Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

The chemical composition of HR 1512, a peculiar helium-weak star

We have used high-resolution spectra to study the chemical composition of HR 1512, a star with effective temperature T _eff = 15 200 K, atmospheric gravity log g = 3.52, microturbulence parameter V _t = 1.5 km/s, and rotation rate v sin i = 17 km s^?1. We confirm the presence of a helium deficiency (?0.6 dex), indicating that HR 1512 is a helium-weak star. Its considerable phosphorus excess (1.6 dex) testifies that the star belongs to the PGa subtype. We suggest that the He and P abundances increase with height; i.e., that there is stratification of He and P in the star’s atmosphere. Among the CNO elements, nitrogen demonstrates an underabundance of ?0.4 dex, while the abundances of carbon and oxygen are solar. Deficits of about ?0.5 or ?0.6 dex were also found for Mg, Si, and S. A neon excess of 0.4 dex was derived from our non-LTE analysis of NeI lines. The largest excess among the iron-peak elements (Cr, Mn, Fe, and Ni) is 0.6 dex, for manganese; the abundances of chromium and nickel display excesses of 0.5 and 0.3 dex, respectively, while the iron abundance is almost normal. The chemical anomalies of HR 1512 generally agree with those for mercury-manganese stars. This supports the hypothesis that PGa stars represent an extension of HgMn stars to higher temperatures.     

Managanese and iron in the White Sea: Sedimentation and diagenesis

Iron and manganese in bottom sediments studied along the sublatitudinal transect from Kandalaksha to Arkhangelsk are characterized by various contents and forms depending on sedimentation environments, grain size of sediments, and diagenetic processes. The latter include redistribution of reactive forms leading to enrichment in Fe and Mn of the surface sediments, formation of films, incrustations, and ferromanganese nodules. Variations in the total Fe content (2–8%) are accompanied by changes in the concentration of its reactive forms (acid extraction) and the concentration of dissolved Fe in the interstitial water (1–14 μM). Variations in the Mn content in sediments (0.03–3.7%) and the interstitial water (up to 500 μM) correspond to a high diagenetic mobility of this element. Changes in the valence of chemical elements results in the redox stratification of sediment strata with maximum concentrations of Fe, Mn, and sulfides. Organic matter of sediments with a considerable terrestrial constituent is oxidized by bottom water oxygen mainly at the sediment surface or in anaerobic conditions within the sediment strata. The role of inorganic components in organic matter oxidation changes from surface sediments, where manganese oxyhydroxide dominates among oxidants, to deeper layers, where sulfate of interstitial water serves as the main oxidant. Differences in river runoff and hydrodynamics are responsible for geochemical asymmetry of the transect. The deep Kandalaksha Bay serves as a sediment trap for manganese (Mn content in sediments varies within 0.5–0.7%), whereas the sedimentary environment in the Dvina Bay promotes its removal from sediments (Mn 0.05%).     

Effect of temperature and pressure on the composition of oils from the Bazhenovskaya Formation in the latitudinal segment of the Ob River area

Detailed data obtained on surface oil samples from the Bazhenovskaya Formation in the latitudinal segment of the Ob River area indicate that the composition of the oil is largely controlled by the P-T conditions in the reservoir. It was determined that the generation of hydrocarbon fluids starts at higher temperatures (T _f > 100°C) if the fluid reflux is hindered and the formation pressures are anomalously high. In systems with the free reflux of hydrocarbon fluids, the processes generating oil and gas are different. The composition of oil in the Bazhenovskaya Formation with the free reflux of hydrocarbon fluids is largely controlled by migration processes, which determine, along with the P-T parameters, the physicochemical characteristics of the oils and their concentrations of hydrocarbon groups and individual hydrocarbons. Original Russian Text ? O.F. Stasova, A.I. Larichev, N.I. Larichkina, 2006, published in Geokhimiya, 2006, No. 9, pp. 996–1005.     

On two types of metalliferous carbonaceous rocks

Two types of metalliferous carbonaceous rocks that differ in associated metals are considered. One of them is characterized by gold occurring in finely dispersed arsenopyrite and arsenic-bearing pyrite, and the other, by finely impregnated native metals in carbonaceous matter. Rocks of the first type also contain elements of the platinum group, while those of the second type bear rhenium, silver, iron, molybdenum, and other metals. Graphitic mineralization is usually localized in the shear zone associated with alkaline basalts.     

The evolution of groundwater in the Tyrrell catchment, south-central Murray Basin, Victoria, Australia

The Tyrell catchment lies on the western margin of the Riverine Province in the south-central Murray Basin, one of Australia’s most important groundwater resources. Groundwater from the shallow, unconfined Pliocene Sands aquifer and the underlying Renmark Group aquifer is saline (total dissolved solids up to 150,000 mg/L) and is Na-Cl-Mg type. There is no systematic change in salinity along hydraulic gradients implying that the aquifers are hydraulically connected and mixing during vertical flow is important. Stable isotopes (¹⁸O+²H) and Cl/Br ratios indicate that groundwater is entirely of meteoric origin and salts in this system have largely been derived by evapotranspiration of rainfall with only minor halite dissolution, rock weathering (mainly feldspar dissolution), and ion exchange between Na and Mg on clays. Similarity in chemistry of all groundwater in the catchment implies relative consistency in processes over time, independent of any climatic variation. Groundwater in both the Pliocene Sands and Renmark Group aquifers yield ages of up to 25 ka. The Tyrrell Catchment is arid to semi-arid and has low topography. This has resulted in relatively low recharge rates and hydraulic gradients that have resulted in long groundwater residence times.