Effects of experimental reheating of natural basaltic ash at different temperatures and redox conditions

A set of experiments have been performed on volcanic materials from Etna, Stromboli and Vesuvius in order to evaluate how the exposure to thermal and redox conditions close to that of active craters affects the texture and composition of juvenile pyroclasts. Selected samples were placed within a quartz tube, in presence of air or under vacuum, and kept at T between 700 and 1,130 °C, for variable time (40 min to 12 h). Results show that reheating reactivates the melt, which, through processes of chemical and thermal diffusion, reaches new equilibrium conditions. In all the experiments performed at T = 700–750 °C, a large number of crystal nuclei and spherulites grows in the groundmass, suggesting conditions of high undercooling. This process creates textural heterogeneities at the scale of few microns but only limited changes of groundmass composition, which remains clustered around that of the natural glasses. Reheating at T = 1,000–1,050 °C promotes massive groundmass crystallization, with a different mineral assemblage as a function of the redox conditions. Morphological modifications of clasts, from softening to sintering as temperature increases, occur under these conditions, accompanied by progressive smoothing of external surfaces, and a reduction in size and abundance of vesicles, until the complete obliteration of the pre-existing vesicularity. The transition from sintering to welding, characteristic of high temperature, is influenced by redox conditions. Experiments at T = 1,100–1,130 °C and under vacuum produce groundmass textures and glass compositions similar to that of the respective starting material. Collapse and welding of the clasts cause significant densification of the whole charge. At the same temperature, but in presence of air, experimental products at least result sintered and show holocrystalline groundmass. In all experiments, sublimates grow on the external surfaces of the clasts or form a lining on the bubble walls. Their shape and composition is a function of temperature and fO₂ and the abundance of sublimates shows a peak at 1,000 °C. The identification of the features recorded by pyroclasts during complex heating–cooling cycles allows reconstructing the complete clasts history before their final emplacement, during weakly explosive volcanic activity. This has a strong implication on the characterization of primary juvenile material and on the interpretation of eruption dynamics.     

A multi-disciplinary study of the 2002–03 Etna eruption: insights into a complex plumbing system

The 2002–03 Mt Etna flank eruption began on 26 October 2002 and finished on 28 January 2003, after three months of continuous explosive activity and discontinuous lava flow output. The eruption involved the opening of eruptive fissures on the NE and S flanks of the volcano, with lava flow output and fire fountaining until 5 November. After this date, the eruption continued exclusively on the S flank, with continuous explosive activity and lava flows active between 13 November and 28 January 2003. Multi-disciplinary data collected during the eruption (petrology, analyses of ash components, gas geochemistry, field surveys, thermal mapping and structural surveys) allowed us to analyse the dynamics of the eruption. The eruption was triggered either by (i) accumulation and eventual ascent of magma from depth or (ii) depressurisation of the edifice due to spreading of the eastern flank of the volcano. The extraordinary explosivity makes the 2002–03 eruption a unique event in the last 300 years, comparable only with La Montagnola 1763 and the 2001 Lower Vents eruptions. A notable feature of the eruption was also the simultaneous effusion of lavas with different composition and emplacement features. Magma erupted from the NE fissure represented the partially degassed magma fraction normally residing within the central conduits and the shallow plumbing system. The magma that erupted from the S fissure was the relatively undegassed, volatile-rich, buoyant fraction which drained the deep feeding system, bypassing the central conduits. This is typical of most Etnean eccentric eruptions. We believe that there is a high probability that Mount Etna has entered a new eruptive phase, with magma being supplied to a deep reservoir independent from the central conduit, that could periodically produce sufficient overpressure to propagate a dyke to the surface and generate further flank eruptions.Editorial responsibility: J. Donnelly-Nolan     

A methodological approach for estimating turbidity in a river

During the operations of purging and disposal of sediments of a reservoir it is necessary to know the values of turbidity in the river downstream in natural condition,in the absence of dams or river training works.The paper shows that under these conditions the ratio of the average values of sediment discharge to the annual maximum value of water discharge is a function of the average annual turbidity.Turbidity can be considered as representative synthetic index of the climatic conditions,the lithological features and the land cover of the basin,and the geometric characteristics of the river network.The proposed relationship of sediment discharge as a function of water discharge were validated on the basis of data collected from different Italian regions that have very different morphological,geo-lithological and rainfall features and that are characterised by a basin area changing between a few dozen and thousands of square kilometres.The results can be considered satisfying.     

