Variations of methane induced pyrite formation in the accretionary wedge sediments offshore southwestern Taiwan

The accretionary wedge of offshore southwestern Taiwan contains abundant deposits of gas hydrate beneath the sea floor. High concentrations of methane in pore waters are observed at several locations with little data concerning historical methane venting available. To understand temporal variation of methane venting in sediments over geologic time, a 23-m-long Calypso piston core (MD05-2911) was collected on the flank of the Yung-An Ridge. Pore water sulfate, dissolved sulfide, dissolved iron, methane, sedimentary pyrite, acid volatile sulfide, reactive iron, organic carbon and nitrogen as well as carbonate δ¹³C were analyzed.Three zones with markedly different pyrite concentration were found at the study site. Unit I sediments (>20 mbsf) were characterized with a high amount of pyrite (251–380 μmol/g) and a δ¹³C-depleted carbonate, Unit II sediments (15–20 mbsf) with a low pyrite (15–43 μmol/g) and a high content of iron oxide mineral and Unit III sediments (<10 mbsf) by a present-day sulfate–methane interface (SMI) at 5 m with a high amount of pyrite (84–221 μmol/g) and a high concentration of dissolved sulfide.The oscillation records of pyrite concentrations are controlled by temporal variations of methane flux. With an abundant supply of methane to Unit I and III, anaerobic methane oxidation and associated sulfate reduction favor diagenetic conditions conducive for significant pyrite formation. No AOM signal was found in Unit II, characterized by typical organically-limited normal marine sediments with little pyrite formation. The AOM induced pyrite formation near the SMI generates a marked pyrite signature, rendering such formation of pyrite as a useful proxy in identifying methane flux oscillation in a methane flux fluctuate environment.     

Herschel SPIRE FTS telescope model correction

Emission from the Herschel telescope is the dominant source of radiation for the majority of SPIRE Fourier transform spectrometer (FTS) observations, despite the exceptionally low emissivity of the primary and secondary mirrors. Accurate modelling and removal of the telescope contribution is, therefore, an important and challenging aspect of FTS calibration and data reduction pipeline. A dust-contaminated telescope model with time invariant mirror emissivity was adopted before the Herschel launch. However, measured FTS spectra show a clear evolution of the telescope contribution over the mission and strong need for a correction to the standard telescope model in order to reduce residual background (of up to 7 Jy) in the final data products. Systematic changes in observations of dark sky, taken over the course of the mission, provide a measure of the evolution between observed telescope emission and the telescope model. These dark sky observations have been used to derive a time dependent correction to the telescope emissivity that reduces the systematic error in the continuum of the final FTS spectra to ～0.35 Jy.     

Herschel celestial calibration sources

Celestial standards play a major role in observational astrophysics. They are needed to characterise the performance of instruments and are paramount for photometric calibration. During the Herschel Calibration Asteroid Preparatory Programme approximately 50 asteroids have been established as far-IR/sub-mm/mm calibrators for Herschel. The selected asteroids fill the flux gap between the sub-mm/mm calibrators Mars, Uranus and Neptune, and the mid-IR bright calibration stars. All three Herschel instruments observed asteroids for various calibration purposes, including pointing tests, absolute flux calibration, relative spectral response function, observing mode validation, and cross-calibration aspects. Here we present newly established models for the four large and well characterized main-belt asteroids (1) Ceres, (2) Pallas, (4) Vesta, and (21) Lutetia which can be considered as new prime flux calibrators. The relevant object-specific properties (size, shape, spin-properties, albedo, thermal properties) are well established. The seasonal (distance to Sun, distance to observer, phase angle, aspect angle) and daily variations (rotation) are included in a new thermophysical model setup for these targets. The thermophysical model predictions agree within 5 % with the available (and independently calibrated) Herschel measurements. The four objects cover the flux regime from just below 1,000 Jy (Ceres at mid-IR N-/Q-band) down to fluxes below 0.1 Jy (Lutetia at the longest wavelengths). Based on the comparison with PACS, SPIRE and HIFI measurements and pre-Herschel experience, the validity of these new prime calibrators ranges from mid-infrared to about 700 μm, connecting nicely the absolute stellar reference system in the mid-IR with the planet-based calibration at sub-mm/mm wavelengths.     

