A new graphical user interface (GUI) for pre-processing reflectance spectra, built using MATLAB and expressly designed for the ASD FieldSpec® spectroradiometer, was developed to solve problems that generally affect experimental ASD data. The GUI is characterised by an easily readable, graphic visualisation of spectra, from which the absorption band depth (ABD) can be obtained for a selected wavelength. The output format of the ASD data is a binary file with an .asd extension. The binary file, that provides a single spectrum, can be processed using a software functionality, by means of a GUI, that allows to select one or more binary files to produce a spectral library in a unique .txt file. The spectral reflectance is re-calibrated with the “convex-hull” methodology to eliminate the convex shape, which is typical of reflectance spectra. Different examples of the use of the new GUI are provided. 相似文献
We performed thermodynamic calculations based on model and natural peridotitic compositions at pressure and temperature conditions relevant to the Earth’s upper mantle, using well-established free energy minimization techniques. The model is consistent with the available experimental data in Cr-bearing peridotitic systems and can therefore be used to predict phase relations and mineral compositions in a wide range of realistic mantle compositions. The generated phase diagrams for six different bulk compositions, representative of fertile, depleted and ultra-depleted peridotitic mantle, shown that the garnet + spinel stability field is always broad at low temperatures and progressively narrows with increasing temperatures. In lithospheric sections with hot geotherms (ca. 60 mW/m2), garnet coexists with spinel across an interval of 10–15 km, at ca. 50–70 km depths. In colder, cratonic, lithospheric sections (e.g. along a 40 mW/m2 geotherm), the width of the garnet–spinel transition strongly depends on bulk composition: In fertile mantle, spinel can coexist with garnet to about 120 km depth, while in an ultra-depleted harzburgitic mantle, it can be stable to over 180 km depth. The formation of chromian spinel inclusions in diamonds is restricted to pressures between 4.0 and 6.0 GPa. The modes of spinel decrease rapidly to less than 1 vol % when it coexists with garnet; hence, spinel grains can be easily overlooked during the petrographical characterization of small mantle xenoliths. The very Cr-rich nature of many spinels from xenoliths and diamonds from cratonic settings may be simply a consequence of their low modes in high-pressure assemblages; thus, their composition does not necessarily imply an extremely refractory composition of the source rock. The model also shows that large Ca and Cr variations in lherzolitic garnets in equilibrium with spinel can be explained by variations of pressure and temperature along a continental geotherm and do not necessarily imply variations of bulk composition. The slope of the Cr# [i.e. Cr/(Cr + Al)mol] isopleths in garnet in equilibrium with spinel changes significantly at high temperatures, posing serious limitations to the applicability of empirical geobarometric methods calibrated on cratonic mantle xenoliths in hotter, off-craton, lithospheric mantle sections. 相似文献
The importance of riparian tree cover in reducing energy inputs to streams is increasingly recognized in schemes to mitigate climate change effects and protect freshwater ecosystems. Assessing different riparian management strategies requires catchment‐scale understanding of how different planting scenarios would affect the stream energy balance, coupled with a quantitative assessment of spatial patterns of streamflow generation. Here, we use the physically based MIKE SHE model to integrate simulations of catchment‐scale run‐off generation and in‐stream hydraulics with a heat transfer model. This was calibrated to model the spatio‐temporal distribution of hourly stream water temperature during warm low flow periods in a Scottish salmon stream. The model was explored as a “proof of concept” for a tool to investigate the effects of riparian management on high stream water temperatures that could affect juvenile Atlantic salmon. Uncertainty was incorporated into the assessment using the generalized likelihood uncertainty estimation approach. Results showed that by decreasing both the warming (daylight hours) and the cooling (night‐time hours) rates, forest cover leads to a reduction of the temperature range (with a delay of the time to peak by up to 2 hr) and can therefore be effectively used to moderate projected climate change effects. The modelling presented here facilitated the quantification of potential mitigating effects of alternative riparian management strategies and provided a valuable tool that has potential to be utilized as an evidence base for catchment management guidance. 相似文献
