Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Estimation of ship velocities from MODIS and OCM

Detection of ships and their tracks in the atmosphere from satellites was earlier demonstrated by Porch, Noone, and Kaufman, among others. In this letter, we have gone one step further to estimate the ship speed and direction by locating them and their tracks from multisatellite imagery. Exhausts from the ships create streaks of clouds in the atmosphere that help identify the same ship from two satellites. Ship velocities are estimated from displacements of ships. We have used optical sensors data from Moderate Resolution Imaging Spectroradiometer (MODIS) and Ocean Color Monitor (OCM) to demonstrate this technique. Estimated velocities of ships are within the expected range. Application of this approach has general interest to the navy, coast guards, shipping corporations, commercial ship owners, and fishermen. More satellite observations can be used to continuously monitor the ship velocities.     

Geocomputation, Geodemographics and Resource Allocation for Local Policing

The field of geodemographics is one of the most fertile applications areas of geocomputation research. Geodemographic profiles of the characteristics of individuals and small areas are pivotal to tactical and strategic resource management in many areas of business, and are becoming similarly central to efficient and effective deployment of resources by public services. In this context, this paper describes research that has been developed in partnership with the Devon and Cornwall Constabulary and Institute of Criminal Justice Studies (ICJS) at the University of Portsmouth to assess the potential use of geodemographics as a policing tool. Crime, the fear of crime and the efficacy of public services are issues that have moved to the top of the UK political agenda and have long been matters of serious public concern. This paper considers the ways in which police forces might use geodemographics to better deploy resources at a variety of spatial scales in England and Wales.     

The Production of Methanol by Flowering Plants and the Global Cycle of Methanol

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.     

Elemental particle size distributions. Measured and estimated dry deposition in Sfax region (Tunisia)

Mass size distribution of the crustal elements (Al, Ca, Fe, Mg, Si, Ti), anthropogenic elements (Zn, Mn, Cr, Cu, K, P, Pb) and sea elements (Na, Cl) were obtained from measurements carried out with an inertial cascade impactor in Sfax. A fitting procedure by data inversion was applied to those data. This procedure yields accurate size distributions of aerosols in the diameter range 0.1–25 μm in two different sites. In a coastal industrial site, the mass distribution of the aerosol showed a bimodal structure; and in urban area, the lower particle mode cannot be observed. The elemental dry deposition flux was calculated as a function of particle size. The element flux size distribution increased rapidly with particle size. The modelling results indicate that the majority of the crustal and anthropogenic elements flux (>90%) was due to particles larger than 3 μm in diameter.     

Variability of the photospheric radiation of active K-M dwarfs and their X-ray luminosities

Variability of the photospheric radiation of 40 (dKe-dMe) dwarfs in the solar neighborhood due to variations in the spottedness of their surfaces is analyzed based on the behavior of their mean annual brightnesses over long time intervals. The amplitudes and characteristic time scales of the variations of the mean annual brightness are taken to be indicators of photospheric activity and were used to infer the levels of photospheric activity in the stars studied. The influence of axial rotation on the development of cyclic activity in young red dwarfs and F-M main-sequence stars is analyzed. The durations and amplitudes of the photospheric variability of rapidly rotating (dK0e-dK5e) stars testifies to a higher level of photospheric activity among red dwarfs and solar-type stars. The X-ray luminosities of these stars grow with the amplitude of the variations of the mean annual brightness. However, this is not typical of rapidly rotating M dwarfs, for which the X-ray emission varies by more than two orders of magnitude, although their degrees of spottedness are all virtually the same. A linear relationship between the X-ray and bolometric luminosities is observed for young (dKe-dMe) stars, with their ratios log(L _x/L _bol) being about ?3. These properties can be used to determine whether a red dwarf is a young star or is already on the main sequence.     

Spatial structure of the old open cluster NGC 2420

The spatial structure of the intermediate and outer regions of the old open cluster NGC 2420 is analyzed using data from the catalog of Paparó. The differential and integrated distributions of the projected [ΔF(r) and F(r)] and spatial [Δf(r) and f(r)] stellar densities are obtained for various subsystems of cluster stars using Kholopov’s star-count method. Analysis of these curves shows that: (1) the cluster has at least three distinct spatial zones with different stellar-density gradients, (2) the each cluster subsystem has a layered structure, and (3) the spatial structure of the cluster changes systematically in the transition to subsystems containing fainter main-sequence stars. Empirical relations describing the structure of the cluster are also derived. Similar structural features can also be found in other globular and open clusters.