in volcanic plumes with conventional measurements that imply the severe risks of local sampling and can last many hours. For these reasons and for the great advantages of laser sensing, the thorough development of volcanic lidars has been undertaken at ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). In fact, lidar profiling allows one to scan remotely volcanic plumes in a fast and continuous way, and with high spatial and temporal resolution. A differential absorption lidar instrument will be presented in this paper: BILLI (BrIdge voLcanic LIdar). It is based on injection-seeded Nd:YAG laser, double-grating dye laser, difference frequency mixing and optical parametric amplifier. BILLI is funded by the ERC (European Research Council) project BRIDGE (BRIDging the gap between Gas Emissions and geophysical observations at active volcanos). It scanned the gas emitted by Pozzuoli Solfatara (Naples, Italy) and Stromboli Volcano (Sicily, Italy) during field campaigns carried out from October 13 to 17, 2014, and from June 24 to 29, 2015, respectively. Carbon dioxide concentration maps were retrieved remotely in few minutes in the crater areas. To our knowledge, it is the first time that carbon dioxide in a volcanic plume is retrieved by lidar. This result represents the first direct measurement of this kind ever performed on active volcanos and shows the high potential of laser remote sensing in early detection of volcanic hazard.     

Livelihoods, fire and policy in eastern Indonesia

Indonesian legislation calls for a zero-burning policy. This approach to fire management is largely in response to significant negative impacts on the economy and the environment, not only in Indonesia but also the neighbouring region, that result annually from peat fires in Kalimantan and Sumatra. In this context, the present paper investigates the local use and management of fire in Flores and Sumba islands in eastern Indonesia. Our appraisals show that people's livelihoods depend on fire to maintain grasslands and, therefore, that the national policy and legislation for zero-burning is inappropriate and needs to be revised. This follows from the fact that not all fires cause damage and are unwanted. Through a series of rapid rural appraisal interviews, we found that the fires in grasslands are often lit intentionally to maintain the grasslands that local people use to sustain a variety of livelihood activities such as cattle rearing, hunting and farming. Although fires can damage or destroy remnant dry forests in eastern Indonesia, in order to be effective, future policy formulations need to account for this human livelihood dimension and the geographic variation in fuels, climate and land use.     

Territorial disparities, natural resource distribution, and land degradation: a case study in southern Europe

The aim of this paper is to analyse the territorial disparities in some socio-economic and environmental factors involved in land degradation (LD) processes in a dry Mediterranean region. A simplified framework in which ecological and economic factors may increase inequality in natural resource distribution along the elevation gradient and accelerate LD is illustrated. To test at a local scale if territorial disparities observed in such factors have increased in the last period, we studied changes in LD sensitivity over thirty years in Latium, central Italy, a region prone to soil degradation phenomena. An estimate of LD sensitivity at the municipality level was obtained through a synthetic index (ISD) composed by three partial indicators analysing respectively climate and soil conditions (CLI), land use characteristics (LAN), and human pressure (POP). ISD and the three partial indicators were computed separately for 1970 and 2000. The divergence in LD sensitivity among coastal and inland areas significantly increased over the study period. In the former zones, median ISD increased with a reduction in score variability among municipalities; the reverse pattern was observed in the latter zones. Differences in ISD score among the elevation gradient are especially due to human factors affecting land use changes and agriculture intensification. New findings to be achieved in the context of human impacts on the environment as an original contribution to the study of LD at a local scale were finally delineated.     

The architecture of an incipient oceanic basin: a tentative reconstruction of the Jurassic Liguria-Piemonte basin along the Northern Apennines–Alpine Corsica transect

In this paper, a scenario for the early evolution of the Jurassic oceanic Liguria-Piemonte basin is sketched. For this purpose, four selected examples of ophiolite sequences from the Northern Apennines and Corsica are described and analyzed. In the External Ligurian units (Northern Apennines), the ocean–continent transition of the Adria plate was characterized by a basement made up of subcontinental mantle and lower continental crust, covered by extensional allochthons of upper crust. Both, the basement rocks and the extensional allochthons are cut by basaltic dikes and covered by basalts and pelagic deposits. The conjugate ocean–continent transition of the Corsica margin, represented by the Balagne nappe (Corsica), was composed of mantle peridotites and gabbros covered by basaltic flows and minor breccias, that in addition include continent-derived clasts. By contrast, the innermost (i.e., closest to the ocean) preserved area observed in the Internal Ligurian (Northern Apennines) and Inzecca (Corsica) units consists of former morphological highs of mantle peridotites and gabbros, bordered by small basins where the basement is covered by a volcano-sedimentary complex, characterized by ophiolitic breccias and cherts interlayered with basaltic flows. The overall picture resulting from our reconstructions suggests an asymmetric architecture for the Liguria-Piemonte basin with a central area bounded by two different transition zones toward the continental margins. This architecture can be interpreted as the result of a rifting process whose development includes a final stage characterized by passive, asymmetric extension of the lithosphere along an east-dipping detachment fault system.