In a mountain environment, the transport of coarse material is a key factor for many fields such as geomorphology, ecology, hazard assessment, and reservoir management. Despite this, there have been only a few field investigations of bedload, in particular using multiple monitoring methods. In this sense, attention has frequently focused on the effects of “high magnitude/low frequency floods” rather than on “ordinary events”. This study aims to analyze the sediment dynamics triggered by three high-frequency floods (recurrence interval “RI” between 1.1 and 1.7 yr) that occurred in the Rio Cordon basin during 2014. The flood events were investigated in terms of both sediment mobility and bedload magnitude. The Rio Cordon is an Alpine basin located in northeastern Italy. The catchment has a surface area of 5 km2, ranging between 1763 and 2763 m above sea level. The Rio Cordon flows on an armored streambed layer, with a stable step-pool configuration and large boulders. Since 1986, the basin has been equipped with a permanent station to continuously monitor water discharge and sediment flux. To investigate sediment mobility, 250 PIT-tags were installed in the streambed in 2012. The 2014 floods showed a clear difference in terms of tracer displacement. The near-bankfull events showed equal mobility conditions, with mean travel distance one order of magnitude higher than the below-bankfull event. Furthermore, only the near-bankfull events transported coarse material to the monitoring station. Both events had a peak discharge up to 2.06 m3 s-1, but the bedload transport rates differed by more than one order of magnitude, proving that under the current supply-limited condition, the bedload appears more related to the sediment supply than to the magnitude of the hydrological features. In this sense, the results demonstrated that near-bankfull events can mobilize large amounts of material for long distances, and that floods of apparently similar magnitude may lead to different sediment dynamics, depending on the type and amount of sediment supply. 相似文献
Stream-water temperature is a key variable controlling chemical, biological, and ecological processes in freshwater environments. Most models focus on a single river cross-section; however, temperature gradients along stretches and tributaries of a river network are crucial to assess ecohydrological features such as aquatic species suitability, growth and feeding rates, or disease transmission. We propose SESTET, a deterministic, spatially explicit stream temperature model for a whole river network, based on water and energy budgets at a reach scale and requiring only commonly available spatially distributed datasets, such as morphology and air temperature, as input. Heat exchange processes at the air–water interface are modelled via the widely used equilibrium temperature concept, whereas the effects of network structure are accounted for through advective heat fluxes. A case study was conducted on the prealpine Wigger river (Switzerland), where water temperatures have been measured in the period 2014–2018 at 11 spatially distributed locations. The results show the advantages of accounting for water and energy budgets at the reach scale for the entire river network, compared with simpler, lumped formulations. Because our approach fundamentally relies on spatially distributed air temperature fields, adequate spatial interpolation techniques that account for the effects of both elevation and thermal inversion in air temperature are key to a successful application of the model. SESTET allows the assessment of the magnitude of the various components of the heat budget at the reach scale and the derivation of reliable estimates of spatial gradients of mean daily stream temperatures for the whole catchment based on a limited number of conveniently located (viz., spanning the largest possible elevation range) measuring stations. Moreover, accounting for mixing processes and advective fluxes through the river network allows one to trust regionalized values of the parameters controlling the relationship between equilibrium and air temperature, a key feature to generalize the model to data-scarce catchments. 相似文献
The fronts of tunnels excavated under particularly difficult ground conditions by employing conventional tunnelling methods are commonly supported: the stabilization is usually achieved either by improving the mechanical properties of the soil (injections, jet grouting, soil freezing, etc.) or by introducing linear inclusions. This last technique, consisting in the introduction of pipes (usually made of fibreglass reinforced polymers) in the front, is particularly popular since it is very simple to adapt the reinforcement geometry, length and number to the different conditions encountered during the excavation. The design of this reinforcement technique is nowadays based on very simplified approaches: on either empirical formula or the limit equilibrium method. In a previous paper, the authors numerically studied the mechanical response of unreinforced fronts in cohesive soils and defined a non-dimensional front characteristic curve. In this paper, the authors intend to take into consideration the role of reinforcements by following the same approach. A procedure allowing the definition of the reinforced non-dimensional front characteristic curve, once the reinforcement pattern is assigned, is introduced. The practical use of this curve is described.