Reconstruction of urban stormwater contamination of an estuary using catchment history and sediment profile dating

Cores were collected from the length of Pakuranga estuary, a small urban estuary in Auckland, New Zealand, to determine sedimentation and contaminant history, and in particular the impact of urbanization. Catchment sediment loads for the most recent history (1953–1995), including urbanization since 1960, were reconstructed using the landcover history and soil erosion modeling. Pollen and¹⁴C dating and pre-urban landcover history were used to reconstruct early estuary sedimentation (i.e., post-3000 yr BP to 1960). Heavy metal concentrations, particle size,¹³⁷Cs, pollen, and catchment sediment loads were all needed to disentangle the complex estuarine response to urbanization.¹³⁷Cs profiles did not reflect the historical fallout pattern, but deposition of¹³⁷Cs-labelled eroded catchment soil, coinciding with peaks in urban construction. Temporal variations in stormwater¹³⁷Cs concentrations are likely due to varying contributions from¹³⁷Cs-rich topsoil and¹³⁷Cs-poor subsoils. A similar pattern was observed in heavy-metal concentrations and attributed to street runoff rather than topsoil being diluted by metal-poor subsoils. Dating of the sediment profiles showed that during urbanization sedimentation rates in the tidal creek and estuary were higher than sedimentation rates associated with past agricultural landuse and the original forest landcover. Urbanization has brought about substantial environmental changes in the upper estuary through continued infilling of shallow, intertidal areas, contamination by heavy metals to levels of ecological concern, sediment textural changes, and rapid mangrove colonization of formerly bare intertidal sediments.     

Significance of a combined approach for replacement stones in the heritage buildings’ conservation frame

Stone substitution is a conventional operation during heritage buildings’ restoration, but becomes problematic for architects and restorers when the quarry is mined out. The compatibility of the substitution stones with the original ones has been for long mainly based on the aesthetical aspect, this resulting too often in a patchwork of original and substitution stones with different patina after several years because of differences of properties. In this study, the objective is to show how substitution stones can be selected by combining aesthetic criteria and stones properties that are relevant for analyzing their compatibility. A couple of French limestones with their potential substitution stones were selected for the study. Our results showed that potential substitution stones selected on their aesthetic criteria require to be rejected because of their differences of physical properties. On the other hand, our results showed also the possibility to select substitution stones with satisfactory aesthetic aspect and properties that enable to expect a satisfactory compatibility with the original stone.     

Parameter identification in fresh-saltwater flow based on borehole resistivities and freshwater head data

By means of a series of borehole resistivity measurements and a resistivity–salinity relation, a particular salt-freshwater inversion was found under the shore with semi-diurnal tides at the French–Belgian border. These resistivity data provide valuable information about the vertical variation of the saltwater percentage in different boreholes. At different places and depths fluctuations of freshwater heads are observed. A regression modelling procedure is proposed in which the hydraulic parameters for density dependent flow and solute transport can be simultaneously considered with the parameters of the resistivity–salinity relation. The object function comprises resistivity residuals and freshwater head residuals along with saltwater percentage residuals and parameter residuals. First, a synthetic problem is elaborated with this regression modelling procedure. It is followed by the application of the procedure on the observed fresh-saltwater flow problem under the shore. In the synthetic problem the identification of the hydraulic parameters was demonstrated without the inclusion of prior information about these parameters. The resistivity–salinity relation was slightly adjusted in this regression. During the regression modelling of the observations made in one of the shore-normal cross sections, the horizontal and vertical conductivity are identified along with the effective porosity and the longitudinal and transverse dispersivity. The optimal values of the dispersivities are very small. Finally, it is shown that the high waters on the back shore forms the main threat of saltwater enchroachment from the sea side of the dunes and that the isolated fresh-brackish lens under the lower part of the shore before the build up area of De Panne can be explained by overexploitation.     

The New SCIAMACHY Reference Solar Spectral Irradiance and Its Validation

This paper describes a new reference solar spectrum retrieved from measurements of the satellite instrument SCIAMACHY in the wavelength region from \(0.24~\upmu\mbox{m}\) to \(2.4~\upmu\mbox{m}\) and its comparison with several other established solar reference spectra. The SCIAMACHY reference spectrum was recorded early in the mission before substantial optical degradation due to the harsh space environment sets in. The radiometric calibration of SCIAMACHY, applied in this study, includes a physical model of the scanner unit. Furthermore, SCIAMACHY’s internal white light source (WLS) is used to correct for on-ground to in-flight changes. The resultant calibrated solar spectrum from SCIAMACHY is in good agreement with several available solar spectral irradiance (SSI) references in the visible spectral range. Strong throughput losses due to detector icing in the near infrared (NIR) are now adequately accounted for. Nevertheless, a deficit with respect to the ATLAS-3 composite and SORCE/SIM SSI is observed in the NIR. However, the SCIAMACHY solar reference spectrum agrees well with the recently re-evaluated SOLAR/SOLSPEC-ISS and recent ground measurements taken at Mauna Loa in the NIR.     

Geochemical diversity in S processes mediated by culture-adapted and environmental-enrichments of Acidithiobacillus spp.

