The effects of a copper-based antifouling paint on mortality and enzymatic activity of a non-target marine organism

Antifouling paints are used on a wide range of underwater structures in order to protect them from the development of fouling organisms. The leaching of the toxic substances from the matrix of the paint causes toxic effects not only to the fouling organisms but also on other "non-target" biota. The present study addresses the impact of the antifouling paint Flexgard VI-II on brine shrimp nauplii selected as convenient test organisms. The surface to volume (S/V) concept developed by Persoone and Castritsi-Catharios (1989) was used to determine S/V-LC50s for the test biota exposed to PVC test panels of 400-1000 mm2 surface coated with the antifouling paint in test vessels containing 20 ml seawater. Total ATPase and Mg2+-ATPase were also analyzed for coated surface areas inducing less than 50% mortality in the brine shrimp nauplii. The calculated S/V-LC50 (24 h) was 24.6 mm2/ml, which shows the high toxic character of the antifouling paint. Decreased enzymatic activities were noted in the brine shrimp nauplii exposed to test panels of 50 and 100 mm2 in 20 ml seawater. The present study indicates that the "surface to volume" concept is an interesting methodology that can be applied with both lethal and sublethal effect criteria for the determination of toxic stress from leaches of painted surfaces.     

Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

A soil chronosequence in Late Glacial and Neoglacial moraines, Humboldt Glacier, northwestern Venezuelan Andes

Late Glacial and Neoglacial (Little Ice Age) deposits on the Humboldt Massif were analyzed for relative-age dating parameters, including geomorphic and weathering characteristics, geochemical and soil properties. The soil chronosequence, formed in chemically uniform parent materials, provides an important database to study soil evolution in a tropical alpine environment. Extractable and total Fe and Al concentrations, examined to assess their use in relative-age determination, and as paleoenvironmental indicators, provide an important measure of the accumulation and downward profile movement over time of organically-bound Al, ferrihydrite and other crystalline forms (hematite and goethite) of extractable Fe. Ferrihydrite is particularly useful in determining former perched water levels in soils with relation to paleoclimate. The ratios of most Fe extracts are time dependent. The Fe_d/Fe_t ratio, within statistical limits, shows a slow increase from LIA (Little Ice Age) to Late Glacial soils, which closely correlates with other alpine soil studies in the middle latitudes and other tropical alpine locales. Values of Al_d (dithionite) and Al_o (oxalate extractable) generally do not correlate with time; however, Al_p (pyrophosphate extractable) measured against Al_t (total) provides insight on the downward translocation over time of organically-bound Al. Low leaching rates in this chronosequence are further supported by clay mineralogy trends and the geochemical data.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

Persisting challenges for performance-based building assessment

Intense research and refinement of the tools used in performance-based seismic engineering have been made, but the maturity and accuracy of these methods have not been adequately confirmed with actual data from the field. The gap between the assumed characteristics of actual building systems and their idealized counterparts used for analysis is wide. When the randomly distributed flaws in buildings as they exist in urban areas and the extreme variability of ground motion patterns combine, the conventional procedures used for pushover or dynamic response history analyses seem to fall short of reconciling the differences between calculated and observed damage. For emergency planning and loss modeling purposes, such discrepancies are factors that must be borne in mind. Two relevant examples are provided herein. These examples demonstrate that consensus-based analytical guidelines also require well-idealized building models that do not lend themselves to reasonably manageable representations from field data. As a corollary, loss modeling techniques, e.g., used for insurance purposes, must undergo further development and improvement.     

Formation conditions of the chemistry of Tersinskie carbonic-acid mineral water

Data on the ion-salt, microcomponent, gas, microbiological, and isotopic composition of water and the results of studies of the equilibriums in the water-rock system are used to analyze the formation processes of the composition of Tersinskie carbonic-acid mineral water and their genesis.     

Analysis of MDI High-Degree Mode Frequencies and their Rotational Splittings

We present a detailed analysis of solar acoustic mode frequencies and their rotational splittings for modes with degree up to 900. They were obtained by applying spherical harmonic decomposition to full-disk solar images observed by the Michelson Doppler Imager onboard the Solar and Heliospheric Observatory spacecraft. Global helioseismology analysis of high-degree modes is complicated by the fact that the individual modes cannot be isolated, which has limited so far the use of high-degree data for structure inversion of the near-surface layers (r>0.97R _⊙). In this work, we took great care to recover the actual mode characteristics using a physically motivated model which included a complete leakage matrix. We included in our analysis the following instrumental characteristics: the correct instantaneous image scale, the radial and non-radial image distortions, the effective position angle of the solar rotation axis, and a correction to the Carrington elements. We also present variations of the mode frequencies caused by the solar activity cycle. We have analyzed seven observational periods from 1999 to 2005 and correlated their frequency shift with four different solar indices. The frequency shift scaled by the relative mode inertia is a function of frequency alone and follows a simple power law, where the exponent obtained for the p modes is twice the value obtained for the f modes. The different solar indices present the same result.     

Current trends of ice coverage changes in the Franz Josef Land Archipelago area

Doklady Earth Sciences - The data on the ice distribution in the Franz Josef Land Archipelago area during the 2010/2011 and 2014/2015 ice seasons depending on climate oscillations are presented...     

Determining basic characteristics of stars from evolutionary computations

A technique for determining a star’s radius from its atmospheric characteristics (effective temperature, surface gravity, and metallicity) is realized based on modernmodel computations of the stellar internal structure and evolution. The atmospheric characteristics can also be used to find the mass and luminosity of the star. The star’s rate of evolution and the initial mass function are taken into account when determining the stellar characteristics, increasing the correctness of the results. Computations of stellar evolution of with and without the stellar rotation taken into account make it possible to remove ambiguity due to missing data on the star’s rotational velocity. The results are checked and uncertainties estimated using stars occupying two heavily populated regions in the Hertzsprung–Russell diagram that have been well studied using various methods: the main sequence and red giant branch. Good agreement with the observations is achieved; there are almost no systematic deviations of the derived point estimates of the fundamental characteristics. The metallicities of the individual components of eclipsing variable stars are estimated using observational data on for such stars displaying lines of both components in their spectra. These metallicities were determined as a function of the stellar masses in a way that eliminates systematic deviations in the derived fundamental characteristics.