中国煤型铀地质–地球化学研究进展

中国铀矿资源缺口巨大,仅靠开发传统铀矿资源无法满足能源和国防建设不断增长对铀资源的需求,煤型铀资源的开发利用可一定程度上缓解对铀资源的需求压力。通过总结近些年煤型铀的研究成果,对我国主要煤型铀矿的含矿点、铀含量范围、含煤地层的形成时代及分布范围进行了归纳,并给出了煤型铀的界定标准（大于或等于40 mg/kg）,为划分煤型铀矿提供依据;对煤型铀的赋存状态、成矿机制及影响因素进行了较为全面的阐述。综合分析认为我国对煤型铀研究较不足,其中对于微观地质选择过程着力不够,而查明煤中铀富集的微观地质选择过程对于成矿机制的理解至关重要;煤型铀矿化时间和期次研究有待进一步加深,有利于分析煤型铀的矿化模式、揭示煤型铀与伴生砂岩型铀矿之间的成因联系,进而深化对煤型铀矿化机制的理解。     

青藏高原申扎-双湖剖面岩石圈电性结构特征及其含义

为了研究班公湖-怒江缝合带的壳幔电性结构及构造特征,并为其俯冲极性提供电性约束,对青藏高原中部申扎-双湖大地电磁测深剖面进行全面数据处理分析,获得了可靠的二维电性结构模型,研究表明:沿剖面上地壳分布的是规模不等的高阻体,底面埋深在10~25 km变化,高阻层之下发现由不连续的高导体构成的中下地壳高导层.通过对电性结构的分析,认为班公湖-怒江特提斯洋的俯冲消亡极性可能是双向的,随后拉萨-羌塘地体碰撞带处的上地壳高阻体发生拆沉,以上两次动力学事件可能共同作用于缝合带处的壳幔高导体,同时北拉萨地体的壳幔高导体还可能体现了构造作用、岩浆活动和成矿作用之间的关系.     

羌塘盆地中央隆起带的抬升演化:构造-热年代学约束

本文综合磷灰石裂变径迹年龄(113~43 Ma)、锆石裂变径迹年龄(169~103 Ma)、锆石U-Pb年龄(215~206 Ma)、黑云母K-Ar年龄(186~178 Ma),通过磷灰石热史模拟,TASC图谱分析和矿物封闭温度年龄等手段,获得了中央隆起晚三叠世至今较为完整的冷却抬升历史。中央隆起主要经历了早侏罗世、晚侏罗世-早白垩世、晚白垩世-中新世早期和中新世晚期至今四期冷却事件,与南北羌塘板块后碰撞伸展、拉萨羌塘板块碰撞、新特提斯洋板片俯冲、印度欧亚板块碰撞以及中新世南北向走滑伸展存在动力学联系,造成11.4 km、2.85 km、4.3~5 km和0.85 km的抬升量。中央隆起在侏罗纪相对两侧盆地抬升,随着两侧盆地经历了侏罗纪的沉积增厚,与两侧盆地高差减小,在早白垩世早期可能位于海平面附近,随后快速抬升至2~2.5 km,统一接受晚白垩世红层沉积,并经历长期持续的逆冲推覆构造活动,进一步抬升至5 km,随后受到中新世古大湖夷平和南北向伸展作用影响,中央隆起相对盆地发生差异抬升。     

南天山蛇绿混杂岩和中天山南缘糜棱岩的40Ar/39Ar年龄及其大地构造意义

 ⁴⁰Ar/³⁹Ar同位素年龄测定,获得南天山蛇绿混杂岩基质黑云母石英片岩单矿物黑云母的两个坪年龄分别为(370.0±4.8)Ma和(259.0±3.3)Ma;中天山南缘长英质糜棱岩单矿物黑云母的坪年龄为(250.5±7.9)Ma,二云母花岗岩单矿物白云母的坪年龄为(348.9±0.3)Ma。结合南天山古生代沉积特征和塔里木及伊犁-哈萨克斯坦板块古地磁数据的综合分析,提出南天山晚泥盆世至石炭纪早期完成向伊犁-哈萨克斯坦板块的B型俯冲,中-晚二叠世进行陆内A型俯冲造山的板块碰撞演化模式。     

关于露天矿山边坡稳定性管理研究的若干问题讨论

本文从科学管理的角度,讨论了露天矿山边坡稳定性管理研究的目的意义;详细论述了边坡稳定性管理研究的基本内容;并探讨了边坡岩体滑坡预报和治理加固时机问题,对保证露天矿山的安全生产具有现实意义。     

Computational study of tetrahedral Al–Si and octahedral Al–Mg ordering in phengite

 As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K₂ ^[6](Al₃Mg)^[4](Si₇Al)O₂₀(OH)₄. Values of the atomic exchange interaction parameters J _n used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range order was observed. Received: 8 August 2002 / Accepted: 14 February 2003 Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility.     

