Binding of monomeric organic compounds to marcomolecular dissolved organic matter in seawater

Several monomeric organic compounds, including amino acids, sugars, and fatty acids, were found to bind abiologically to dissolved macromolecular materials in particle-free seawater at natural substrate concentrations. The binding primarily occurred in ocean surface waters, at rates slower than in situ biological utilization rates of most of the compounds. Seasonal patterns of binding in Gulf of Maine waters may have been related to seasonal variations in macroalgal exudation of polyphenolic materials. Enhanced reactivity of relatively hydrophobic monomers implicated hydrophobic effects as potentially important in marine organic condensations. The resultant condensates showed high particle reactivity, consistent with low concentrations of dissolved condensed materials in seawater.     

Niveo-aeolian sand deposition in subarctic dunes,eastern coast of Hudson Bay,Québec,Canada

Aeolian sand transport during winter and the snow-free season was assessed quantitatively by direct year-round field measurements along transects on the lee side of parabolic dunes in subarctic Québec. In 1987–1988, niveo-aeolian deposition was more important than aeolian sedimentation in three of the four study sites, and contributed > 75% of the total annual accumulation in exposed sites and < 25% in protected forest sites. The maximum depth of interstratified snow and sand deposits (3.5 m) was recorded in March. Semi-permanent snow lenses may persist longer than 2 years in the aeolian sediments. After dissipation of snow, 22 cm of sand (as a maximum) accumulated on the slipface of the most active dunes, whereas only minor sand accumulation occurred in distant areas from active sand erosion. Wind-driven sand was dispersed over 7.4 km² in the Whapmagoostui-Kuujjuarapik area. The acumulation of snow and sand during the snow season, together with spring thaw and collapse of the niveo-aeolian deposit, caused different types of injuries to trees, especially in 1985 and 1987 when a maximum of torn branches was recorded over the last 10 year period.     

Can Distrust Enhance Public Engagement? Insights From a National Survey on Energy Issues in Canada

Research examining the relationship between trust, public engagement, and natural resource management asserts that trust fosters positive behavior and enhanced cooperation. Yet some scholars are finding that certain kinds of distrust are helpful in achieving democratic outcomes by providing would-be participants with the motivation to engage in issues of public concern. This article seeks to clarify this apparent disjuncture in the trust literature by examining the multidimensional nature of trust as it relates to public engagement on energy-related issues in Canada. Based on a national online survey (n?=?3000) we use a binary probit model to explore the connections between trust, knowledge, and public engagement. About 70% of respondents had participated in at least one form of public engagement over the last 3 years. Drawing on a two-dimensional conception of trust, we find that general trust on its own is not positively linked to public engagement. A combination of general trust and skepticism, however, is positively associated with public engagement and confirms our hypothesis that at least some concern regarding credibility, bias, and vested interest can motivate public engagement. In this sense, trust is not uniformly good for public engagement. These results signal a need to further refine our assumptions about the relationship between public trust, public engagement and environmental governance.     

Precise temperature monitoring in boreholes: evidence for oscillatory convection? Part 1: Experiments and field data

Temperature was monitored in two boreholes in Kamchatka (Russia) in years 2001–2003. Ten-min reading (sampling) interval was selected for the first half-year run followed by shorter (12 days) experiment with 5-s reading interval. A similar experiment was repeated later in the test borehole Sporilov (Prague, Czech Republic), where four temperature–time series were performed with reading intervals varying from 1 to 20 s. All temperature–time series (except the record from the bottom of the hole) displayed intermittent, non-periodic oscillations of temperature of up to several hundredths of degree with sharp gradients and large fluctuations over all observed time intervals. No such oscillation was detected at the bottom of the hole. The spectral analysis revealed a high level of stochasticity in the measured signal. Calculated spectra showed “band-pass” behavior without any definite peaks, which might characterize certain periodicity. Local growth of the second moment technique revealed the presence of at least two distinct temperature-forming processes. One of them can be related to heat transfer in the structurally and compositionally complex subsurface. The second process, which presents the bulk of the measured signal, probably reflects certain intra-hole convection. We hypothesized that the oscillatory regime of such convection is responsible for the stochastic nature of measured temperatures. Results of numerical modeling describing the fluctuation of water-cells in a vertical slot support the idea of thermally unstable water column in a hole, the instability of which produces a complex oscillation system. Model solutions and their discussion is presented in Part II of this work.     

