White-light radiation from semi-empirical flare models

Solar Physics - We show that some recently published semi-empirical models for solar flares predict a significant flux of visible continuum radiation, due to bound-free radiation from hydrogen...     

Seasonal low-degree changes in terrestrial water mass load from global GNSS measurements

Large-scale mass redistribution in the terrestrial water storage (TWS) leads to changes in the low-degree spherical harmonic coefficients of the Earth’s surface mass density field. Studying these low-degree fluctuations is an important task that contributes to our understanding of continental hydrology. In this study, we use global GNSS measurements of vertical and horizontal crustal displacements that we correct for atmospheric and oceanic effects, and use a set of modified basis functions similar to Clarke et al. (Geophys J Int 171:1–10, 2007) to perform an inversion of the corrected measurements in order to recover changes in the coefficients of degree-0 (hydrological mass change), degree-1 (centre of mass shift) and degree-2 (flattening of the Earth) caused by variations in the TWS over the period January 2003–January 2015. We infer from the GNSS-derived degree-0 estimate an annual variation in total continental water mass with an amplitude of \((3.49 \pm 0.19) \times 10^{3}\) Gt and a phase of \(70^{\circ } \pm 3^{\circ }\) (implying a peak in early March), in excellent agreement with corresponding values derived from the Global Land Data Assimilation System (GLDAS) water storage model that amount to \((3.39 \pm 0.10) \times 10^{3}\) Gt and \(71^{\circ } \pm 2^{\circ }\), respectively. The degree-1 coefficients we recover from GNSS predict annual geocentre motion (i.e. the offset change between the centre of common mass and the centre of figure) caused by changes in TWS with amplitudes of \(0.69 \pm 0.07\) mm for GX, \(1.31 \pm 0.08\) mm for GY and \(2.60 \pm 0.13\) mm for GZ. These values agree with GLDAS and estimates obtained from the combination of GRACE and the output of an ocean model using the approach of Swenson et al. (J Geophys Res 113(B8), 2008) at the level of about 0.5, 0.3 and 0.9 mm for GX, GY and GZ, respectively. Corresponding degree-1 coefficients from SLR, however, generally show higher variability and predict larger amplitudes for GX and GZ. The results we obtain for the degree-2 coefficients from GNSS are slightly mixed, and the level of agreement with the other sources heavily depends on the individual coefficient being investigated. The best agreement is observed for \(T_{20}^C\) and \(T_{22}^S\), which contain the most prominent annual signals among the degree-2 coefficients, with amplitudes amounting to \((5.47 \pm 0.44) \times 10^{-3}\) and \((4.52 \pm 0.31) \times 10^{-3}\) m of equivalent water height (EWH), respectively, as inferred from GNSS. Corresponding agreement with values from SLR and GRACE is at the level of or better than \(0.4 \times 10^{-3}\) and \(0.9 \times 10^{-3}\) m of EWH for \(T_{20}^C\) and \(T_{22}^S\), respectively, while for both coefficients, GLDAS predicts smaller amplitudes. Somewhat lower agreement is obtained for the order-1 coefficients, \(T_{21}^C\) and \(T_{21}^S\), while our GNSS inversion seems unable to reliably recover \(T_{22}^C\). For all the coefficients we consider, the GNSS-derived estimates from the modified inversion approach are more consistent with the solutions from the other sources than corresponding estimates obtained from an unconstrained standard inversion.     

Hydrological Evaluation of the Canadian Meteorological Ensemble Reforecast Product

This paper evaluates the quality of the ensemble hydrological reforecasts obtained using the 18-year ensemble meteorological reforecast dataset available from the Canadian Centre for Meteorological and Environmental Prediction (CCMEP). This study focuses on four large watersheds in the province of Quebec. A distribution-based scaling (DBS) post-processing method is used to correct the 18-year ensemble precipitation reforecasts. An Ensemble Kalman Filter (EnKF) assimilation technique is also assessed to improve the initial conditions of the hydrologic model. There is a slight improvement in performance and reliability after applying the DBS approach to precipitation reforecasts, but this technique induces a reduction in the spread. The impact of the integration of the post-processed precipitation into the hydrologic model is also quite marginal. However, the addition of an EnKF provides better ensemble hydrological reforecasts with high performance, reliability, and skill, especially in the first reforecast horizons. The best results are, however, generally obtained when using DBS and an EnKF together. Combining DBS and an EnKF, hydrological forecasts for the next two weeks are obtained using the CCMEP reforecast and also the second generation Global Ensemble Forecast System (GEFS v2) reforecast, which is considered a reference. Forecasts of comparable skill and spread are obtained, with CCMEP-based forecasts showing better spread during the first week, and GEFS v2–based reforecasts showing better skill and spread during the second week. Finally, it is shown that the two meteorological reforecast products assessed in this study have similar economic value for hydrological forecasting applications based on the cost–loss model.     

δ30Si and δ29Si Determinations on USGS BHVO-1 and BHVO-2 Reference Materials with a New Configuration on a Nu Plasma Multi-Collector ICP-MS

We report silicon isotopic determinations for USGS rock reference materials BHVO-1 and BHVO-2 using a Nu Plasma multi-collector (MC)-ICP-MS, upgraded with a new adjustable entrance slit, to obtain medium resolution, as well as a stronger primary pump and newly designed sampler and skimmer cones ("B" cones). These settings, combined with the use of collector slits, allowed a resolution to be reached that was sufficient to overcome the ¹⁴N¹⁶O and ¹⁴N₂ interferences overlying the ³⁰Si and the ²⁸Si peaks, respectively, in an earlier set-up. This enabled accurate measurement of both δ³⁰Si and δ²⁹Si. The δ value is expressed in per mil variation relative to the NBS 28 quartz reference material. Based on data acquired from numerous sessions spread over a period of six months, we propose a recommended average δ³⁰Si of −0.33 ± 0.05‰ and −0.29 ± 0.11‰ (2se) for BHVO-1 and BHVO-2, respectively. Our BHVO grand mean silicon isotope composition (δ³⁰Si =−0.31 ± 0.06‰) is significantly more negative than the only published value for BHVO-2, but is in very good agreement with the recently established average value of ocean island basalts (OIB), confirming the conclusion that the OIB reservoir has a distinct isotopic composition from the solar reservoir as sampled by chondrites.     