Exponential Gaussian approach for spectral modeling: The EGO algorithm I. Band saturation

Curve fitting techniques are a widespread approach to spectral modeling in the VNIR range [Burns, R.G., 1970. Am. Mineral. 55, 1608-1632; Singer, R.B., 1981. J. Geophys. Res. 86, 7967-7982; Roush, T.L., Singer, R.B., 1986. J. Geophys. Res. 91, 10301-10308; Sunshine, J.M., Pieters, C.M., Pratt, S.F., 1990. J. Geophys. Res. 95, 6955-6966]. They have been successfully used to model reflectance spectra of powdered minerals and mixtures, natural rock samples and meteorites, and unknown remote spectra of the Moon, Mars and asteroids. Here, we test a new decomposition algorithm to model VNIR reflectance spectra and call it Exponential Gaussian Optimization (EGO). The EGO algorithm is derived from and complementary to the MGM of Sunshine et al. [Sunshine, J.M., Pieters, C.M., Pratt, S.F., 1990. J. Geophys. Res. 95, 6955-6966]. The general EGO equation has been especially designed to account for absorption bands affected by saturation and asymmetry. Here we present a special case of EGO and address it to model saturated electronic transition bands. Our main goals are: (1) to recognize and model band saturation in reflectance spectra; (2) to develop a basic approach for decomposition of rock spectra, where effects due to saturation are most prevalent; (3) to reduce the uncertainty related to quantitative estimation when band saturation is occurring. In order to accomplish these objectives, we simulate flat bands starting from pure Gaussians and test the EGO algorithm on those simulated spectra first. Then we test the EGO algorithm on a number of measurements acquired on powdered pyroxenes having different compositions and average grain size and binary mixtures of orthopyroxenes with barium sulfate. The main results arising from this study are: (1) EGO model is able to numerically account for the occurrence of saturation effects on reflectance spectra of powdered minerals and mixtures; (2) the systematic dilution of a strong absorber using a bright neutral material is not responsible for band deformation. Further work is still required in order to analyze the behavior of the EGO algorithm with respect to the saturation phenomena using more complex band shapes than pyroxene bands.     

Petrologic evidence of a complex plumbing system feeding the July–August 2001 eruption of Mt. Etna,Sicily, Italy

After the major 1991–1993 eruption, Mt. Etna resumed flank activity in July 2001 through a complex system of eruptive fissures cutting the NE and the S flanks of the volcano and feeding effusive activity, fire fountains, Strombolian and minor phreatomagmatic explosions. Throughout the eruption, magmas with different petrography and composition were erupted. The vents higher than 2,600 m a.s.l. (hereafter Upper vents, UV) erupted porphyritic, plagioclase-rich trachybasalt, typical of present-day summit and flank activity. Differently, the vents located at 2,550 and 2,100 m a.s.l. (hereafter Lower vents, LV) produced slightly more primitive trachybasalt dominated by large clinopyroxene, olivine and uncommon minerals for Etna such as amphibole, apatite and orthopyroxene and containing siliceous and cognate xenoliths. Petrologic investigations carried out on samples collected throughout the eruption provided insights into one of the most intriguing aspects of the 2001 activity, namely the coeval occurrence of distinct magmas. We interpret this evidence as the result of a complex plumbing system. It consists in two separate magma storage systems: a shallow one feeding the activity of the UV and a deeper and more complex storage related to the activity of LV. In this deep storage zone, which is thermally and compositionally zoned, the favourable conditions allow the crystallization of amphibole and the occurrence of cognate xenoliths representing wall cumulates. Throughout 2001 eruption, UV and LV magmas remain clearly distinct and ascended following different paths, ruling out the occurrence of mixing processes between them. Furthermore, integrating the 2001 eruption in the framework of summit activity occurring since 1995, we propose that the 2001 magma feeding the vents lower than 2,600 m a.s.l. is a precursor of a refilling event, which reached its peak during the 2002–2003 Etna flank eruption.     

Three-dimensional earthquake locations and upper crustal structure of the Sannio-Matese region (southern Italy)

The Sannio-Matese region is one of the most seismically active regions of Italy and has been struck by large historical earthquakes. At present, the area is characterized by low magnitude background seismicity and small seismic sequences following M4 main events. In this paper, we show Vp and Vp/Vs models and 3D locations for a complete set of earthquakes occurring in the period 1991–2001. We observe a significant crustal heterogeneity, with large scale east-verging high Vp fault-related-folds, stacked by the Pliocene compression. The relocated earthquakes cluster along a 70° east-dipping, NW-striking plane located at the border of the high Vp thrust units. Normal fault earthquakes related to the young and active extension occur within these high Vp zones, interpreted as high strength material. We expect large future earthquakes to occur within these high Vp zones actually characterized by low magnitude seismicity at their borders.     