Defining geo-habitats for groundwater ecosystem assessments: an example from England and Wales (UK)

Groundwater ecosystems comprising micro-organisms and metazoans provide an important contribution to global biodiversity. Their complexity depends on geology, which determines the physical habitat available, and the chemical conditions within it. Despite this, methods of classifying groundwater habitats using geological data are not well established and researchers have called for higher resolution habitat frameworks. A novel habitat typology for England and Wales (UK) is proposed, which distinguishes 11 geological habitats (geo-habitats) on hydrogeological principles and maps their distribution. Hydrogeological and hydrochemical data are used to determine the characteristics of each geo-habitat, and demonstrate their differences. Using these abiotic parameters, a new method to determine abiotic habitat quality is then developed. The geo-habitats had significantly different characteristics, validating the classification system. All geo-habitats were highly heterogeneous, containing both high quality habitat patches that are likely to be suitable for fauna, and areas of low quality that may limit faunal distributions. Karstic and porous habitats generally were higher quality than fractured habitats. Overall, 70% of England and Wales are covered by lower quality fractured habitats, with only 13% covered by higher quality habitats. The main areas of high quality habitats occur in central England as north–south trending belts, possibly facilitating dispersal along this axis. They are separated by low quality geo-habitats that may prevent east-west dispersal of fauna. In south-west England and Wales suitable geo-habitats occur as small isolated patches. Overall, this paper provides a new national-scale typology that is adaptable for studies in other geographic areas.     

Interdisciplinary research: framing and reframing

Framing encompasses the processes of identifying and bounding the area of research and based on our own experiences as academics we have found significant differences in the ways that researchers establish and frame a disciplinary, compared to an interdisciplinary, research project. In this paper we have attempted to contribute to the development of the conceptual framework underpinning interdisciplinary research through analysis of interviews with a number of academics already working in an interdisciplinary manner. Successful projects are able to identify and support the processes that allow the communication and negotiation that is necessary, not just for the initial framing of a research funding proposal but to be able to maintain negotiation. Self awareness and continual reflexivity and a willingness to be questioned by others are essential to this process.     

The role of innovation in advancing understanding of hydrological processes

Innovation and understanding hydrological processes are intimately linked. Existing research has demonstrated the role of technological, societal, and political drivers in shaping and delivering new understandings in hydrological processes. In this paper we pose three research questions to explore how innovation can further our understanding of hydrological processes, if working towards the sustainable development goals (SDGs) provides a helpful focus, and whether specific mechanisms can be used to facilitate innovation and research into hydrological processes. First, we examine key aspects of innovation and explore innovation in the context of water security. We then present a series of innovation projects to determine their effectiveness in delivering innovation in managing hydrological processes, but also their contribution to scientific understanding. Our research suggests that product and process innovation were more closely related to increasing scientific understanding of hydrological processes than other forms of innovation. The NE Water Hub demonstrated that the design of the innovation ecosystem was crucial to its success and provides a model to integrate innovation and research more widely to further scientific understanding and deliver behaviour change to address the SDGs.     

Catalyzing mitigation ambition under the Paris Agreement: elements for an effective Global Stocktake

The Global Stocktake (GST) takes a central role within the architecture of the Paris Agreement, with many hoping that it will become a catalyst for increased mitigation ambition. This paper outlines four governance functions for an ideal GST: pacemaker, ensurer of accountability, driver of ambition and provider of guidance and signal. The GST can set the pace of progress by stimulating and synchronizing policy processes across governance levels. It can ensure accountability of Parties through transparency and public information sharing. Ambition can be enhanced through benchmarks for action and transformative learning. By reiterating and refining the long term visions, it can echo and amplify the guidance and signal provided by the Paris Agreement. The paper further outlines preconditions for the effective performance of these functions. Process-related conditions include: a public appraisal of inputs; a facilitative format that can develop specific recommendations; high-level endorsement to amplify the message and effectively inform national climate policy agendas; and an appropriate schedule, especially with respect to the transparency framework. Underlying information provided by Parties complemented with other (scientific) sources needs to enable benchmark setting for collective climate action, to allow for transparent assessments of the state of emissions and progress of a low-carbon transformation. The information also needs to be politically relevant and concrete enough to trigger enhancement of ambition. We conclude that meeting these conditions would enable an ideal GST and maximize its catalytic effect.

Key policy insights

• The functional argument developed in this article may inspire a purposeful design of the GST as its modalities and procedures are currently being negotiated.

• The analytical framework provided serves as a benchmark against which to assess the GST's modalities and procedures.

• Gaps and blind spots in the official GST can and should be addressed by processes external to the climate regime in academia and civil society.