Evaluation of aluminum speciation in surface waters in China and its environmental risk assessment

As the ongoing global research on acid precipitation is developing in depth, more and more attention has been paid to the ecological effects of aluminum (Al) due to its toxicity to plants and animals, which is caused by acid precipitation. As a very serious problem of terrestrial and aquatic environmental acidification occurs in China, especially in southwestern China, a systematic investigation of Al speciation in these regions is very important. In this paper, the Al speciation results of surface waters in China are reported and its ecological impacts is evaluated. More than 100 water samples were collected from about twenty provinces of China. Driscoll's Al speciation scheme combined with the modified MINQEL computer model is used for speciation of Al. This study shows that the ecological impacts of acidification are quite different between China and Western countries, because of different geographical environments and geological settings. In Western countries, acidification is mainly caused by NO₂^-. Due to low concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺, the buffer capacities of soil and water are weak. Therefore, natural waters can be acidified to pH<5 very easily, resulting in a considerable mobilization of Al and worsening of the ecological environment. In China, acid precipitation is mainly in the form of sulfuric acid. In northwestern China, concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ are high in soil and surface waters. This leads to much higher capacity and a high resistance ability to acidification. The pH values of waters in this region are high (around 7) and no serious Al toxicity is found at present. However, in northeastern and southeastern China, the soil is rich in Al (unsaturated aluminosilicates in northeastern China, saturated aluminosilicates in north and central China, aluminum-rich soil in southeastern and southwestern China). The concentrations of K⁺, Na⁺, Ca²⁺, Mg²⁺ in soil and waters are lower than those of northwestern China. Therefore the buffer capacity is limited. Numerous surface waters have already been acidified and pH values declined to 5. The impacts of Al toxicity on ecological systems in these regions are very serious, especially in Jiangxi, Hubei Provinces and Chongqing Municipality.     

Separate lead isotope analyses of leachate and residue rock fractions: implications for metal source tracing in ore deposit studies

Separate lead isotope analyses of leachate and residue fractions are applied to a broad spectrum of rocks commonly investigated in metallogenic studies. Resulting data highlight a systematic behavior of leachate and residue fractions with respect to lead isotope compositions, which essentially depends on the mineralogical composition of the rock. Granitoid and high-grade metamorphic rocks have residue compositions virtually identical to common lead. In contrast, low-grade metasedimentary rocks may have residue compositions swamped by radiogenic lead of leach-resistant zircons. Mafic magmatic rocks have residues that are often more radiogenic than leachates, depending on the ratio of leach-refractory zircons to common lead in the residual fraction of these rocks. Separate leachate and residue analyses of source rocks provide two lead isotope end members whose mixture may represent lead with the appropriate ore fluid composition. Our leaching experiments indicate that hot acid solutions (and by inference hydrothermal fluids) preferentially leach radiogenic lead from medium- to high-grade metamorphic and granitoid rocks, whereas they preferentially leach common lead from low-grade metasedimentary and mafic magmatic rocks. The method presented in this study provides a reliable alternative to other methods (i.e., age-correction of bulk-rock compositions) for the determination of the common lead signature of felsic to intermediate magmatic rocks. This may be preferable to age-corrected bulk-rock analyses, where ages to apply for corrections of bulk-rock data are not known or where moderately to highly altered rocks must be used. Case studies of orogenic gold and MVT districts of Peru (Pataz and San Vicente, respectively) show that separate leachate and residue lead isotope analyses carried out systematically on whole rocks allow a more thorough evaluation of metal source reservoirs than does the standard method of age-corrected or uncorrected bulk-rock analyses.     

基于块体化程度确定裂隙岩体表征单元体

表征单元体（REV,或典型单元体）的存在是应用连续介质方法研究岩体问题的前提,因此,裂隙岩体表征单元体研究是岩体力学及岩体水力学中的一个基础问题,表征单元体的存在与否可以从不同物理参数的角度进行分析。从岩体块体化程度的角度对其存在性进行了较系统的分析,把岩体中由裂隙圈闭形成的孤立块体的总体积在岩体中所占体积百分比定义为裂隙岩体的块体化程度。介绍了GeneralBlock软件的基本分析过程,利用软件建立了三维裂隙岩体模型。根据国际岩石力学学会的裂隙分级,针对5个延展性级别、7个间距级别建立了35种岩体结构模型。利用GeneralBlock对这35种岩体进行了块体识别,分别讨论了这35种岩体结构的块体化程度随着模型范围变化的波动情况。由于所建立的岩体结构模型是随机的,对每种结构的每个研究范围进行了5次随机实现。结果表明,对所有的35种岩体,表征单元体的尺寸在4～8倍间距之间,不超过8倍间距。