Crystal population density in not stationary volcanic systems: estimate of olivine growth rate in basalts of Lanzarote (Canary Islands)

Summary We have collected pupulation density data of melanephelinite to olivine tholeiite lavas showing seriated olivine phenocrysts as the first, and often the only, phase occurring on the liquidus. The samples are from the island of Lanzarote, where large volumes of primitive basaltic magmas reach directly the surface from their source regions at a depth between 100 and 50 km. A minimum ascent speed of 1.0 ms^–1, corresponding to times of rise of the magmas in the order of 1 day, was estimated from the occurrence of mantle xenoliths. Modal data have been automatically collected from digitalized images of thin sections. The spatial size distribution densities of olivine show an exponential variation for small crystal dimensions and a nearly constant value for large ones. Theoretical analysis shows that this behaviour can be related to variations of nucleation and growth rate with undercooling. Parameters derived for olivine growth rate equation suggest a growth rate of about 3 x 10^–7 cm s^–1 for undercooling of about 30°C.[/ p]

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Kristall-populations-dichte in nicht-stationären vulkanischen systemen: Abschätzung der wachstumsraten von olivin in basalten auf Lanzarote (Kanarische Inseln).

Zusammenfassung Wir haben Populations-Dichte-Daten von Melanephelinit bis Olivin-Tholeiit-Laven, die Olivin-Kristalle als erste und oft einzige Phase am Liquidus zeigen, erarbeitet. Die Proben stammen von der Insel Lanzarote, wo große Volumina primitiver BasaltMagmen direkt von einer Ursprungsregion in einer Tiefe von 100-50 km an die Oberfläche kommen. Das Vorkommen von Mantel-Xenolithen weist auf eine minimale Aufstiegsgeschwindigkeit von 1.0 ms^–1 hin, und dies entspricht Aufstiegszeiten der Magmen in der Größenordnung von einem Tag. Modale Daten wurden automatisch von digitalisierten Bildern von Dünnschliffen gesammelt. Die räumlichen GrößenverteilungsDichten von Olivin zeigen eine exponentionelle Variation für kleine Kristalle und einen beinahe konstanten Wert für große Kristalle. Dieses Verhaltensteht mit Schwankungen der Nukleations- und Wachstumsraten bei Unterkühlung im Zusammenhang. Parameter, die sich für Olivin-Wachstumsraten ergaben, weisen auf Werte von ungefähr 3 × 10^–7 cm s^–1 für Unterkühlung von 30°C hin.[/ p]

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With 4 Figures     

The 1669 eruption at Mount Etna: chronology,petrology and geochemistry,with inferences on the magma sources and ascent mechanisms

 Analysis of the petrochemical characters of the 1669 Etnean lavas shows that they can be grouped into two sets: SET1 lavas were erupted from 11 to 20 March and are more primitive in composition than SET2, erupted later until the end of activity. Both sets may be interpreted as the result of crystallization under different conditions of two primary magmas which are compositionally slightly distinct and which fractionate different volumetric proportions of minerals. To explain why more mafic lavas (SET1) were erupted earlier than more acid ones (SET2), we argue that new deeper magma rose up into a reservoir where residing magma was fractionating. Density calculations demonstrate that new magma is less dense and may originate a plume, rapidly rising through the residing magma which is cooler and more volatile-depleted than the new magma. Calculations of uprise velocity assuming laminar flow are consistent with this hypothesis. Received: 20 November 1995 / Accepted: 2 August 1996     

The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)

This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percentage was 88 ± 9%. The detection limit (LOD) of analytical procedure was less than 0.2 μg/kg d.w. for all analytes. The quantification limit (LOQ) of analytical procedure was less than 0.7 μg/kg d.w.The resulting distributions and weight ratios of specific compounds are discussed in terms of sampling location and origin of organic matter. A comparison with other studies of total PAHs suggests that the levels are within the concentration ranges already reported by other authors. From an eco-toxicological point of view, total PAH concentrations at seven out of the eight sites studied represent a relatively clean environment when compared to other sites.Organic matter content and PAH concentrations were found to be correlated and the compounds present in Stagnone sediments were shown to be mainly of pyrolitic origin, while a negligible quantity of PAHs may derive from biogenic sources since all the sediments contain perylene traces. There is no evidence of coal-tar contamination.Cluster analysis was carried out in order to discriminate between different PAH origins.