Coupled S speciation and acid generation resulting from S processing associated with five different microbial treatments, all primarily Acidithiobacillus spp. (i.e. autotrophic S-oxidizers) were evaluated in batch laboratory experiments. Microbial treatments included two culture-adapted strains, Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans, their consortia and two environmental enrichments from a mine tailings lake that were determined to be >95% Acidithiobacillus spp., by whole-cell fluorescent hybridization. Using batch experiments simulating acidic mine waters with no carbon amendments, acid generation, and S speciation associated with the oxidation of three S substrates (thiosulfate, tetrathionate, and elemental S) were evaluated. Aseptic controls showed no observable pH decrease over the experimental time course (1 month) for all three S compounds examined. In contrast, pH decreased in all microbial treatments from starting pH values of 4 to 2 or less for all three S substrates. Results show a non-linear relationship between the pH dynamics of the batch cultures and their corresponding sulfate concentrations, and indicate how known microbial S processing pathways have opposite impacts, ultimately on pH dynamics. Associated geochemical modeling indicated negligible abiogenic processes contributing to the observed results, indicating strong microbial control of acid generation extending over pH ranges from 4 to less than 2. However, the observed acid generation rates and associated S speciation were both microbial treatment and substrate-specific. Results reveal a number of novel insights regarding microbial catalysis of S oxidation: (1) metabolic diversity in S processing, as evidenced by the observed geochemical signatures in S chemical speciation and rates of acid generation amongst phylogenetically similar organisms (to the genus level); (2) consortial impacts differ from those of individual strain members; (3) environmental enrichments of Acidithiobacillus spp. catalyze different S reaction arrays than pure strain Acidithiobacillus spp.; and (4) microbial catalysis of S reactions involves significant disproportionation tied to substantial H⁺ consumption, with the formation of as yet, poorly characterized intermediate S species, most likely polythionates and polysulfane monosulfonic acids that are thought to be involved in microbial S storage mechanisms.     

Seamless integration of spatial statistics and GIS: The S-PLUS for ArcView and the S+Grassland Links

The extension of the functional capacity of geographic information systems (GIS) with tools for statistical analysis in general and exploratory spatial data analysis (ESDA) in particular has been an increasingly active area of research in recent years. In this paper, two operational implementations that combine the functionality of spatial data analysis software with a GIS are considered more closely. They consist of linkages between the S-PLUS software for data analysis and two different GIS implementations, the ArcView desktop system, which is mostly vector-oriented, and the primarily raster-based Grassland open GIS environment. We emphasize conceptual and technical issues related to the software implementation of these approaches and suggest future directions for linking spatial statistics and GIS. Received: 14 January 1999 / Accepted: 11 May 1999     

Screening of Mercury and Persistent Organochlorine Pollutants in Long-Finned Pilot Whale (Globicephala melas) in the Faroe Islands

Results of mercury and organochlorine analyses in pooled muscle and blubber samples representing in all 417 long-finned pilot whales (Globicephala melas) sampled in 1997 in the Faroe Islands are presented. The 28 pooled muscle samples from (in all) 9 pods were analysed for total mercury and the same number of pooled blubber samples were analysed for PCB (IUPAC CBs no. 28, 52, 99, 101, 105, 118, 128, 138, 153, 170, 180, 183 and 187), p,p′-DDT and metabolites and o,p′-DDT and metabolites, cis () and trans (γ)-chlordane, cis- and trans-nonachlor, oxychlordane, mirex, hexachlorobenzene, β-HCH and toxaphene (Parlars no. 26 (T2), 32, 50 (T12), 62 (T20) and 69.     

New high resolution observations of the solar diameter from space and ground with the microsatellite program PICARD

The PICARD microsatellite mission will provide 2 to 6 years simultaneous measurements of the solar diameter, differential rotation and solar constant to investigate the nature of their relations and variabilities. The 100 kg satellite has a 40 kg payload consisting of 3 instruments which will provide an absolute measure (better than 10 milliarcsec) of the diameter and the solar shape, a measure of total solar irradiance, and UV and visible flux in selected wavelength bands. Now in Phase B, PICARD is expected to be launched before mid-2003. The engineering model of the diameter telescope will be used on ground simultaneously with the satellite to investigate the atmospheric bias and state on the possible accuracy of the ground measurements carried up to now. We review the scientific goals linked to the diameter measurement, present the payload, and give a brief overview of the program aspects.     

Refurbishment, redevelopment or relocation? The changing form and location of football stadiums in the Netherlands

Summary This paper discusses the causes of the current wave of renewal and relocation of football stadiums in the Netherlands and tries to shed some light on the changing form and location of Dutch football stadiums. Comparison with developments in the United Kingdom shows not only remarkable resemblances and mutual influences, but also some significant differences. In an inextricable upward spiral of causes and consequences such as recent successes of clubs and the national team, rising attendances, increasingly positive media attention, rising interests of commercial investors, new international and national requirements on stadium construction and an increasingly positive attitude of municipalities, a new wave of stadium redevelopment and relocation has emerged in the Netherlands. In this paper it will become clear that every stadium tells its own story; some of these stories are highlighted.