Herschel SPIRE FTS relative spectral response calibration

Herschel/SPIRE Fourier transform spectrometer (FTS) observations contain emission from both the Herschel Telescope and the SPIRE Instrument itself, both of which are typically orders of magnitude greater than the emission from the astronomical source, and must be removed in order to recover the source spectrum. The effects of the Herschel Telescope and the SPIRE Instrument are removed during data reduction using relative spectral response calibration curves and emission models. We present the evolution of the methods used to derive the relative spectral response calibration curves for the SPIRE FTS. The relationship between the calibration curves and the ultimate sensitivity of calibrated SPIRE FTS data is discussed and the results from the derivation methods are compared. These comparisons show that the latest derivation methods result in calibration curves that impart a factor of between 2 and 100 less noise to the overall error budget, which results in calibrated spectra for individual observations whose noise is reduced by a factor of 2–3, with a gain in the overall spectral sensitivity of 23 % and 21 % for the two detector bands, respectively.     

Recent environmental changes on Banks Island (N.W.T., Canadian Arctic) quantified using fossil diatom assemblages

Banks Island (N.W.T.) has become a focal point for climate change studies in the Canadian Arctic. However, long-term climatic and environmental data are very sparse from this large island, as they are for the entire southwestern region of the Canadian Arctic Archipelago. In this paleolimnological study, diatom species assemblage shifts documented in cores collected from a pond and a lake on Banks Island were interpreted to represent a response to climate warming commencing in the nineteenth century. We found that, although the timing and overall nature of the species changes in the two cores were consistent, the signal was muted in the deeper site likely as a result of differences in ice cover extent and duration between lakes and ponds. A high-resolution study was also conducted from a second pond, at sub-decadal resolution, that only spanned the last ∼60 years. In the deeper lake site, Fragilaria construens and F. pinnata dominated the assemblages, similar to those noted in other high Arctic regions where lakes are characterized by extended ice cover. In contrast, Denticula kuetzingii dominated the shallower ponds and, in the case of the pond core representing the longer time period, this taxon increased in the post-1850 sediments, likely coincident with climate warming. In all cores, diatom assemblages became more diverse and Achnanthes species (particularly A. minutissima) increased from ∼1850 to the present, similar to changes documented in other Arctic regions. Beta diversity values calculated for the diatom species changes indicated that assemblage shifts in the Banks Island cores were of similar magnitude to those recorded in other Arctic regions with high species turnover, such as Ellesmere Island. A diatom-based Total Nitrogen (TN) transfer function previously developed for Banks Island was applied to the three ²¹⁰Pb dated cores as an exploratory tool for inferring past changes in nitrogen concentrations. In both the lake and pond cores, diatom-inferred TN concentrations tended to increase in the more recent sediments, as may be expected with warming; however these trends were not very distinct.     

The impact of the diurnal cycle on the MJO over the Maritime Continent: a modeling study assimilating TRMM rain rate into global analysis

In the present study, we use modeling experiments to investigate the impact of the diurnal cycle on the Madden-Julian Oscillation (MJO) during the Australian summer. Physical initialization and a nudging technique enable us to assimilate the observed Tropical Rainfall Measuring Mission (TRMM) rain rate and atmospheric variables from the National Centers for Environmental Prediction—National Center for Atmospheric Research Reanalysis 2 (R2) into the Florida State University Global Spectral Model (FSUGSM), resulting in a realistic simulation of the MJO. Model precipitation is also significantly improved by TRMM rain rate observation via the physical initialization. We assess the influence of the diurnal cycle on the MJO by modifying the diurnal component during the model integration. Model variables are nudged toward the daily averaged values from R2. Globally suppressing the diurnal cycle (NO_DIURNAL) exerts a strong impact on the Maritime Continent. The mean state of precipitation increases and intraseasonal variability becomes stronger over the region. It is well known that MJO weakens as it passes over the Maritime Continent. However, the MJO maintains its strength in the NO_DIURNAL experiment, and the diminution of diurnal signals during the integration does not change the propagating speed of the MJO. We suggest that diminishing the diurnal cycle in NO_DIURNAL consumes less moist static energy (MSE), which is required to trigger both diurnal and intraseasonal convection. Thus, the remaining MSE may play a major role along with larger convective instability and stronger lower level moisture convergence in intensifying the MJO over the Maritime Continent in the model simulation.     

Diurnal Variation of Tropical Convection during TOGA COARE IOP

Diurnal variation of tropical convection and kinematic and thermodynamic conditions was investigated for different large-scale environments of the convectively active and inactive periods by using satellite observations and surface measurements during the Intensive Observation Period （IOP） of the Tropical Ocean Global Atmosphere/Coupled Ocean-Atmosphere Response Experiment （TOGA/COARE）. During the convectively active period, the features of nocturnal convection appear in vertical profiles of convergence, vertical velocity, heat source, and moisture sink. The specific humidity increases remarkably in the middle troposphere at dawn. On the other hand, the altitude of maximum convergence and that of the upward motion is lower during the convectively inactive period. The specific humidity peaks in the lower troposphere in the daytime and decreases in the middle troposphere. Spectral analyses of the time series of the infrared （IR） brightness temperature （TBB） and amounts of rainfall suggest multiscale temporal variation with a prominent diurnal cycle over land and oceanic regions such as the Intensive Flux Array （IFA） and the South Pacific Convergence Zone （SPCZ）. Over land, the daily maximum of deep convection associated with cloud top temperature less than 208 K appears at midnight due to the daytime radiative heating and the sea-land breeze. Over the ocean, convection usually tends to occur at dawn for the convectively active period while in the afternoon during the inactive period. Comparing the diurnal variation of convection with large-scale variables, the authors inferred that moisture in the middle troposphere contributes mostly to the development of nocturnal convection over the ocean during the convectively active period.     