Groundwater flow in the vicinity of two artificial recharge ponds in the Belgian coastal dunes

Since July 2002, tertiary treated wastewater has been artificially recharged through two infiltration ponds in the dunes of the Belgian western coastal plain. This has formed a lens of artificially recharged water in the dunes’ fresh water lens. Recharged water is recovered by extraction wells located around the ponds. Hydraulic aspects of the artificial recharge and extraction are described using field observations such as geophysical borehole loggings and a tracer test. Borehole logs indicate recharged water up to 20 m below surface, whereas the tracer test gives field data about the residence times of the recharged water. Furthermore, a detailed solute transport model was made of the area surrounding the ponds. Groundwater flow, capture zone, residence times and volume of recharged water in the aquifer are calculated. This shows that the residence time varies between 30 days and 5 years due to the complex flow pattern. The extracted water is a mix of waters with different residence times and natural groundwater, assuring a relatively stable water quality of the extracted water.     

The Effect of Breaking Waves on $$\hbox {CO}_2$$ Air–Sea Fluxes in the Coastal Zone

The influence of wave-associated parameters controlling turbulent \(\hbox {CO}_2\) fluxes through the air–sea interface is investigated in a coastal region. A full year of high-quality data of direct estimates of air–sea \(\hbox {CO}_2\) fluxes based on eddy-covariance measurements is presented. The study area located in Todos Santos Bay, Baja California, Mexico, is a net sink of \(\hbox {CO}_2\) with a mean flux of \(-1.3\, \upmu \hbox {mol m}^{-2}\hbox {s}^{-1}\) (\(-41.6\hbox { mol m}^{-2}\hbox {yr}^{-1}\)). The results of a quantile-regression analysis computed between the \(\hbox {CO}_2\) flux and, (1) wind speed, (2) significant wave height, (3) wave steepness, and (4) water temperature, suggest that the significant wave height is the most correlated parameter with the magnitude of the flux but the behaviour of the relation varies along the probability distribution function, with the slopes of the regression lines presenting both positive and negative values. These results imply that the presence of surface waves in coastal areas is the key factor that promotes the increase of the flux from and into the ocean. Further analysis suggests that the local characteristics of the aqueous and atmospheric layers might determine the direction of the flux.     

Flowpath controls on high-spatial-resolution water-chemistry profiles in headwater streams

Stream water chemistry is routinely measured over time at fixed and sparse sites, which provides a coarse image of spatial variability. Here, we measured nitrate, dissolved organic carbon (DOC) and several chemical proxies for water flowpaths, catchment residence time and biogeochemical transformations, every 50–100 m along 13 km of streams in six agricultural headwater catchments (1.1–3.5km²). The objective was to examine controls on longitudinal nitrate profiles at a high spatial resolution during four seasons: rewetting of the catchments in autumn, winter high-flow, spring recession and summer low-flow. Our results showed monotonic trends in longitudinal profiles for nitrate and DOC, which were opposite for the two solutes. Spatial trends in water-chemistry profiles persisted across seasons, which suggests time-invariant controls on the spatial variations in concentrations. Four catchments exhibited decreasing nitrate and increasing DOC from upstream to downstream, while two catchments exhibited increasing nitrate and decreasing DOC. These smooth gradients did not reflect a longitudinal land-use gradient, but rather an increase in the proportion of groundwater inflows when moving downstream, as suggested by the chemical proxies and punctual discharge measurements. Water chemistry also changed abruptly at confluences, at a farm point source and at a localized groundwater inflow zone.     

A Comparative Study of the Use of Organoclay‐Based Formulations and Organic Amendment to Reduce the Leaching of the Herbicide MCPA in Soil

MCPA (4‐chloro‐2‐methylphenoxyacetic acid) is an acidic herbicide widely used on olive crops in Spain. Due to its anionic form at natural soil pH, there is high risk of leaching and groundwater contamination by the use of this herbicide. The aim of this work was to study the effects of organoclay‐based formulations of MCPA and olive oil waste amendment on MCPA leaching in a sandy loam soil. For this purpose, batch adsorption and column leaching studies were performed. The organoclays used to prepare the clay‐based formulations of MCPA were obtained by treating Wyoming montmorillonite (SWy‐2) and Arizona montmorillonite (SAz‐1) with an amount of hexadecyltrimethylammonium (HDTMA) cation equal to 100% of the CEC of the montmorillonites. The organic residue used in this study was a solid waste from olive oil production (olive oil waste, OOW). The soil was amended with the organic residue at the rate of 10% (w/w). Batch release and column leaching studies indicated that organoclay‐based formulations of MCPA reduced the release rate and the leaching of the herbicide as compared to the use of a conventional formulation containing the herbicide in an immediately available form. The increase in soil organic matter of the soil upon amendment with the organic residue also resulted in greater adsorption and reduced leaching of MCPA in the soil. Accordingly, both the use of organoclay‐based formulations and the amendment of soil with OOW are proposed as efficient strategies to reduce extensive leaching losses associated with the application of MCPA in high‐risk scenarios, such as Mediterranean olive groves.