Antecedent mid-tropospheric frontogenesis caused by the interaction between a tropical cyclone and midlatitude trough: a case study of Typhoon Rusa (2002)

This study examines antecedent mid-tropospheric frontogenesis (AMF) resulting from the interaction between Typhoon Rusa (2002) and a midlatitude trough over the Korean Peninsula. In this event, the AMF contributed to the first peak in the time series of rainfall in Gangneung (37.75°N, 128.90°E), occurring about 12 h before the time of the extratropical transition (ET) process of the tropical cyclone (TC). Using observations and high-resolution model outputs, we showed that the AMF contributed to the antecedent rainfall in Gangneung during the first rainfall period when Gangneung was located outside of Rusa's sphere of direct influence. A Weather Research Forecasting (WRF) model experiment was conducted to diagnose the frontogenetical features and associated precipitation processes in detail. The experiment revealed that the AMF was mainly forced by the horizontal deformation forcing (HDF). The direction of the HDF was oriented from southwest to northeast in the middle part of the peninsula. The HDF increased positively due to the confluence of the southeasterlies from the TC and the northwesterlies emanating from the midlatitude trough. The experiment also suggested that the mid-tropospheric moisture originated from the subtropical ocean and deposited into the frontal region by the southerlies on the eastern periphery of the TC, which enhanced the convergence of moisture flux in the frontal region during the first rainfall period. The thermally direct circulation associated with the AMF lead to the mid-tropospheric saturation, which enhanced the precipitation of the first rainfall event together with the orographically forced convection at the low level above Gangneung.     

Aluminium solubility in rainwater and molten snow

Large variations of aluminium solubilities are found in marine and rural precipitations. The results of seven field experiments are used to produce a model of the solubilization of aluminium independent of the sampling site. Large variations of solubility appear, and the pH seems to be a major factor explaining this solubility changes. Thermodynamic calculations at T=278K suggest that, at higher pHs (>5), equilibrium with gibbsite (Al(OH)₃) or a trivalent alkaline insoluble form acts as a limiting of aluminium solubility and at lower pHs (<5), Al could be in equilibrium with a hydroxysulfate salt Al(OH)_1.5(SO₄)_0.75.Paper submitted to the 7th International Symposium of the Commission for Atmospheric Chemistry and Global Pollution on the Chemistry of the Global Atmosphere held in Chamrousse, France, from 5 to 11 September 1990.     

Evolution of waves and currents over a submerged laboratory shoal

The vertically-integrated effect of interaction between waves and wave-induced currents on wave transformation over a submerged elliptic shoal was investigated based on numerical simulations of the Vincent and Briggs experiment [Vincent, C.L., Briggs, M.J., 1989. Refraction- diffraction of irregular waves over a mound. Journal of Waterway, Port, Coastal and Ocean Engineering, 115(2), pp. 269–284.]. The numerical simulations were performed using two numerical wave-current model systems: one, a combination of the wave model SWAN and the current model SHORECIRC, and the other, a combination of the wave model REF/DIF and the same current model. A time-dependent, phase-resolving wave and current model, FUNWAVE, was also utilized to simulate the experiment. In the simulations, the developed wave-induced currents defocused waves behind the shoal and brought on a wave shadow zone that showed relatively low wave height distributions. For the breaking case of monochromatic waves, the wave heights computed using FUNWAVE showed good agreement with the measurements and the resulting wave-induced currents showed a jet-like velocity distribution in transverse direction. And the computed results of the two model combinations agreed better with the measurements than the computed results obtained by neglecting wave-current interaction. However, it was found that for the case in which transverse interference pattern caused by refracted waves was strong, REF/DIF-SHORECIRC did not correctly evaluate radiation stresses, the gradients of which generate wave-induced currents. SWAN-SHORECIRC, which cannot deal with the interference patterns, predicted a jet-like wave-induced current. For breaking random wave cases, the computed results of the two model combinations and FUNWAVE agreed well with the measurements. The agreements indicate that it is necessary to take into account the effect of wave-induced current on wave refraction when wave breaking occurs over a submerged shoal.